公开(公告)号：US20050251932A1

公开(公告)日：2005-11-17

申请号：US10525300

申请日：2003-08-26

Applicant: Jean-Marie Adam ,  Taher Yousaf ,  Victor Eliu

Inventor： Jean-Marie Adam ,  Taher Yousaf ,  Victor Eliu

IPC: A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07C245/24 ,  C09B67/00 ,  C09B67/36 ,  C07C245/02 ,  C09B1/00

CPC classification number: A61K8/4966 ,  A61Q5/065 ,  C07C245/24 ,  C09B67/0079

Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.

Abstract translation: 描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在 至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团， 并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分， 不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应。

公开(公告)号：US07041143B2

公开(公告)日：2006-05-09

申请号：US10469619

申请日：2002-02-28

Applicant: Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling

Inventor： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling

IPC: A61K7/13 ,  D06P1/02

CPC classification number: C09B67/0079 ,  C07C245/24

Abstract: A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) a capped diazonium compound and b) a water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.

Abstract translation: 描述了多孔材料，特别是人发的着色方法，该方法包括以任何所需的顺序依次或同时施用着色的材料a）封端的重氮化合物和b）在条件下的水溶性偶联组分 使得最初不发生偶合，然后使存在于材料上的封端重氮化合物与偶联组分反应。

公开(公告)号：US20050166337A1

公开(公告)日：2005-08-04

申请号：US10505596

申请日：2003-02-18

Applicant: Jean-Marie Adam ,  Taher Yousaf ,  Beate Frohling

Inventor： Jean-Marie Adam ,  Taher Yousaf ,  Beate Frohling

IPC: A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61Q5/10 ,  A61K7/13 ,  C07C245/02

CPC classification number: A61K8/466 ,  A61K8/40 ,  A61K8/415 ,  A61Q5/10

Abstract: The present invention relates to a method of colouring keratin-containing fibres comprising applying at least one diazonium compound of formula Ia or Ib, wherein R1 to R5 are each independently of the others C1-C12alkyl, C5-C14aryl, C5-C8cycloalkyl, C6-C20aralkyl, C1-C12alkoxy or C1-C12alkylthio unsubstituted or substituted by one or more halogen atoms, nitro, cyano or alkoxy groups; or hydrogen, halogen, hydroxy, nitro, COOH, SO3H, CN, SCN, C1-C4alkylsulfonyl, phenylsulfonyl, benzylsulfonyl, di-C1-C4alkylaminosulfonyl, C1-C4alkylcarbonylamino, C1-C4alkoxysulfonyl or dihydroxy-C1-C4alkylaminosulfonyl and X− is o−, COO− or SO3−, and at least one coupling component, preferably a a water-soluble to the material to be coloured and causing them to react at a pH in the range of 8 to 12.

Abstract translation: 本发明涉及一种着色含角蛋白的纤维的方法，包括施用至少一种式Ia或Ib的重氮化合物，其中R 1至R 5各自独立地为 其它C 1 -C 12烷基，C 5 -C 14芳基，C 5 - C 1 -C 8环烷基，C 6 -C 20芳烷基，C 1 -C 3 - 未取代或被一个或多个卤素原子，硝基，氰基或烷氧基取代的C 1 -C 12烷氧基或C 1 -C 12烷硫基; 或氢，卤素，羟基，硝基，COOH，SO 3 H，CN，SCN，C 1 -C 4烷基磺酰基，苯基磺酰基，苄基磺酰基 ，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基羰基氨基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基， 烷基磺酰基或二羟基-C 1 -C 4烷基氨基磺酰基和X - 或至少一种偶联组分，优选为水溶性至（Ⅳ） 待着色的物质，使其在8〜12范围内的pH反应。

公开(公告)号：US20050003135A1

公开(公告)日：2005-01-06

申请号：US10495184

申请日：2002-11-05

Applicant: Beat Schmidhalter ,  Jean-Marie Adam ,  Leonhard Feiler ,  Urs Lehmann ,  Gerardus De Keyzer ,  Taher Yousaf

Inventor： Beat Schmidhalter ,  Jean-Marie Adam ,  Leonhard Feiler ,  Urs Lehmann ,  Gerardus De Keyzer ,  Taher Yousaf

