公开(公告)号：US4371732A

公开(公告)日：1983-02-01

申请号：US297450

申请日：1981-08-28

申请人： Joe Van Pool

发明人： Joe Van Pool

IPC分类号： C07C9/16 ,  C07C2/58

CPC分类号： C07C9/16

摘要： An alkylation process comprising fractionating the hydrocarbon phase separated from the alkylation effluent into an overhead condensate comprising at least three portions wherein one portion is subjected to depropanization, another portion is used as reflux for the fractionating, and another portion is recycled to the alkylation.

摘要翻译： 烷基化方法包括将从烷基化流出物分离出的烃相分级成塔顶冷凝物，其包含至少三个部分，其中一部分进行去丙烷化，另一部分用作分馏的回流，另一部分被再循环至烷基化。

公开(公告)号：US4409420A

公开(公告)日：1983-10-11

申请号：US296948

申请日：1981-08-28

申请人： Joe Van Pool ,  Mack F. Potts

发明人： Joe Van Pool ,  Mack F. Potts

IPC分类号： B01J19/00 ,  C07C2/62 ,  C07C7/00 ,  B01D53/34

CPC分类号： C07C7/005 ,  B01J19/002 ,  C07C2/62 ,  B01J2219/0027

摘要： Hydrocarbon vapors containing HF, as from an HF alkylation refrigerated vent gas yield, the reactor settler, and the like are charged to a liquid knock-out drum to remove entrained liquid therefrom, the recovered liquid being pumped to storage in response to liquid level control on the knock-out drum. Recovered vapors are charged to a circulating aqueous caustic treater to yield HF-free vapors, as to a flare. The circulating caustic solution is indirectly heated in response to a preselected caustic solution temperature to prevent freezing. A high pressure rupture disc, upstream from the knock-out drum, affords a vapor relief safety by-pass of the treater. Dry gas, such as nitrogen or sweet, natural gas, continuously sweeps the relief line to maintain this line open and operable.

摘要翻译： 将含有HF的烃蒸汽，从HF烷基化冷冻通气气体产量，反应器沉淀器等装入液体分离鼓中以从中除去夹带的液体，回收的液体响应于液面控制被泵送至储存 在敲门鼓上。 将回收的蒸气加入到循环的苛性碱水处理器中，以产生无HF的蒸气。 响应于预选的苛性碱溶液温度间接加热循环的苛性碱溶液以防止冻结。 在脱离鼓的上游的高压破裂盘提供处理器的蒸汽消除安全旁路。 干燥气体，如氮气或甜天然气，连续扫除救生线，以保持线路畅通和可操作。

公开(公告)号：US4316998A

公开(公告)日：1982-02-23

申请号：US173304

申请日：1980-07-29

申请人： Joe Van Pool

发明人： Joe Van Pool

IPC分类号： C07C2/62 ,  C07C9/16 ,  C07C2/56 ,  C07C2/58 ,  C07C7/10

CPC分类号： C07C2/62 ,  C07C9/16 ,  C07C2527/1206

摘要： HF is removed from hydrocarbon streams, e.g., a propane liquid stream from HF alkylation by water washing, the wash stream being contacted with solid caustic to remove moisture therefrom. The used wash water containing HF is combines with aqueous caustic obtained from said contacting and the admixture is used to contact HF acid soluble oil to remove HF therefrom. The thus, used aqueous stream separated from this last contacting is reacted with a calcium compound to form insoluble calcium fluoride and a supernatant aqueous liquid containing regenerated caustic. The regenerated caustic is used to remove the sulfur compounds from the alkylation hydrocarbons feed.

摘要翻译： 从烃流中除去HF，例如通过水洗从HF烷基化的丙烷液体流，洗涤流与固体苛性碱接触以从中除去水分。 所用的含有HF的洗涤水与从所述接触获得的苛性碱水溶液结合，并且该混合物用于接触HF酸溶性油以从其中除去HF。 将由此最后接触分离出的所用含水流与钙化合物反应形成不溶性氟化钙和含有再生苛性碱的上清液含水液体。 再生的苛性碱用于从烷基化烃进料中除去硫化合物。

公开(公告)号：US4155877A

公开(公告)日：1979-05-22

申请号：US888809

申请日：1978-03-21

申请人： Joe Van Pool

发明人： Joe Van Pool

IPC分类号： B01J21/20 ,  B01J23/90 ,  B01J29/90 ,  B01J29/38 ,  C10G13/16

CPC分类号： B01J29/90 ,  B01J21/20 ,  B01J23/90

摘要： Catalyst regeneration process and apparatus wherein air introduced to a midsection of a downwardly-moving mass of catalyst particles is taken off at the top and at the bottom of said bed through provided outlets and a third outlet is provided at the bottom portion of the said bed adapted to be controlled responsive to change in the flows through the top outlet and first mentioned bottom outlet to maintain substantially constant the total upward and downward flows through said bed. In an embodiment in which coke laydown on a hydrocarbon treated catalyst is burned off flue gases flow upwardly and out from the bed, e.g., through a carbon monoxide or flue gas burning boiler while downwardly flowing flue gas is taken off through a pressure control outlet or opening on which suction is taken by a blower passing flue gases to a boiler, a third outlet also flow controlled is operated responsive to change in the desired upward and downward flows of the flue gases. The third outlet, in operation of the regeneration system, can be normally closed or partly opened so that a condition of no flow or some flow, respectively, can exist.

