公开(公告)号：US08609885B2

公开(公告)日：2013-12-17

申请号：US13880438

申请日：2011-10-19

Applicant: Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Bernard M. Malofsky

Inventor： Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Bernard M. Malofsky

IPC: C07C69/34

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e.g., improved cure speed, retention of cure speed, improved shelf-life and/or stability).

Abstract translation: 本发明提供使用Knovenagel合成反应化学合成丙二酸亚甲酯的改进方法。 本发明的方法通过显着减少或消除替代和/或有害副产物的形成，显着减少或消除不需要的丙二酸亚丙酯消耗，以及显着降低或消除丙二酸亚甲酯的降解来提供改进的亚甲基丙二酸酯。 这些优点导致亚甲基丙二酸酯，其在回收时具有更高的质量，更高的纯度，更高的产率并且具有总体改进的性能特征（例如，改进的固化速度，固化速度的保持，改善的保存期限和/或稳定性）。

公开(公告)号：US06452031B1

公开(公告)日：2002-09-17

申请号：US09997302

申请日：2001-11-21

Applicant: Daniel A. Gately ,  Jeffrey M. Sullivan ,  Karin A. Voll Barclay ,  Dawn A. Arkin

Inventor： Daniel A. Gately ,  Jeffrey M. Sullivan ,  Karin A. Voll Barclay ,  Dawn A. Arkin

IPC: C07F1700

CPC classification number: C07F17/00 ,  C07F7/003 ,  Y10S526/943

Abstract: Conversion of a ligand of titanium organometallic complex to a titanium bisalkoxy or a titanium dichloride is described.

Abstract translation: 描述了钛有机金属络合物的配位体转变为钛双链烷氧基或二氯化钛。

公开(公告)号：US6015916A

公开(公告)日：2000-01-18

申请号：US241446

申请日：1999-02-02

Applicant: Jeffrey M. Sullivan ,  Daniel Anthony Gately

Inventor： Jeffrey M. Sullivan ,  Daniel Anthony Gately

IPC: C07F7/10 ,  C07F7/28 ,  C07F17/00 ,  C08F4/64 ,  C08F10/00

CPC classification number: C07F17/00 ,  C08F10/00 ,  Y10S526/943

Abstract: A practical and scalable process for the synthesis of constrained geometry metallocene catalyst is described.

Abstract translation: 描述了用于合成约束几何金属茂催化剂的实用和可缩放的方法。

公开(公告)号：USRE36115E

公开(公告)日：1999-02-23

申请号：US800384

申请日：1997-02-14

Applicant: Jeffrey M. Sullivan

Inventor： Jeffrey M. Sullivan

IPC: C07F5/02 ,  C07D333/56

CPC classification number: C07F5/022

Abstract: A method for producing amine-boranes, specifically pyridine-borane which is highly stable and of good color is described.

Abstract translation: PCT No.PCT / US92 / 05141 Sec。 371日期1994年2月15日 102（e）1994年2月15日PCT 1992年6月18日提交PCT描述了高度稳定且色泽良好的胺 - 硼烷，特别是吡啶 - 硼烷的方法。

公开(公告)号：US06531619B1

公开(公告)日：2003-03-11

申请号：US10042002

申请日：2002-01-08

Applicant: Daniel A. Gately ,  Jeffrey M. Sullivan ,  Karin A. Voll Barclay ,  Dawn A. Arkin

Inventor： Daniel A. Gately ,  Jeffrey M. Sullivan ,  Karin A. Voll Barclay ,  Dawn A. Arkin

IPC: C07F1700

CPC classification number: B01J31/2295 ,  B01J2231/60 ,  B01J2231/70 ,  B01J2531/46 ,  C07F17/00 ,  Y10S526/943

Abstract: Cyclopentadienyl or indenyl titanium trichlorides are produced by converting a cyclopentadiene or an indene to a corresponding cyclopentadienyl or indenyl titanium trialkoxide which is treated with a halogenating agent to provide the desired cyclopentadienyl or indenyl titanium trichloride.

