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公开(公告)号:US20180178411A1
公开(公告)日:2018-06-28
申请号:US15735286
申请日:2016-06-09
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: SangJun AHN , Wolfgang FISCHER , Norbert NIESSNER , Brian J. BANASZAK , Roland WALKER , Ula EL-JABY , Achim STAMMER , Klaus-Dieter HUNGENBERG , Bernd HISGEN
IPC: B29B7/74 , B29B7/60 , B29B7/32 , C08F267/08 , C08F257/02 , B01J19/24
CPC classification number: B29B7/7485 , B01J8/10 , B01J8/20 , B01J8/38 , B01J8/388 , B01J19/1837 , B01J19/1881 , B01J19/2465 , B29B7/12 , B29B7/24 , B29B7/325 , B29B7/60 , B29B7/7461 , B29B7/7466 , B29B7/7495 , B29K2055/02 , C08F257/02 , C08F267/08 , C08L25/12 , C08L55/02
Abstract: The invention relates to a process for the production of thermoplastic moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a loop conduit (29) which comprises a static mixer (36), wherein the reagents (11, 12) are pressed in loops through the loop conduit (29) and passing the static mixer (36), whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the static mixer (36). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.
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公开(公告)号:US20180085732A1
公开(公告)日:2018-03-29
申请号:US15564586
申请日:2016-04-11
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: SangJun AHN , Wolfgang FISCHER , Norbert NIESSNER , Brian J. BANASZAK , Roland WALKER , Ula EL-JABY , Achim STAMMER , Klaus-Dieter HUNGENBERG , Bernd HISGEN
CPC classification number: B01J19/1837 , B01J8/10 , B01J8/20 , B01J8/38 , B01J8/388 , B01J19/1881 , B29B7/12 , B29B7/24 , B29B7/48 , B29B7/60 , B29B7/7461 , B29B7/7485 , C08L53/00 , C08L55/02
Abstract: The invention relates to a process for the production of thermoplastic moulding compounds, in particular ABS, wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a gear pump (10) which comprises a housing and at least a first gear wheel that is rotatable relative to the housing about a first axis, and a second gear wheel that is rotatable relative to the housing about a second axis, wherein a loop conduit (29) is provided, and wherein the reagents (11, 12) are pressed in a loop through the loop conduit (29) and passing the gear wheels, whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the gear pump (10). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.
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公开(公告)号:US20180066117A1
公开(公告)日:2018-03-08
申请号:US15560312
申请日:2016-03-23
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Brian J. BANASZAK , Roland WALKER , Libor SEDA , Johannes BARTH , Gisbert MICHELS , Nikolaus NESTLE
CPC classification number: C08J3/24 , C08F2/26 , C08F2/38 , C08F279/04 , C08J2300/22 , C08L25/12 , C08L55/02 , G01R33/46 , C08F220/44 , C08F212/08
Abstract: A process produces a polymer composition (A) containing a styrene copolymer (a) and an impact modifier (b), comprising a copolymer (b1) as graft base and a graft (b2), where the steps of the process are: (1) providing a crosslinked copolymer (b1) made of: (b11) from 70 to 99.99% by weight of a conjugated diene or acrylate, (b12) from 0 to 29% by weight of another comonomer, (b13) from 0 to 10% by weight of crosslinking monomers, and (b14) from 0.01 to 0.7% by weight of a chain-transfer reagent; (2) applying, to the copolymer (b1), at least one graft (b2) comprising: (b21) from 65 to 95% by weight of a vinylaromatic monomer, (b22) from 5 to 35% by weight of acrylonitrile and/or methacrylonitrile, and (b23) from 0 to 30% by weight of monoethylenically unsaturated monomers, thus providing the impact modifier (b); (3) mixing the styrene copolymer (a) and the impact modifier (b), and thus leads to improved mechanical properties of the polymer composition (A).
