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    Water repellant curable aqueous compositions
    3.
    发明授权
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US07766975B2

    公开(公告)日：2010-08-03

    申请号：US11481144

    申请日：2006-07-05

    申请人： Guy Clamen ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  William C. Finch ,  Barry Weinstein

    IPC分类号： C11D3/00 ,  C08L31/00 ,  C03C25/10

    CPC分类号： D04H1/645 ,  C03C25/47 ,  C08F8/14 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/4234 ,  D04H1/4242 ,  D04H1/4258 ,  D04H1/4282 ,  D04H1/4334 ,  D04H1/435 ,  D04H1/587 ,  D04H1/64 ,  D21H13/40 ,  D21H17/38 ,  F16D69/02 ,  Y10T428/24994 ,  Y10T442/20 ,  C08F20/06

    摘要： The present invention provides water repellant curable compositions comprising (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof, (ii) one or more polyol comprising at least two hydroxyl groups, (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C5 to C30 alk(en)yl bis(2-hydroxyethyl)amide, C11 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C11 to C30 alk(en)yl bis(2-hydroxy-ethyl)amine, C11 to C30 alk(en)yl tris(2-hydroxyethyl)amine, C5 to C30 alk(en)yl monoglyceride, C5 to C30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof, and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The compositions provide concentrates dilutable with water to make thermosetting aqueous binder compositions for use in methods to treat or contact substrates chosen from a non-woven, woven and a composite, e.g. glass fiber substrates, followed by drying and curing.

    摘要翻译： 本发明提供防水可固化组合物，其包含（i）一种或多种包含至少两个羧酸基团，酸酐基团或其盐的多元酸，（ii）一种或多种包含至少两个羟基的多元醇，（iii）一种或多种 选自C5至C30烷基（烯）基2-羟基乙基（alk（en））酰胺，C 5至C 30烯（烯）基双（2-羟乙基）酰胺，C 11至C 30烯（烯）基 2-羟乙基（alk（en））胺，C 11至C 30烷基（烯）基双（2-羟基 - 乙基）胺，C 11至C 30烯（烯）基三（2-羟乙基）胺，C 5至C 30烷基 en）单酸甘油酯，三元多元醇的C 5 -C 30烯（en）基单羧酸酯及其混合物，和（iv）任选的一种或多种含磷促进剂，其中所述羧酸的当量数 酸基团，酸酐基团或其盐与所述羟基的当量的总数为1 / 0.01至1/3。 组合物提供可与水稀释的浓缩物以制备用于处理或接触选自无纺布，编织物和复合材料的基材的热固性水性粘合剂组合物，例如。 玻璃纤维基材，然后干燥和固化。

    Water repellant curable aqueous compositions
    5.
    发明授权
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US07579289B2

    公开(公告)日：2009-08-25

    申请号：US11496193

    申请日：2006-07-31

    申请人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    IPC分类号： B32B3/00 ,  D03D15/00 ,  C08G63/00 ,  B05D1/36 ,  B05D7/00

    CPC分类号： C08J7/08 ,  C08J7/04 ,  Y10T442/20 ,  Y10T442/2311 ,  Y10T442/2402 ,  Y10T442/30

    摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.

    摘要翻译： 根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三羟基多元醇的C5至C30烷基（en）基单羧酸酯，C5至C30烷基（烯）基胺（多）烷氧基化物，C5至C30烷基（en） （多）烷氧基化物，在烯（en）基胺基中含有醚或硫代基团的C 5 -C 30烷（烯）基胺（多）烷氧基化物，及其混合物。 组合物可用水稀释以制备热固性水性粘合剂组合物。 本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

    Water repellant curable aqueous compositions
    6.
    发明申请
    Water repellant curable aqueous compositions 有权
    防水固化水性组合物

    公开(公告)号：US20080009209A1

    公开(公告)日：2008-01-10

    申请号：US11496193

    申请日：2006-07-31

    申请人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    发明人： Guy Clamen ,  Nolwenn Colmou ,  William C. Finch ,  Barry Weinstein

    IPC分类号： B32B5/02

    CPC分类号： C08J7/08 ,  C08J7/04 ,  Y10T442/20 ,  Y10T442/2311 ,  Y10T442/2402 ,  Y10T442/30

    摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.

