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    Water repellant curable aqueous compositions
    1.
    发明授权
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US07766975B2

    公开(公告)日：2010-08-03

    申请号：US11481144

    申请日：2006-07-05

    申请人： Guy Clamen ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  William C. Finch ,  Barry Weinstein

    IPC分类号： C11D3/00 ,  C08L31/00 ,  C03C25/10

    CPC分类号： D04H1/645 ,  C03C25/47 ,  C08F8/14 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/4234 ,  D04H1/4242 ,  D04H1/4258 ,  D04H1/4282 ,  D04H1/4334 ,  D04H1/435 ,  D04H1/587 ,  D04H1/64 ,  D21H13/40 ,  D21H17/38 ,  F16D69/02 ,  Y10T428/24994 ,  Y10T442/20 ,  C08F20/06

    摘要： The present invention provides water repellant curable compositions comprising (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof, (ii) one or more polyol comprising at least two hydroxyl groups, (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C5 to C30 alk(en)yl bis(2-hydroxyethyl)amide, C11 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C11 to C30 alk(en)yl bis(2-hydroxy-ethyl)amine, C11 to C30 alk(en)yl tris(2-hydroxyethyl)amine, C5 to C30 alk(en)yl monoglyceride, C5 to C30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof, and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The compositions provide concentrates dilutable with water to make thermosetting aqueous binder compositions for use in methods to treat or contact substrates chosen from a non-woven, woven and a composite, e.g. glass fiber substrates, followed by drying and curing.

    摘要翻译： 本发明提供防水可固化组合物，其包含（i）一种或多种包含至少两个羧酸基团，酸酐基团或其盐的多元酸，（ii）一种或多种包含至少两个羟基的多元醇，（iii）一种或多种 选自C5至C30烷基（烯）基2-羟基乙基（alk（en））酰胺，C 5至C 30烯（烯）基双（2-羟乙基）酰胺，C 11至C 30烯（烯）基 2-羟乙基（alk（en））胺，C 11至C 30烷基（烯）基双（2-羟基 - 乙基）胺，C 11至C 30烯（烯）基三（2-羟乙基）胺，C 5至C 30烷基 en）单酸甘油酯，三元多元醇的C 5 -C 30烯（en）基单羧酸酯及其混合物，和（iv）任选的一种或多种含磷促进剂，其中所述羧酸的当量数 酸基团，酸酐基团或其盐与所述羟基的当量的总数为1 / 0.01至1/3。 组合物提供可与水稀释的浓缩物以制备用于处理或接触选自无纺布，编织物和复合材料的基材的热固性水性粘合剂组合物，例如。 玻璃纤维基材，然后干燥和固化。

    Water repellant curable aqueous compositions
    2.
    发明授权
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US07579289B2

    公开(公告)日：2009-08-25

    申请号：US11496193

    申请日：2006-07-31

    申请人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    IPC分类号： B32B3/00 ,  D03D15/00 ,  C08G63/00 ,  B05D1/36 ,  B05D7/00

    CPC分类号： C08J7/08 ,  C08J7/04 ,  Y10T442/20 ,  Y10T442/2311 ,  Y10T442/2402 ,  Y10T442/30

    摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.

    摘要翻译： 根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三羟基多元醇的C5至C30烷基（en）基单羧酸酯，C5至C30烷基（烯）基胺（多）烷氧基化物，C5至C30烷基（en） （多）烷氧基化物，在烯（en）基胺基中含有醚或硫代基团的C 5 -C 30烷（烯）基胺（多）烷氧基化物，及其混合物。 组合物可用水稀释以制备热固性水性粘合剂组合物。 本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

    Water repellant curable aqueous compositions
    3.
    发明申请
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US20080009209A1

    公开(公告)日：2008-01-10

    申请号：US11496193

    申请日：2006-07-31

    申请人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    IPC分类号： B32B5/02

    CPC分类号： C08J7/08 ,  C08J7/04 ,  Y10T442/20 ,  Y10T442/2311 ,  Y10T442/2402 ,  Y10T442/30

    摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.

    摘要翻译： 根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三元多羟基化合物的C 5 -C 30酸（en）基单羧酸酯，C C 5 -C 30烷基（烯）烷基化物，C 5至C 30烷基（烯）基二胺 （烯）烷基化物，C 5 -C 30烷基（C 3）烷基（烯）烷（alk）（alk）（alk）（alk） 其中。 组合物可用水稀释以制备热固性水性粘合剂组合物。 本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

    Wood Adhesives Comprising Protein and Oxazoline Polymer or Resin
    9.
    发明申请
    Wood Adhesives Comprising Protein and Oxazoline Polymer or Resin 审中-公开
    木质粘合剂包括蛋白质和唑啉聚合物或树脂