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公开(公告)号:US20240368390A1
公开(公告)日:2024-11-07
申请号:US18557583
申请日:2022-04-28
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert NIESSNER , Wolfgang FISCHER , Brian J. BANASZAK , Roman HONEKER , Gisbert MICHELS , Rudy VERSTRAETEN , Jinhwa Andrew CHUNG , YoungHwa HWANG , SangJun AHN , Koen TAELMAN
IPC: C08L25/12 , B29B7/00 , B29B7/48 , B29B7/72 , B29B7/82 , B29B7/84 , B29B7/86 , B29B7/90 , B29B13/06 , B29K33/00 , B29K55/02 , B29K67/00 , B29K69/00 , B29K77/00 , B29K105/00 , B29K105/16 , B29K409/00 , C08J3/21
Abstract: The invention is directed to a process for producing a ABS composition comprising 30-80 wt.-% of copolymer A, 19.99-60 wt.-% of ABS-copolymer B, 0-40 wt.-% of polymer C and 0.01-20 wt.-% of additives D, having the steps: a) mixing the components A, B and D and optionally C, by using an extruder comprising: a first feeding zone FZ1, a preheating zone PZ, a mechanical dewatering zone DZ, in which component B is mechanically dewatered, and wherein: the mechanical dewatering zone DZ comprises at least one dewatering aperture, in particular for liquid water; in a second feeding zone FZ2, at least part of component A and optionally part of component D are fed, preferably in melt and/or solid form, to the ex-truder, in a degassing zone DG component A and/or component B are degassed, and b) removing the ABS molding composition from a discharge zone CZ of the extruder.
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公开(公告)号:US20180179315A1
公开(公告)日:2018-06-28
申请号:US15307122
申请日:2015-04-24
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Roland WALKER , Gisbert MICHELS , Brian J. BANASZAK
IPC: C08F279/02 , C08L25/12
CPC classification number: C08F279/02 , C08L25/12 , C08L55/02 , C08F212/08 , C08F220/44
Abstract: The present invention relates to a process for the production of styrene graft copolymers comprising addition and graft copolymerization of styrene monomers A1 and vinyl cyanide monomers A2 to a graft base B where the ratio by mass of A1 to A2 in the monomer feed at the end of the monomer feed time is lower than the ration by mass integrated over the entire monomer feed time. The present invention further relates to a graft copolymer obtainable by a process according to the invention, a molding composition comprising such a graft copolymer, and a molding obtained from such a molding composition.
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公开(公告)号:US20250002706A1
公开(公告)日:2025-01-02
申请号:US18708581
申请日:2022-11-10
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert NIESSNER , Wolfgang FISCHER , Brian J. BANASZAK , Roman HONEKER , Gisbert MICHELS , Rudy VERSTRAETEN , Andrew CHUNG , YoungHwa HWANG , SangJun AHN , Koen TAELMAN
IPC: C08L55/02 , C08F279/04 , C08J3/12 , C08J5/18 , C09D155/02
Abstract: The thermoplastic ABS molding composition comprises at least one thermoplastic copolymer matrix A, at least one ABS-copolymer B, optionally one or more polymers C, and one or more additives D, wherein, in the thermoplastic ABS molding composition, in particular after thermoplastic processing by extrusion, thermoforming and/or injection molding, the grafted rubber of component B is present in form of small particles.
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公开(公告)号:US20240218173A1
公开(公告)日:2024-07-04
申请号:US18557505
申请日:2022-04-28
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert NIESSNER , Wolfgang FISCHER , Brian J. BANASZAK , Roman HONEKER , Gisbert MICHELS , Rudy VERSTRAETEN , Jinhwa Andrew CHUNG , YoungHWA HWANG , Sangjun AHN , Koen TAELMAN
CPC classification number: C08L55/02 , B29C48/022 , B29C48/288 , B29C48/761 , B29C48/92 , C08L25/12 , B29C2948/92704 , B29K2025/08 , B29K2055/02 , C08L2205/025 , C08L2205/03
Abstract: The invention is directed to a process for producing a ABS composition comprising 30-80 wt.-% of copolymer matrix A, 19.99-60 wt.-% of ABS-copolymer B, 0-40 wt.-% of polymer C and 0.01-20 wt.-% of additives D, having the steps: a) mixing the components A, B and D and optionally C, by using an extruder comprising: a first feeding zone FZ1, a mechanical dewatering zone DZ, in which component B is mechanically dewatered, and wherein: the mechanical dewatering zone DZ comprises at least one dewatering aperture, in particular for liquid water, wherein the mechanical dewatering DZ zone comprises one or more elements made of a stainless steel material; in a second feeding zone FZ2, at least part of component A and optionally part of component D are fed, preferably in melt and/or solid form, to the extruder, in a degassing zone DG component A and/or component B are degassed, and b) removing the ABS molding composition from a discharge zone CZ of the extruder.