    摘要翻译： 根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三元多羟基化合物的C 5 -C 30酸（en）基单羧酸酯，C C 5 -C 30烷基（烯）烷基化物，C 5至C 30烷基（烯）基二胺 （烯）烷基化物，C 5 -C 30烷基（C 3）烷基（烯）烷（alk）（alk）（alk）（alk） 其中。 组合物可用水稀释以制备热固性水性粘合剂组合物。 本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

    Stable reactive thermosetting formulations of reducing sugars and amines
    8.
    发明授权
    Stable reactive thermosetting formulations of reducing sugars and amines 有权
    稳定的还原糖和胺的反应性热固性配方

    公开(公告)号：US08747953B2

    公开(公告)日：2014-06-10

    申请号：US13305776

    申请日：2011-11-29

    申请人： William Christopher Finch ,  Charles James Rand ,  C. Damien Rodowski ,  Barry Weinstein ,  Drew Elliot Williams

    发明人： William Christopher Finch ,  Charles James Rand ,  C. Damien Rodowski ,  Barry Weinstein ,  Drew Elliot Williams

    IPC分类号： B05D3/10 ,  C09J179/02

    CPC分类号： C08L79/02 ,  C08J5/24 ,  C08J2379/02

    摘要： The present invention provides stable aqueous thermosetting binder compositions having a total solids content of 15 wt. % or higher, preferably, 20 wt. % or higher, and having extended shelf life comprising one or more reducing sugar, one or more primary amine compound, and one or more stabilizer acid or salt having a pKa of 8.5 or less. The total amount of stabilizer used may range from 5 to 200 mole %, based on the total moles of primary amine present in the binder. The stabilizer may be an organic stabilizer chosen from a monocarboxylic acid, a dicarboxylic acid, a fatty acid, an acid functional fatty acid ester, an acid functional fatty acid ether, or an inorganic stabilizer chosen from a mineral acid, a mineral acid amine or ammonia salt, and a Lewis acid, and mixtures thereof. The compositions can be used to provide binders for substrate materials including, for example, glass fiber.

    摘要翻译： 本发明提供了固体含量为15wt。％的稳定的水性热固性粘合剂组合物。 ％以上，优选20重量％ ％或更高，并且具有延长的保质期，其包含一种或多种还原糖，一种或多种伯胺化合物和一种或多种pKa为8.5或更低的稳定剂酸或盐。 基于存在于粘合剂中的伯胺的总摩尔数，所使用的稳定剂的总量可以为5-200摩尔％。 稳定剂可以是选自单羧酸，二羧酸，脂肪酸，酸官能脂肪酸酯，酸官能脂肪酸醚或选自无机酸，无机酸胺或无机酸的无机稳定剂的有机稳定剂， 氨盐和路易斯酸，以及它们的混合物。 组合物可用于提供用于基材的粘合剂，包括例如玻璃纤维。

    STABLE REACTIVE THERMOSETTING FORMULATIONS OF REDUCING SUGARS AND AMINES
    10.
    发明申请
    STABLE REACTIVE THERMOSETTING FORMULATIONS OF REDUCING SUGARS AND AMINES 有权
    降低糖和淀粉的稳定的反应性热稳定剂

    公开(公告)号：US20120135152A1

    公开(公告)日：2012-05-31

    申请号：US13305776

    申请日：2011-11-29

    申请人： William Christopher Finch ,  Charles James Rand ,  Charles Damien Rodowski ,  Barry Weinstein ,  Drew Elliot Williams

    发明人： William Christopher Finch ,  Charles James Rand ,  Charles Damien Rodowski ,  Barry Weinstein ,  Drew Elliot Williams

    IPC分类号： B05D3/10 ,  C09J179/02

    CPC分类号： C08L79/02 ,  C08J5/24 ,  C08J2379/02

    摘要： The present invention provides stable aqueous thermosetting binder compositions having a total solids content of 15 wt. % or higher, preferably, 20 wt. % or higher, and having extended shelf life comprising one or more reducing sugar, one or more primary amine compound, and one or more stabilizer acid or salt having a pKa of 8.5 or less. The total amount of stabilizer used may range from 5 to 200 mole %, based on the total moles of primary amine present in the binder. The stabilizer may be an organic stabilizer chosen from a monocarboxylic acid, a dicarboxylic acid, a fatty acid, an acid functional fatty acid ester, an acid functional fatty acid ether, or an inorganic stabilizer chosen from a mineral acid, a mineral acid amine or ammonia salt, and a Lewis acid, and mixtures thereof. The compositions can be used to provide binders for substrate materials including, for example, glass fiber.

    摘要翻译： 本发明提供了固体含量为15wt。％的稳定的水性热固性粘合剂组合物。 ％以上，优选20重量％ ％或更高，并且具有延长的保质期，其包含一种或多种还原糖，一种或多种伯胺化合物和一种或多种pKa为8.5或更低的稳定剂酸或盐。 基于存在于粘合剂中的伯胺的总摩尔数，所使用的稳定剂的总量可以为5-200摩尔％。 稳定剂可以是选自单羧酸，二羧酸，脂肪酸，酸官能脂肪酸酯，酸官能脂肪酸醚或选自无机酸，无机酸胺或无机酸的无机稳定剂的有机稳定剂， 氨盐和路易斯酸，以及它们的混合物。 组合物可用于提供用于基材的粘合剂，包括例如玻璃纤维。