    公开(公告)号：US20100069533A1

    公开(公告)日：2010-03-18

    申请号：US12583405

    申请日：2009-08-20

    申请人： Jean M. Brady ,  Stephen A. Crescimanno ,  William C. Finch ,  Roger S. C. Hsin ,  Xun Tang

    发明人： Jean M. Brady ,  Stephen A. Crescimanno ,  William C. Finch ,  Roger S. C. Hsin ,  Xun Tang

    IPC分类号： C09J197/02 ,  C09J189/00 ,  C09J197/00

    CPC分类号： C09J189/00 ,  C08L79/04 ,  C08L97/02 ,  C09J197/02 ,  C09J199/00 ,  C08L89/00

    摘要： The present invention provides wood adhesive binder compositions comprising a naturally occurring protein component, e.g. soy flour, and an oxazoline-functional group containing polymer or resin component, the two components in a solids weight ratio of from 60:40 to 98:2. As formulated, the compositions may comprise from 40 to 98 wt. % of the naturally occurring protein component, preferably, 50 wt. % or more. Preferably, the wood adhesive binder further comprises lignins or lignosulfonate. Where the wood adhesive binder compositions comprise lignins or lignosulfonates, they remain more fluid and workable at a higher pH such as, for example, 4.5 or more. Any of the compositions may be formulated with one or more in situ acid generator compound to insure more rapid cure on heating or pressing. The binder enables the provision of mechanically sound, low cost and biodegradable composites, such as, medium density fiberboard (MDF).

    摘要翻译： 本发明提供了包含天然存在的蛋白质组分的木粘合剂粘合剂组合物， 大豆粉和含恶唑啉官能团的聚合物或树脂组分，固体重量比为60:40至98:2的两种组分。 如所配制的，组合物可以包含40至98wt。 ％的天然存在的蛋白质组分，优选50重量％ ％ 或者更多。 优选地，木材粘合剂粘合剂还包含木质素或木质素磺酸盐。 在木材粘合剂粘合剂组合物包含木质素或木质素磺酸盐的情况下，它们保持更高的流动性并且在较高的pH例如4.5或更高的pH下可使用。 任何组合物可以用一种或多种原位酸发生剂化合物配制，以确保在加热或加压下更快速固化。 粘合剂能够提供机械声音，低成本和可生物降解的复合材料，例如中密度纤维板（MDF）。

    Powder compositions comprising beta-hydroxyalkyl amides from the ring-opening of acidic compounds
    10.
    发明申请
    Powder compositions comprising beta-hydroxyalkyl amides from the ring-opening of acidic compounds 审中-公开
    包含酸性化合物开环的β-羟基烷基酰胺的粉末组合物

    公开(公告)号：US20080114132A1

    公开(公告)日：2008-05-15

    申请号：US11975930

    申请日：2007-10-23

    申请人： Andrew T. Daly ,  William C. Finch ,  Gordon L. Tullos

    发明人： Andrew T. Daly ,  William C. Finch ,  Gordon L. Tullos

    IPC分类号： C08F20/00

    CPC分类号： C09D167/02 ,  C08K5/20

    摘要： The present invention provides powder compositions for making coatings or films comprising one or more film-forming polymer or resin and one or more β-hydroxyalkyl amide curing agent chosen from β-hydroxyalkyl amide curing agents made from the reaction of one or more lactone or lactide with one or more alkanolamine compound containing one or more β-aminoalcohol, oligomeric β-hydroxyalkyl amide curing agents made from the reaction of one or more mixture of aromatic anyhydride with aliphatic anhydride with one or more alkanolamine compound containing one or more β-aminoalcohol, mixtures thereof, and mixtures thereof with one or more tetrafunctional β-hydroxyalkyl amide curing agent. The present invention enables the reduction of defects in coatings and films, especially in the case of coatings and films 75 μm or thicker, and, further, provides coating powders that are less expensive than coating powders that are cured solely with tetrafunctional β-hydroxyalkyl amides.

    摘要翻译： 本发明提供用于制备包含一种或多种成膜聚合物或树脂的涂层或薄膜的粉末组合物和一种或多种β-羟基烷基酰胺固化剂，其选自由一种或多种内酯或丙交酯反应制备的β-羟基烷基酰胺固化剂 与一种或多种含有一种或多种β-氨基醇的链烷醇胺化合物，由一种或多种芳族任何酐与脂族酸酐与一种或多种含有一种或多种β-氨基醇的链烷醇胺化合物的反应制得的低聚β-羟基烷基酰胺固化剂， 其混合物，以及它们与一种或多种四官能β-羟基烷基酰胺固化剂的混合物。 本发明能够减少涂层和膜中的缺陷，特别是在75μm或更厚的涂层和膜的情况下，并且还提供比仅用四官能β-羟基烷基酰胺固化的涂层粉末便宜的涂层粉末 。