摘要翻译： 催化剂再生方法和装置，其中引入到向下移动的催化剂颗粒的中部的空气通过提供的出口在所述床的顶部和底部被排出，并且第三出口设置在所述床的底部 适于响应于通过顶部出口和首先提到的底部出口的流动的变化而被控制，以保持基本上恒定的上下流动通过所述床。 在碳氢化合物处理的催化剂上的焦炭沉积被燃烧的实施方案中，烟道气从床上向外流出，例如通过一氧化碳或烟道气燃烧锅炉，同时向下流动的烟气通过压力控制出口或 通过烟气将烟道送到锅炉的吸气被吸入，第三出口也被流动控制，响应于期望的烟气的向上和向下的流动的变化。 在再生系统运行中的第三出口可以是常闭或部分打开，从而可以分别存在无流动或一些流动的状态。

公开(公告)号：US4490563A

公开(公告)日：1984-12-25

申请号：US464819

申请日：1983-02-08

申请人： Joe Van Pool ,  Paul D. Hann

发明人： Joe Van Pool ,  Paul D. Hann

IPC分类号： C07C41/06 ,  C07C41/42 ,  C07C41/58

CPC分类号： C07C41/06 ,  C07C41/42

摘要： MTBE is recovered from an ether containing effluent by fractionation. When driers are not used on the hydrocarbon feed to MTBE manufacture, a separate water-methanol phase occurs in the fractionation overhead which is separately processed in a methanol fractionator and the water recovered is used to water wash the separated hydrocarbon phase from the overhead while methanol is recycled to MTBE and when driers are used on the hydrocarbon feed a separate methanol phase occurs in the fractionation overhead which can be recycled to MTBE manufacture and the hydrocarbon phase is directly passed to a drier preceding alkylation.

摘要翻译： 通过分馏从含醚流出物中回收MTBE。 当在MTBE制造的烃进料上不使用干燥器时，在分馏塔顶馏分中发生单独的水 - 甲醇相，其在甲醇分馏器中分开处理，并且回收的水用于从顶部水中洗涤分离的烃相，同时甲醇 被再循环到MT​​BE中，并且当在烃进料上使用干燥器时，在分馏塔顶馏出物中发生单独的甲醇相，其可以再循环到MT​​BE制备中，烃相直接进入烷基化前的干燥器。

公开(公告)号：US4123351A

公开(公告)日：1978-10-31

申请号：US824583

申请日：1977-08-15

申请人： Charles C. Chapman ,  Joe Van Pool

发明人： Charles C. Chapman ,  Joe Van Pool

IPC分类号： B01D53/14 ,  C07C7/148 ,  C10G19/073 ,  C10G17/00

CPC分类号： C07C7/1485 ,  B01D53/1412 ,  B01D53/1456 ,  C10G19/073 ,  Y10S208/01 ,  Y10S585/956

摘要： In the removal of HF from hydrocarbon streams by chemical reaction with solid potassium hydroxide, runaway temperatures and subsequent explosions can occur when excess HF is present in the hydrocarbon charged to the KOH treater. According to the invention, a control system and method are provided which regulate the flow of hydrocarbon charged to the KOH treater responsive to temperature changes within the system indicative of excessive amount of HF in the hydrocarbon stream, thereby preventing the treater temperature from exceeding a preselected maximum allowable value. Several embodiments are provided whereby temperature changes in the KOH treater or a differential temperature across an HF stripper are used as temperature sensing points to control flow of hydrocarbon to the KOH treater.