IPC: G02B5/20 ,  B41M5/26 ,  C09B23/00 ,  C09B55/00 ,  C09B57/10 ,  C09B67/22 ,  C09B69/02 ,  C09B69/04 ,  C09D11/00 ,  C09D11/02 ,  G02B5/22 ,  G11B7/244 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/2472 ,  G11B7/2478 ,  G11B7/2492 ,  G11B7/253 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/254 ,  G11B7/257 ,  G11B7/26 ,  G11B7/24 ,  C09B69/00

CPC classification number: G11B7/2492 ,  C09B67/0033 ,  C09B69/02 ,  C09D11/037 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/2472 ,  G11B7/2478 ,  G11B7/248 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/254 ,  G11B2007/24612 ,  G11B2007/25706 ,  G11B2007/2571 ,  G11B2007/25713 ,  G11B2007/25715 ,  G11B2007/25716

Abstract: The present invention relates to compositions comprising at least one oxonol dye and at least one metal complex of formula (I-1) or (I-2), to recording media comprising the compositions and to use of the compositions in the production of optical recording media, colour filters and printing inks, wherein the substituents are as defined in the description. Use of the metal complexes of formula (I) results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow even in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.

Abstract translation: 本发明涉及包含至少一种氧杂菁染料和式（I-1）或（I-2）的至少一种金属络合物的组合物，其包含该组合物的记录介质以及该组合物在制备光学记录中的用途 介质，滤色器和印刷油墨，其中取代基如说明书中所定义。 令人惊奇的是，使用式（I）的金属配合物，结果是在固体状态下氧化腈染料聚集的比较弱的趋势，即使在固体状态下吸收曲线仍然有利地窄，结果是记录介质 具有高反射率以及高灵敏度和在所需光谱范围内良好的播放特性。

公开(公告)号：US07232467B2

公开(公告)日：2007-06-19

申请号：US10525300

申请日：2003-08-26

Applicant: Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

Inventor： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

IPC: A61K7/13

CPC classification number: A61K8/4966 ,  A61Q5/065 ,  C07C245/24 ,  C09B67/0079

Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component

Abstract translation: 描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在 至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团， 并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分， 不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应

公开(公告)号：US07192453B2

公开(公告)日：2007-03-20

申请号：US10492325

申请日：2002-10-08

Applicant: Jean-Marie Adam ,  Taher Yousaf

Inventor： Jean-Marie Adam ,  Taher Yousaf

IPC: A61K7/13

CPC classification number: A61K8/494 ,  A61K8/415 ,  A61Q5/065

Abstract: The present invention relates to a method of coloring keratin-containing fibres, especially human hair, in which method a compound of formula (I), wherein R is hydroxy or NHR1, R1 being hydrogen or C1–C4alkyl, and B is an aromatic or heterocyclic ring, is diazotised, and the resulting diazonium salt is applied at a pH of from 2 to 5 to the material being colored and then, by means of increasing the pH to from 7 to 12, is fixed on the material in the form of an oligomeric or polymeric colorant

Abstract translation: 本发明涉及一种着色含角蛋白的纤维，特别是人类头发的方法，其中式（I）化合物，其中R是羟基或NHR 1，R 1， / SUB>为氢或C 1 -C 4烷基，B为芳族或杂环，被重氮化，所得重氮盐的pH为 从2至5对被着色的材料，然后通过将pH升高至7至12，以低聚或聚合着色剂的形式固定在材料上

公开(公告)号：US07786313B2

公开(公告)日：2010-08-31

申请号：US12218904

申请日：2008-07-17

Applicant: Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Düggeli ,  Taher Yousaf ,  Gerardus De Keyzer

Inventor： Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Düggeli ,  Taher Yousaf ,  Gerardus De Keyzer

IPC: C07D487/04 ,  C09B67/22

CPC classification number: C09B67/0033 ,  C09B57/004

Abstract: The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.

Abstract translation: 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法，其中A1和A2各自独立地为芳族或杂芳族基团，琥珀酸酯与至少一种未取代的 或取代的芳族或杂芳族腈，该方法包括在至少一种下式化合物存在下进行反应其中A是芳族或杂芳族基，R 3是氢，卤素，甲基，甲氧基，-CF 3或-CN，R 4 C 1 -C 10烷基，C 6 -C 10芳基或C 6 -C 24芳烷基，X是-S-，-O-，-CR 5 R 5'-，-COO-，-CONR 5 - ，-SO- ，SO 2 - ，-SO 2 NR 5 - 或-NR 5 - 以及R 5和R 5'各自独立地为氢或直链或从C3向上任选支链的C 1 -C 30烷基，C 6 -C 10芳基或C 6 -C 24芳烷基， 这样的混合物在 有机材料和化妆品着色，以及新型二酮吡咯并吡咯颜料混合物。

