Separation of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone
    3.
    发明授权
    Separation of 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone 失效
    1,5-二硝基四氢呋喃和1,8-四氮杂环戊烷的分离

    公开(公告)号:US4053488A

    公开(公告)日:1977-10-11

    申请号:US723915

    申请日:1976-09-16

    CPC分类号: C07C225/34

    摘要: A process for separating 1,5-dinitroanthraquinone and 1,8-dinitroanthraquinone by heating a dinitroanthraquinone mixture, in a mixture of from 5 to 85 per cent by weight of N-methylpyrrolidone and from 95 to 15 per cent by weight of an organic liquid which boils at from 80.degree. to 210.degree. C and is miscible in all proportions with N-methylpyrrolidone, at from 60.degree. to 180.degree. C, and separating off the undissolved material, at the extraction temperature, after the solution equilibrium has been reached. The insoluble material contains more than 85 per cent by weight, and as a rule more than 90 per cent by weight, of 1,5-dinitroanthraquinone. From the extract, it is possible to isolate the dissolved 1,8-dinitroanthraquinone together with the dissolved 1,5-dinitroanthraquinone and any byproducts which may be present.