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公开(公告)号:US20180044443A1
公开(公告)日:2018-02-15
申请号:US15554268
申请日:2016-03-03
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Roland WALKER , Gisbert MICHELS , Brian J. BANASZAK , Norbert NIESSNER
IPC: C08F2/24 , C09D151/00 , C08L25/12 , C08L51/00 , C08F265/04 , C08F297/02
CPC classification number: C08F2/24 , C08F212/08 , C08F220/44 , C08F265/04 , C08F297/02 , C08L25/12 , C08L51/003 , C08L2207/53 , C09D151/003 , C08F220/56 , C08L83/04
Abstract: The invention relates to graft copolymers (B) composed of an agglomerated graft core (B1) and at least one graft shell (B2) and also to copolymers (C) having an agglomerating effect, a method for producing said graft copolymers (B), thermoplastic molding compositions and also the use of the thermoplastic molding compositions.
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公开(公告)号:US20160304652A1
公开(公告)日:2016-10-20
申请号:US15103669
申请日:2014-04-16
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert NIESSNER , SangJun AHN , Rudy VERSTRAETEN , Gisbert MICHELS , Florian PATCAS , YoungHwa HWANG , Brian J. BANASZAK , Roland WALKER , Michel PEPERS , Johannes BARTH
IPC: C08F279/04 , C08J5/00 , C08J5/18 , C08L25/12
CPC classification number: C08F279/04 , C08F2500/17 , C08F2800/20 , C08J5/00 , C08J5/18 , C08J2325/12 , C08L25/12 , C08L55/02 , C08L67/00 , C08L69/00 , C08L69/005 , C08L77/02 , C08L77/06 , C08L2201/02 , C08L2201/10 , C08L2203/30 , C08L2205/025 , C08L2205/035 , C08L2207/04 , C08F2/22
Abstract: The invention relates to thermoplastic ABS molding compositions comprising components A) and B): A) from 5 to 80% by weight of a graft polymer A) having bimodal particle size distribution made from, based on A), a1) from 40 to 90% by weight of graft base a1), obtainable by polymerization of, based on a1), a11) from 75.5 to 89.5% by weight of at least one conjugated diene, a12) from 10.5 to 24.5% by weight of at least one vinylaromatic monomer and a2) from 10 to 60% by weight of a graft a2) made from, based on a2), a21) from 65 to 95% by weight of at least one vinylaromatic monomer, a22) from 5 to 35% by weight of acrylonitrile, and a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, B) from 20 to 95% by weight of a thermoplastic polymer B) having a viscosity number VN of from 50 to 120 ml/g, made from, based on B), b1) from 69 to 81% by weight of at least one vinylaromatic monomer, b2) from 19 to 31% by weight of acrylonitrile, and b3) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer. The invention further relates to a process for the preparation of graft copolymer A and to the graft copolymer obtainable by said process.
Abstract translation: 本发明涉及包含组分A)和B)的热塑性ABS模塑组合物:A)5-80重量%的接枝聚合物A),其具有基于A),a1)40至90的双峰粒度分布 a11),通过基于a1),a11)75.5-89.5重量%的至少一种共轭二烯的聚合获得,a12)10.5-24.5重量%的至少一种乙烯基芳族单体 和a2)10至60重量%的基于a2)制备的接枝物a2),a21)65至95重量%的至少一种乙烯基芳族单体,a22)5至35重量%的丙烯腈 ,和a23)0至30重量%的至少一种其它单烯键式不饱和单体,B)20至95重量%的粘度为VN为50至120ml / g的热塑性聚合物B),制成 基于B),b1)69至81重量%的至少一种乙烯基芳族单体,b2)19至31重量%的丙烯腈,和b3)0至30 重量%的至少一种其它单烯属不饱和单体。 本发明还涉及制备接枝共聚物A的方法和可通过所述方法获得的接枝共聚物。
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