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1.发明申请公开(公告)号：US20190382550A1
公开(公告)日：2019-12-19
申请号：US16463755
申请日：2017-11-15
申请人： JSP Corporation
摘要： The present invention provides expanded beads of thermoplastic polyurethane, wherein the thermoplastic polyurethane constituting the expanded beads is an ether-based thermoplastic polyurethane, and a difference (T1−T2) between a melting peak temperature (T1) and a melting peak temperature (T2) is from 0 to 8° C., wherein the melting peak temperature (T1) is a melting peak temperature at the time of first heating in a DSC curve obtained by heating the expanded beads from 20° C. to 260° C. at a heating rate of 10° C./min, the melting peak temperature (T2) is a melting peak temperature at the time of second heating in a DSC curve obtained by cooling from 260° C. to 20° C. at a cooling rate of 10° C./min after the first heating and further heating again from 20° C. to 260° C. at a heating rate of 10° C./min, and the DSC curves are obtained by the heat flux differential scanning calorimetry in conformity with JIS K7121-1987. The expanded beads of thermoplastic polyurethane not only have excellent surface appearance and fusion bonding properties but also have a low shrinkage factor.
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2.发明申请公开(公告)号：US20180155518A1
公开(公告)日：2018-06-07
申请号：US15578608
申请日：2016-05-25
申请人： JSP Corporation
CPC分类号： C08J9/18 , B29C44/3461 , B29C44/445 , B29K2075/00 , B29K2101/12 , B29K2105/046 , B29K2995/0063 , B29K2995/007 , C08J9/228 , C08J9/232 , C08J2205/052 , C08J2300/22 , C08J2375/04 , C08L75/04
摘要： Provided are expanded beads capable of providing an expanded thermoplastic polyurethane beads molded article which is excellent in physical properties, such as compression characteristics, repulsion elasticity, etc., and an expanded thermoplastic polyurethane beads molded article. Expanded beads of thermoplastic polyurethane, wherein a Shore A hardness of the thermoplastic polyurethane is 85 or more; an average cell diameter of the expanded beads is 50 to 300 μm; and a closed cell ratio when bisecting the expanded thermoplastic polyurethane bead is 60% or more; and an expanded thermoplastic polyurethane beads molded article obtained through in-mold molding of the same are disclosed.
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公开(公告)号：US20220306827A1
公开(公告)日：2022-09-29
申请号：US17617521
申请日：2020-04-02
申请人： JSP CORPORATION
发明人： Nobumasa KOSHITA , Hajime OHTA , Shota TAKAGI
摘要： A modified expanded bead that includes an expanded bead which includes a specific base polymer (β) and a coating layer which includes a specific base polymer (α). The coating layer covers at least part of an outer surface of the expanded bead. The melting point Tα of the base polymer (α) and the melting point Tβ of the base polymer (β) satisfy a relationship of 0≤Tα−Tβ≤20. When the modified expanded bead is cut into two halves along a cutting plane to form two half portions and thereafter one of the two half portions is cut along planes perpendicular to the cutting plane to form ten small pieces, outermost pieces among the ten small pieces have a xylene-insoluble content (B) which is less than a xylene-insoluble content (A) in the half portion and the xylene-insoluble content (A) is 10-80% by mass.
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公开(公告)号：US20200032025A1
公开(公告)日：2020-01-30
申请号：US16491456
申请日：2018-03-01
申请人： JSP Corporation
摘要： The present invention relates to an expanded beads molded article, which is obtained through in-mold molding of expanded thermoplastic elastomer beads, has voids, and has a density of 150 to 300 kg/m3 and a voidage of 10 to 70% by volume.
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5.发明申请公开(公告)号：US20160009888A1
公开(公告)日：2016-01-14
申请号：US14791885
申请日：2015-07-06
申请人： JSP CORPORATION
CPC分类号： C08J9/18 , C08J9/0019 , C08J9/0061 , C08J9/0066 , C08J9/122 , C08J9/232 , C08J2201/026 , C08J2201/034 , C08J2203/06 , C08J2205/052 , C08J2323/06 , C08J2463/02 , C08J2471/12 , C08J2481/06
摘要： A method for producing cross-linked polyethylene resin expanded beads, including dispersing polyethylene resin particles containing a halogen-containing flame retardant in a dispersing medium in an autoclave, impregnating the dispersed resin particles with an organic peroxide and cross-linking the polyethylene resin therewith at a specific temperature range determined by the melting point of the polyethylene resin and by melting point or glass transition temperature of the flame retardant, impregnating the dispersed resin particles with a blowing agent, and then foaming and expanding the resulting cross-linked polyethylene-based resin particles.
