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    Diblock copolymers prepared by cross metathesis
    4.
    发明授权
    Diblock copolymers prepared by cross metathesis 有权
    通过交叉复分解制备的二嵌段共聚物

    公开(公告)号：US08940839B2

    公开(公告)日：2015-01-27

    申请号：US13072383

    申请日：2011-03-25

    Applicant: John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    Inventor： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    IPC: C08G61/04 ,  C08L65/00

    CPC classification number: C08G61/04 ,  C08G2261/419 ,  C08L65/00

    Abstract: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

    Abstract translation: 本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体， 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度 在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

    Diblock Copolymers Prepared by Cross Metathesis
    6.
    发明申请
    Diblock Copolymers Prepared by Cross Metathesis 有权
    通过交叉复分解制备的二嵌段共聚物

    公开(公告)号：US20120245290A1

    公开(公告)日：2012-09-27

    申请号：US13072383

    申请日：2011-03-25

    Applicant: John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    Inventor： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    IPC: C08F299/00 ,  C08L53/00

    CPC classification number: C08G61/04 ,  C08G2261/419 ,  C08L65/00

    Abstract: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

    Abstract translation: 本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体， 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度 在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

    Carbene complexes of lithium and/or magnesium metal salts, and uses thereof
    7.
    发明授权
    Carbene complexes of lithium and/or magnesium metal salts, and uses thereof 有权
    锂和/或镁金属盐的卡宾络合物及其用途

    公开(公告)号：US08519147B2

    公开(公告)日：2013-08-27

    申请号：US12939063

    申请日：2010-11-03

    Applicant: John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Renuka N. Ganesh

    Inventor： John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Renuka N. Ganesh

    IPC: C07F3/02 ,  C07F1/02

    CPC classification number: C07F15/0046 ,  C07D207/06 ,  C10G3/00 ,  C10G2300/1014 ,  C10G2300/1088 ,  C10G2400/20 ,  C10G2400/22 ,  Y02E50/13

    Abstract: This invention relates to a carbene complex of metal salt represented by the formula: [T−M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23° C. for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1−)s(L2−)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L0 is a neutral ligand, L1− is a monoanionic ligand, L2− is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3, or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.

    Abstract translation: 本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。 本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L 0是中性配体，L1-是单阴离子配体， L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是总电荷 的分子。 过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

    Carbene Complexes of Lithium And/Or Magnesium Metal Salts, And Uses Thereof
    9.
    发明申请
    Carbene Complexes of Lithium And/Or Magnesium Metal Salts, And Uses Thereof 有权
    锂和/或镁金属盐的卡宾络合物及其用途

    公开(公告)号：US20110112304A1

    公开(公告)日：2011-05-12

    申请号：US12939063

    申请日：2010-11-03

    Applicant: John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Renuka N. Ganesh

    Inventor： John R. Hagadorn ,  Matthew W. Holtcamp ,  Matthew S. Bedoya ,  Renuka N. Ganesh

    IPC: C07F15/00 ,  C07D207/06 ,  C10G1/00

    CPC classification number: C07F15/0046 ,  C07D207/06 ,  C10G3/00 ,  C10G2300/1014 ,  C10G2300/1088 ,  C10G2400/20 ,  C10G2400/22 ,  Y02E50/13

    Abstract: This invention relates to a carbene complex of metal salt represented by the formula: [T−M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23° C. for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1−)s(L2−)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L° is a neutral ligand, L1− is a monoanionic ligand, L2− is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3, or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.

    Abstract translation: 本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。 本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是来自第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L°是中性配体，L1-是单阴离子配体 ，L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是整体 分子的电荷。 过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

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