Abstract translation: 将环戊二烯基或茚基三氯化钛通过将环戊二烯或茚转化成相应的用卤化剂处理的环戊二烯基或茚基三烷氧基钛来提供所需的环戊二烯基或茚基三氯化钛来制备。

公开(公告)号：US06455719B1

公开(公告)日：2002-09-24

申请号：US09761151

申请日：2001-01-17

Applicant: Jeffrey M. Sullivan ,  Daniel A. Gately

Inventor： Jeffrey M. Sullivan ,  Daniel A. Gately

IPC: C07F1700

CPC classification number: C07F17/00 ,  Y10S526/943

Abstract: A novel constrained geometry titanium(II) diene complex and ligands of such complexes are described. The novel complex has an olefin polymerization activity substantially in excess of a defined activity standard characteristic of analogous prior art constrained geometry diene complexes. Methods for the synthesis of the novel, high-activity complexes are described.

公开(公告)号：US06444835B1

公开(公告)日：2002-09-03

申请号：US09880289

申请日：2001-06-13

Applicant: Jeffrey M. Sullivan

Inventor： Jeffrey M. Sullivan

IPC: C07F1700

CPC classification number: C07F7/003

Abstract: A method for producing a titanocene wherein a TiCl3 complex free from salts of metals other than titanium is reacted with a titanocene ligand.

Abstract translation: 一种制备二茂钛的方法，其中不含钛以外的金属的TiCl 3配合物与二茂钛配体反应。

公开(公告)号：US06307063B1

公开(公告)日：2001-10-23

申请号：US09784736

申请日：2001-02-15

Applicant: Jeffrey M. Sullivan

Inventor： Jeffrey M. Sullivan

IPC: C07F1700

CPC classification number: C07F7/003

Abstract: The reduction of a titanium tetrahalide with titanium in the presence of an ether which forms an adduct with titanium trihalide, wherein an adduct insoluble in said ether is produced.

Abstract translation: 在与三卤化钛形成加合物的醚存在下，用钛还原四卤化钛，其中产生不溶于所述醚的加合物。

公开(公告)号：US6124489A

公开(公告)日：2000-09-26

申请号：US382195

申请日：1999-08-23

Applicant: Jeffrey M. Sullivan ,  Roustam Gareyev

Inventor： Jeffrey M. Sullivan ,  Roustam Gareyev

IPC: C07F7/00 ,  C07F17/00

CPC classification number: C07F17/00

Abstract: Production of aryl cyclopentadienyl Group IVA metal dihalides by dehydrogenation of a substituted or unsubstituted bis-(cyclohexenylcyclopentadienyl) Group IVA metal dihalide is described.

Abstract translation: 描述了芳基环戊二烯基通过取代或未取代的双 - （环己烯基环戊二烯基）ⅣA族金属二卤化物脱氢制备IVA族金属二卤化物。

公开(公告)号：US20130281580A1

公开(公告)日：2013-10-24

申请号：US13880471

申请日：2011-10-19

Applicant: Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Michael C. Cockrem

Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Michael C. Cockrem

IPC: C08F122/14 ,  C08L35/02 ,  C08L47/00 ,  C08F136/20

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde optionally in the presence of an acidic or basic catalyst and optionally in the presence of an acidic or non-acidic solvent to form reaction complex. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

Abstract translation: 本发明提供一种制备亚甲基丙二酸单体的方法，其包括以下步骤：使丙二酸酯与甲醛源任选地在酸性或碱性催化剂存在下反应，并任选在酸性或非酸性溶剂存在下反应 形成反应复合物。 该反应任选地在诸如传热剂，传热表面，辐射源或激光的能量转移装置的存在或接触的情况下进行，使得反应复合物基本上蒸发以产生包含亚甲基丙二酸酯的气相 可以分离的单体。 本发明还提供了通过本发明方法制备的亚甲基丙二酸单体，以及由亚甲基丙二酸酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和聚合物 （如纤维，薄膜，薄片，医用聚合物，复合聚合物和表面活性剂）。