摘要翻译： 一种生产交联聚乙烯树脂发泡珠的方法，包括将分散介质中含有含卤阻燃剂的聚乙烯树脂颗粒分散在高压釜中，用有机过氧化物浸渍分散的树脂颗粒，并将其与聚乙烯树脂交联 由聚乙烯树脂的熔点和阻燃剂的熔点或玻璃化转变温度确定的特定温度范围，用发泡剂浸渍分散的树脂颗粒，然后使所得的交联聚乙烯类树脂 粒子。
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公开(公告)号：US20210095091A1
公开(公告)日：2021-04-01
申请号：US16634637
申请日：2018-08-01
申请人： JSP Corporation
IPC分类号： C08J9/16
摘要： The present invention relates to expanded thermoplastic urethane-based elastomer beads including, as a base material, a thermoplastic urethane-based elastomer having a melting point Tm of 175° C. or higher and such a glass transition temperature Tg that a difference (Tm-Tg) between the melting point Tm and the glass transition temperature Tg is 200° C. or more.
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公开(公告)号：US20190153189A1
公开(公告)日：2019-05-23
申请号：US16313236
申请日：2017-05-12
申请人： JSP Corporation
摘要： An in-mold molded article of expanded thermoplastic polyurethane beads containing a colorant, wherein when an average surface cell wall thickness of the in-mold molded article is 20 μm or more, the expanded TPU beads molded article is high in uniformity of color and good in color developing properties. Expanded thermoplastic polyurethane beads containing a colorant, wherein when an apparent density of the expanded beads is 80 to 300 kg/m3, an average cell diameter of the expanded beads is 100 to 400 μm, and an average surface cell wall thickness of the expanded beads is 15 μm or more, a molded article resulting from in-mold molding of the expanded beads is suppressed in color unevenness and has high uniformity of color.
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公开(公告)号：US20190112444A1
公开(公告)日：2019-04-18
申请号：US16088713
申请日：2017-03-27
申请人： JSP Corporation
摘要： Provided are spherical expanded beads obtained through expansion of thermoplastic polyurethane beads, wherein a bead mass of the expanded beads is 3 to 12 mg, and a ratio of a long diameter to a short diameter of the expanded bead (long diameter/short diameter) is 1.5 or less; an apparent density of the expanded beads is 80 to 300 kg/m3; an average cell diameter Da of the expanded beads is 80 to 300 μm; and a closed cell ratio of the expanded beads is 80% or more.
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公开(公告)号：US20190100640A1
公开(公告)日：2019-04-04
申请号：US16088746
申请日：2017-02-03
申请人： JSP Corporation
摘要： The present invention is concerned with expanded beads of thermoplastic polyurethane in which a water-soluble anionic surfactant is attached at 50 mg/m2 to 1,000 mg/m2 onto the surfaces of expanded beads of thermoplastic polyurethane having a dispersant attached thereto; and a method for producing an expanded beads molded article, including filling the expanded beads of thermoplastic polyurethane in a mold for molding and heating with a water vapor to mutually fuse the expanded beads with each other. The present invention provides expanded beads from which an expanded TPU beads molded article having excellent tensile strength and a method for producing an expanded TPU beads molded article.
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公开(公告)号：US20180022886A1
公开(公告)日：2018-01-25
申请号：US15542261
申请日：2015-01-09
申请人： JSP Corporation
发明人： Masaharu OIKAWA , Nobumasa KOSHITA , Syouta TAKAGI
CPC分类号： C08J9/228 , C08J9/0061 , C08J9/122 , C08J9/16 , C08J9/22 , C08J9/232 , C08J2203/06 , C08J2323/16 , C08J2423/08 , C08J2423/16 , C08L23/16 , C08L2205/025
摘要： Provided is an expanded propylene resin bead including a core layer in a foamed state, which includes a propylene-based resin composition (a) satisfying the following (i) and (ii); and a cover layer which includes an olefin-based resin (b) satisfying the following (iii) or (iv): (i) the propylene-based resin composition (a) is a mixture of 65% by weight to 98% by weight of a propylene-based resin (a1) having a melting point of 145° C. to 165° C. and a flexural modulus of 1,200 MPa or more and 35% by weight to 2% by weight of a propylene-based resin (a2) having a melting point of 100° C. to 145° C. and a flexural modulus of 800 MPa to 1,200 MPa; (ii) a difference in a melting point between the resin (a1) and the resin (a2) is 5° C. to 25° C.; (iii) the olefin-based resin (b) is a crystalline olefin-based resin having a melting point (TmB) that is lower than a melting point (TmA) of the composition (a) and being in a relation of (0° C.
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