MEMBRANE STRUCTURES SUITABLE FOR GAS SEPARATION, AND RELATED PROCESSES
    1.
    发明申请
    MEMBRANE STRUCTURES SUITABLE FOR GAS SEPARATION, AND RELATED PROCESSES 审中-公开
    适用于气体分离的膜结构及相关工艺

    公开(公告)号:US20130022510A1

    公开(公告)日:2013-01-24

    申请号:US13630807

    申请日:2012-09-28

    Abstract: A method for fabricating a high-density zeolite membrane structure is described. The method includes the step of combining (i) a mineral zeolite material; (ii) at least one cement precursor; and (iii) an organic binder, with an aqueous component, to form an aqueous composite zeolite composition. The zeolite composition is then applied on a surface of a scaffold formed from a porous, metal oxide material. The zeolite composition is dried, and then heated under conditions to form a metal oxide-zeolite composite layer. This layer is exposed to a phosphate composition, under conditions sufficient to reduce the porosity to a level no greater than about 10%. A high-density zeolite cement composite membrane structure results. Related methods for separating hydrogen from a fluid stream, using the membrane structure, are also disclosed.

    Abstract translation: 描述了一种制造高密度沸石膜结构的方法。 该方法包括以下步骤:(i)矿物沸石材料; (ii)至少一种水泥前体; 和(iii)具有水性组分的有机粘合剂,以形成水性复合沸石组合物。 然后将沸石组合物施加在由多孔金属氧化物材料形成的支架的表面上。 将沸石组合物干燥,然后在条件下加热以形成金属氧化物 - 沸石复合层。 在足以将孔隙率降低到不超过约10%的水平的条件下,将该层暴露于磷酸盐组合物。 高密度沸石水泥复合膜结构的结果。 还公开了使用膜结构从流体流分离氢的相关方法。

    METHODS AND SYSTEMS FOR AMMONIA PRODUCTION
    6.
    发明申请
    METHODS AND SYSTEMS FOR AMMONIA PRODUCTION 审中-公开
    氨基酸生产的方法和系统

    公开(公告)号:US20140120023A1

    公开(公告)日:2014-05-01

    申请号:US13665370

    申请日:2012-10-31

    Abstract: A method for ammonia synthesis using a water-gas shift membrane reactor (WGSMR) is presented. The method includes carrying out a water-gas shift reaction in the WGSMR to form a first product stream and a carbon dioxide (CO2) stream, wherein the first product stream includes nitrogen (N2) and hydrogen (H2), and a molar ratio of H2 to N2 in the first product stream is about 3. The method further includes separating at least a portion of the residual CO2 in the first product stream in a CO2 separation unit to form a second product stream, and separating at least a portion of the residual CO2 and carbon monoxide (CO) in the second product stream in a methanator unit to form a third product stream. The method further includes generating an ammonia stream from the third product stream in an ammonia synthesis unit. A system for ammonia synthesis is also presented.

    Abstract translation: 提出了一种使用水煤气变换膜反应器(WGSMR)进行氨合成的方法。 该方法包括在WGSMR中进行水煤气变换反应以形成第一产物流和二氧化碳(CO 2)流,其中第一产物流包括氮(N 2)和氢(H 2),摩尔比 第一产物流中的H 2至N 2为约3.该方法还包括在CO 2分离单元中分离第一产物流中的残余CO 2的至少一部分以形成第二产物流,并将至少一部分 在甲烷化器单元中的第二产物流中的残余CO 2和一氧化碳(CO),以形成第三产物流。 该方法还包括在氨合成单元中从第三产物流产生氨流。 还提出了一种氨合成系统。

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