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1.Synthesis of bis (cyclopentadienyl) and bis (indenyl) ruthenium complexes 有权
Title translation: 双(环戊二烯基)和双(茚基)钌络合物的合成公开(公告)号:US06642402B2
公开(公告)日:2003-11-04
申请号:US10178014
申请日:2002-06-21
Applicant: Karin A. Voll Barclay , Jeffrey M. Sullivan , Dawn A. Arkin , Fredric R. Askham
Inventor: Karin A. Voll Barclay , Jeffrey M. Sullivan , Dawn A. Arkin , Fredric R. Askham
IPC: C07F1702
CPC classification number: C07F17/00
Abstract: A process for preparing a cyclopentadienyl or indenyl ruthenium complex by treatment of a cyclopentadienyl or indenyl compound with ruthenium trichloride dihydrate and magnesium powder in an alkanol at 10° C. to −30° C. is described.
Abstract translation: 描述了通过在10℃至-30℃下在链烷醇中处理环戊二烯基或茚基化合物与三氯化钌二水合物和镁粉末在链烷醇中制备环戊二烯基或茚基钌络合物的方法。
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公开(公告)号:US07834228B1
公开(公告)日:2010-11-16
申请号:US11424831
申请日:2006-06-16
Applicant: Karin A. Voll Barclay , Richard D. Crawford , Dawn A. Arkin , Daniel A. Gately
Inventor: Karin A. Voll Barclay , Richard D. Crawford , Dawn A. Arkin , Daniel A. Gately
CPC classification number: C07C1/326 , C07C2601/10 , C07C13/15
Abstract: Synthesis of mono-substituted alkylcyclopentadienes by mixing alkyl iodides with cyclopentadienyl magnesium chloride in tetrahydrofuran is described.
Abstract translation: 描述了通过将烷基碘与环戊二烯基氯化镁在四氢呋喃中混合来合成单取代的烷基环戊二烯。
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3.Conversion of cyclopentadienyl silyl amines to organometallic complexes comprising titanium bisalkoxy moiety or titanium dichloride moiety 有权
Title translation: 将环戊二烯基甲硅烷基胺转化为包含钛双烷氧基部分或二氯化钛部分的有机金属络合物公开(公告)号:US06590114B2
公开(公告)日:2003-07-08
申请号:US10045209
申请日:2001-11-09
Applicant: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
Inventor: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
IPC: C07F1700
CPC classification number: B01J31/1608 , B01J31/0212 , B01J31/1805 , B01J31/2208 , B01J31/2295 , B01J2531/0205 , B01J2531/46 , C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/6592
Abstract: Conversion of cyclopentadienyl or indenyl compounds to titanium organometallic complexes by treatment with titanium tetraalkoxides is described.
Abstract translation: 描述了通过用四烷氧基钛处理将环戊二烯基或茚基化合物转化成钛有机金属配合物。
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4.Preparation of titanium organometallic complexes comprising a titanium bisalkoxide or dihalide moiety 有权
Title translation: 包含双链烷氧基钛或二卤化物部分的钛有机金属络合物的制备公开(公告)号:US06452031B1
公开(公告)日:2002-09-17
申请号:US09997302
申请日:2001-11-21
Applicant: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
Inventor: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
IPC: C07F1700
CPC classification number: C07F17/00 , C07F7/003 , Y10S526/943
Abstract: Conversion of a ligand of titanium organometallic complex to a titanium bisalkoxy or a titanium dichloride is described.
Abstract translation: 描述了钛有机金属络合物的配位体转变为钛双链烷氧基或二氯化钛。
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5.Preparation of cyclopentadienyl or indenyl titanium trihalides 有权
Title translation: 环戊二烯基或茚基三卤化钛的制备公开(公告)号:US06531619B1
公开(公告)日:2003-03-11
申请号:US10042002
申请日:2002-01-08
Applicant: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
Inventor: Daniel A. Gately , Jeffrey M. Sullivan , Karin A. Voll Barclay , Dawn A. Arkin
IPC: C07F1700
CPC classification number: B01J31/2295 , B01J2231/60 , B01J2231/70 , B01J2531/46 , C07F17/00 , Y10S526/943
Abstract: Cyclopentadienyl or indenyl titanium trichlorides are produced by converting a cyclopentadiene or an indene to a corresponding cyclopentadienyl or indenyl titanium trialkoxide which is treated with a halogenating agent to provide the desired cyclopentadienyl or indenyl titanium trichloride.
Abstract translation: 将环戊二烯基或茚基三氯化钛通过将环戊二烯或茚转化成相应的用卤化剂处理的环戊二烯基或茚基三烷氧基钛来提供所需的环戊二烯基或茚基三氯化钛来制备。
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