公开(公告)号：US20080287689A1

公开(公告)日：2008-11-20

申请号：US12218904

申请日：2008-07-17

Applicant: Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Duggeli ,  Taher Yousaf ,  Gerardus De Keyzer

Inventor： Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Duggeli ,  Taher Yousaf ,  Gerardus De Keyzer

IPC: C07D487/04

CPC classification number: C09B67/0033 ,  C09B57/004

Abstract: The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.

Abstract translation: 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法，其中A 1和A 2各自独立地为另一个 芳族或杂芳族基团，通过琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应，该方法包括在至少一种下式的化合物存在下进行反应其中A是芳族或杂芳族基，R 3是氢，卤素，甲基，甲氧基，-CF 3或-CN，R 4是线性的，或者是C 1 -C 3 - 3个以上，任选支链C 1 -C 30烷基，C 6 -C 10芳基 或C 6 -C 24芳烷基，X是-S-，-O-，-CR 5 R 5， -COO - ， - CONR 5 - ， - SO - ，SO 2 - ， - SO 2 NR 2 - 5 - 或-NR 5 - 和R 5和R 5 - 各自独立地为另一个氢或直链或者从C 3向上，任选支链C 1 -C 30烷基， C 6 -C 12芳基或C 6 -C 24 - 芳烷基，使用这种混合物 在有机材料和化妆品的着色中，以及新型二酮吡咯并吡咯颜料混合物。

公开(公告)号：US07417154B2

公开(公告)日：2008-08-26

申请号：US10576703

申请日：2004-10-04

Applicant: Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Düggeli ,  Taher Yousaf ,  Gerardus De Keyzer

Inventor： Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Düggeli ,  Taher Yousaf ,  Gerardus De Keyzer

IPC: C07D487/04 ,  C09B67/22

CPC classification number: C09B67/0033 ,  C09B57/004

Abstract: The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures

Abstract translation: 本发明涉及一种制备包含至少两种结构不同的式（1）二酮吡咯并吡咯颜料的混合物的方法，其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团，通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应，该方法包括在至少一种式（2）的化合物存在下进行反应，其中A是 芳族或杂芳族基团，R 3是氢，卤素，甲基，甲氧基，-CF 3或-CN，R 4是直链或 ，C 3 - 从上至上，任选支链C 1 -C 3亚烷基，C 6 -C 10个芳基或C 6 -C 2 4芳烷基，X是-S-，-O-，-CR 5 R -COO - ， - CONR 5 - ， - SO - ，SO 2 - ， - SO 2 - ， - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基，C 6 -C 10芳基或C 6 -C 24芳烷基，至 在有机材料和化妆品的着色中使用这样的混合物，以及新型二酮吡咯并吡咯颜料混合物

公开(公告)号：US20070028807A1

公开(公告)日：2007-02-08

申请号：US10576703

申请日：2004-10-04

Applicant: Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Duggeli ,  Taher Yousaf ,  Gerardus De Keyzer

Inventor： Olof Wallquist ,  Roman Lenz ,  Leonhard Feiler ,  Mathias Duggeli ,  Taher Yousaf ,  Gerardus De Keyzer

IPC: C07D487/02 ,  C08K5/00

CPC classification number: C09B67/0033 ,  C09B57/004

Abstract: The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, -0-, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.

Abstract translation: 本发明涉及一种制备包含至少两种结构不同的式（1）二酮吡咯并吡咯颜料的混合物的方法，其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团，通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应，该方法包括在至少一种式（2）的化合物存在下进行反应，其中A是 芳族或杂芳族基团，R 3是氢，卤素，甲基，甲氧基，-CF 3或-CN，R 4是直链或 ，C 3 - 从上至上，任选支链C 1 -C 3亚烷基，C 6 -C 10个芳基或C 6 -C 12亚芳基，X是-S-，-O-，-CR 5 R -COO - ， - CONR 5 - ， - SO - ，SO 2 - ， - SO 2 - ， - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基，C 6 -C 10芳基或C 6 -C 24芳烷基，至 在有机材料和化妆品的着色中使用这种混合物，以及新型二酮吡咯并吡咯颜料混合物。