摘要翻译： 在通过与固体氢氧化钾的化学反应从烃流中除去HF时，当加入KOH处理器的烃中存在过量的HF时，可能发生失控的温度和随后的爆炸。 根据本发明，提供一种控制系统和方法，其控制响应于系统内温度变化的加入到KOH处理器中的烃的流动，表明烃流中的过量的HF，从而防止处理器温度超过预选 最大允许值。 提供了几个实施例，其中使用KOH处理器中的温度变化或HF汽提器上的差温作为温度感测点来控制烃向KOH处理器的流动。

公开(公告)号：US4111805A

公开(公告)日：1978-09-05

申请号：US714930

申请日：1976-08-16

申请人： Joe Van Pool ,  R. Neil Jackson

发明人： Joe Van Pool ,  R. Neil Jackson

IPC分类号： B01D17/02 ,  C01B17/033 ,  C02B1/02

CPC分类号： B01D17/0208 ,  C01B17/033

摘要： A method and apparatus for separating solvent from liquid sulfur. The invention entails introducing an emulsion of liquid sulfur and a solvent of lower specific gravity into a first zone of a separator segregating the emulsion behind a sloped baffle to allow breaking of the emulsion with the solvent rising above the sulfur to form a separate layer of liquid; restraining the liquid sulfur behind a second baffle having sufficient clearance from the floor of the vessel to allow sulfur to flow thereunder while forming a second zone of liquid behind this baffle in which a collecting chamber is arranged so that solvent flows from a separated upper layer of liquid over a trapout weir into the chamber to be removed; and downstream of the second baffle a restraining weir of sufficient height to maintain an operating level in the second zone allowing the overflow of solvent into the collecting chamber with liquid sulfur overflowing the restraining weir into a collection means.

公开(公告)号：US4513165A

公开(公告)日：1985-04-23

申请号：US620787

申请日：1984-06-15

申请人： Joe Van Pool

发明人： Joe Van Pool

IPC分类号： C07C2/62 ,  C07C9/16 ,  C07C2/58

CPC分类号： C07C2/62 ,  C07C9/16 ,  C07C2527/1206

摘要： A slip stream of system HF from HF alkylation is charged to propane stripping of the fractionation system to purify the HF for recycle to the alkylation. Bottoms yield from propane stripping is fractionated to separate propane from the acid soluble oil separated from the slip stream of HF.

摘要翻译： 将来自HF烷基化的系统HF的滑流装入丙烷汽提分馏系统以纯化HF以再循环至烷基化。 从丙烷汽提产生的底部产物被分馏以将丙烷从与HF的滑流分离的酸溶性油分离出来。

公开(公告)号：US4490572A

公开(公告)日：1984-12-25

申请号：US567036

申请日：1983-12-30

申请人： Joe Van Pool ,  Paul D. Hann

发明人： Joe Van Pool ,  Paul D. Hann

IPC分类号： C07C7/10 ,  C07C7/00 ,  C07C2/56

CPC分类号： C07C7/10

摘要： A method for removing organic fluorides from HF alkylation propane in which a stream of relatively pure liquid HF obtained by settling liquid HF from the liquefied hydrocarbon passed to the overhead accumulator common for both the depropanizing column and a hydrogen fluoride stripping column is intimately contacted with a stream of liquid hydrocarbon containing organic fluorides derived from condensing the mixed overhead vapor from a depropanizing column and overhead vapor from an HF stripping column in the process of separating products from a hydrogen fluoride alkylation. In preferred embodiments, the contacting takes place in the static mixer.

摘要翻译： 从HF烷基化丙烷中除去有机氟化物的方法，其中通过将来自液化烃的液体HF沉降到通过脱丙烷塔和氟化氢汽提塔共同的塔顶蓄能器获得的相对纯的液体HF的流与一个 在将产物从氟化氢烷基化分离的过程中，衍生自冷凝来自脱丙烷塔的混合塔顶蒸气和来自HF汽提塔的塔顶蒸气的液态含烃有机氟化物流。 在优选实施例中，接触发生在静态混合器中。

公开(公告)号：US4479018A

公开(公告)日：1984-10-23

申请号：US297461

申请日：1981-08-28

申请人： Joe Van Pool

发明人： Joe Van Pool

IPC分类号： C07C2/62 ,  C07C9/16 ,  C07C41/06

CPC分类号： C07C41/06 ,  C07C2/62 ,  C07C9/16 ,  C07C2527/1206

摘要： Introduction of undesirable materials through liquid containing vessels of an ether forming unit into an alkylation unit is prevented by pressurizing one or more of these liquid containing vessels of the ether forming unit with a gas which is compatible with both the ether forming reaction and the alkylation reaction and which has a boiling point to keep it in essentially the gas phase in the pressurized vessel and to keep it in the liquid or dissolved form in the overhead accumulator associated with the fractionator of the alkylation unit (if said gas is present in the accumulator at all).

摘要翻译： 通过将含有醚形成单元的容器的液体通过含有乙醚形成单元的容器引入到烷基化单元中来引入不期望的材料，通过用与醚形成反应和烷基化反应两者相容的气体对这些含醚形成单元的这些液体容器进行加压来防止 并且其具有沸点以将其保持在加压容器中基本上为气相，并将其保持在与烷基化单元的分馏器相关联的塔顶储存器中的液体或溶解形式（如果所述气体存在于储液器中 所有）。