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公开(公告)号:US20210175494A1
公开(公告)日:2021-06-10
申请号:US17268233
申请日:2019-08-06
Inventor: Xuejie Huang , Hailong Yu , Yuanjie Zhan , Wenbin Qi , Wenwu Zhao
IPC: H01M4/36 , H01M4/58 , H01M4/62 , H01M4/66 , H01M4/136 , H01M10/0525 , H01M10/0562 , H01M50/434
Abstract: The present invention provides a sulfur-based positive electrode active material for use in a solid-state battery, comprising: 30-80 wt % of Li2S, 10-40 wt % of one or more second lithium compounds selected from LiI, LiBr, LiNO3, and LiNO2, and 0-30 wt % of a conductive carbon material; a method for preparing the sulfur-based positive electrode active material, a positive electrode including the sulfur-based positive electrode active material, and a solid-state battery including the positive electrode. The sulfur-based positive electrode active material and the positive electrode provide a high specific capacity and an increased discharge voltage.
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公开(公告)号:US11362327B2
公开(公告)日:2022-06-14
申请号:US16500070
申请日:2017-09-05
Inventor: Zhou Jin , Hailong Yu , Xuejie Huang
Abstract: This invention relates to a double layer composite-coated nano-silicon negative electrode material, and its preparation methods and use, the negative electrode material comprising: a silicon-based nanoparticle, a copper layer coated on the surface of the silicon-based nanoparticle, and a conductive protective layer coated on the surface of the copper layer. Nano-copper has superplastic ductility and conductivity, and the prior art has proved that lithium ions can penetrate nano-copper; therefore, the copper coating layer has effects of inhibiting the volume expansion of the silicon-based nanoparticle and keeping the silicon-based nanoparticle from cracking so that direct contact between the silicon-based nanoparticle and an electrolyte is effectively avoided and a stable SEI is formed, and increasing the conductivity of the electrode. The surface of the nano-copper is coated with a further conductive protective layer to effectively inhibit the oxidation of the nano-copper, thereby improving the electrochemical performance.
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公开(公告)号:US20230133537A1
公开(公告)日:2023-05-04
申请号:US17905857
申请日:2021-01-18
Inventor: Mengyu Tian , Wenbin Qi , Hailong Yu , Xuejie Huang
Abstract: Provided is a prelithiation material, comprising a lithium-containing compound and an inorganic non-metallic reductive agent. Further provided is a method for preparing the prelithiation material of the present invention. Further provided is use of the prelithiation material of the present invention in a lithium ion battery. By mixing the prelithiation material provided by the present invention with a positive electrode material or coating the side of a separator near the positive electrode with the same, a battery is assembled, and during first cycle, active lithium can be released so as to compensate active lithium lost from a negative electrode. The prelithiation material provided by the present invention has a good compatibility with currently commercially available positive and negative electrodes, and is very suitable for current secondary lithium ion batteries.
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公开(公告)号:US11362328B2
公开(公告)日:2022-06-14
申请号:US16631752
申请日:2018-09-29
Inventor: Zhou Jin , Hailong Yu , Xuejie Huang
IPC: H01M4/38 , H01M4/04 , H01M4/36 , H01M10/0525 , H01M4/02
Abstract: The invention provides a composite-coated nano-tin negative electrode material, which comprises a tin-based nanomaterial, a nano-copper layer coated on the surface of the tin-based nanomaterial and a conductive protective layer coated on the surface of the nano-copper layer. The nano-copper layer can inhibit the volume expansion of nano-tin, keep the nano-tin material from cracking, avoid direct contact between nano-tin and electrolyte to form stable SEI and increase the conductivity of the electrode. Coating a conductive layer on the surface of the nano-copper layer can effectively inhibit the oxidation of nano-copper, thus improving its electrochemical performance. The composite-coated nano-tin negative electrode material according to the invention is used as a negative electrode material of a lithium-ion battery, has excellent electrochemical performance, and has potential application prospects in portable mobile devices and electric vehicles.
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5.
公开(公告)号:US20200185711A1
公开(公告)日:2020-06-11
申请号:US16631752
申请日:2018-09-29
Inventor: Zhou Jin , Hailong Yu , Xuejie Huang
IPC: H01M4/38 , H01M10/0525 , H01M4/36 , H01M4/04
Abstract: The invention provides a composite-coated nano-tin negative electrode material, which comprises a tin-based nanomaterial, a nano-copper layer coated on the surface of the tin-based nanomaterial and a conductive protective layer coated on the surface of the nano-copper layer. The nano-copper layer can inhibit the volume expansion of nano-tin, keep the nano-tin material from cracking, avoid direct contact between nano-tin and electrolyte to form stable SRI and increase the conductivity of the electrode. Coating a conductive layer on the surface of the nano-copper layer can effectively inhibit the oxidation of nano-copper, thus improving its electrochemical performance. The composite-coated nano-tin negative electrode material according to the invention is used as a negative electrode material of a lithium-ion battery, has excellent electrochemical performance, and has potential application prospects in portable mobile devices and electric vehicles.
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