公开(公告)号：US4693844A

公开(公告)日：1987-09-15

申请号：US801098

申请日：1985-11-22

申请人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07C33/05 ,  A61K8/34 ,  A61Q13/00 ,  C07C27/00 ,  C07C33/12 ,  C07C45/50 ,  C07C67/00 ,  C11B9/00 ,  A61K7/46 ,  C07C35/22

CPC分类号： C11B9/0046 ,  C07C33/12 ,  C07C45/50

摘要： A vinylnorbornyl alcohol of 5- or 6-vinyl-2-hydroxymethylbicyclo[2.2.1]heptane which is represented by the following structural formula: ##STR1## The compound has particular fragrance of a mint-like note partaking of camphor tone.

摘要翻译： 由以下结构式表示的5-或6-乙烯基-2-羟甲基双环[2.2.1]庚烷的乙烯基降冰片醇：该化合物具有特别的分散樟脑色调的薄荷状香料的香味。

公开(公告)号：US3948966A

公开(公告)日：1976-04-06

申请号：US514100

申请日：1974-10-11

申请人： Yoshiaki Inamoto ,  Hisao Kitano ,  Yoshiaki Tanaka ,  Fumio Tanimoto ,  Atsushi Nishibata ,  Susumu Handa

发明人： Yoshiaki Inamoto ,  Hisao Kitano ,  Yoshiaki Tanaka ,  Fumio Tanimoto ,  Atsushi Nishibata ,  Susumu Handa

IPC分类号： C07B61/00 ,  B01J31/00 ,  C07C67/00 ,  C07C241/00 ,  C07C263/02 ,  C07C265/00 ,  C07C265/08 ,  C07D251/34 ,  C07C118/00

CPC分类号： C07C263/02

摘要： A process for preparing benzene derivatives having an isocyanatomethyl group by reacting a benzene derivative having a chloromethyl group with sodium cyanate in dimethylformamide at 60.degree. to 160.degree.C., in the presence of a catalytic amount of an acidic metal chloride-dimethylformamide compound, made present in the reaction mixture from the start of the reaction by being dissolved in the starting reaction mixture.

摘要翻译： 在催化量的酸性金属氯化物 - 二甲基甲酰胺化合物的存在下，在60〜160℃下，使具有氯甲基的苯衍生物与氰酸钠在二甲基甲酰胺中反应制备具有异氰酸甲酯基的苯衍生物的方法， 通过溶解在起始反应混合物中而从反应开始就存在于反应混合物中。

公开(公告)号：US4331569A

公开(公告)日：1982-05-25

申请号：US220528

申请日：1980-12-29

申请人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07C29/09 ,  C07C29/48 ,  C07C45/29 ,  C07C49/653 ,  C07D317/72 ,  C07D319/08 ,  C11B9/00 ,  A61K7/46 ,  C07D317/10 ,  C07D319/04

CPC分类号： C07D317/72 ,  C07C29/095 ,  C07C29/48 ,  C07C45/292 ,  C07C49/653 ,  C07D319/08 ,  C11B9/0088 ,  C07C2102/42

摘要： The substituted norbornanones represented by general formula (I): ##STR1## (wherein R.sub.1 is an alkenyl group having 2 or 3 carbon atoms or an alkylidene group having 1 to 3 carbon atoms and R.sub.2 is a saturated hydrocarbon group having 2 to 7 carbon atoms with the dotted line between the two carbon atoms indicating a single bond when R.sub.1 is an alkenyl group and a double bond when R.sub.1 is an alkylidene group) are useful for perfume compositions. The substituted norbornanones represented by the general formula (I) may be prepared from the corresponding alkenyl or alkylidene norbornanones with diols in the presence of an acid catalyst.

摘要翻译： 由通式（I）表示的取代的降冰片烯酮：其中R1是具有2或3个碳原子的烯基或具有1至3个碳原子的亚烷基，R2是饱和烃基，其具有2至 7个碳原子，两个碳原子之间的虚线表示当R1为烯基时为单键，当R 1为亚烷基时为双键）可用于香料组合物。 由通式（I）表示的取代的降冰片烯酮可以在酸催化剂存在下由相应的烯基或亚烷基降冰片烷酮与二醇制备。

公开(公告)号：US4266055A

公开(公告)日：1981-05-05

申请号：US147522

申请日：1980-05-07

申请人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07D251/34

CPC分类号： C07D251/34

摘要： Disclosed in this invention are a novel compound tris(3-acetylthiopropyl)isocyanurate which can serve as an intermediate for the preparation of tris(3-mercaptopropyl)isocyanurate useful as a polymerization reaction regulator, crosslinking agent, curing agent, lubricant adjunct, etc., and a process for preparing the said compound, as well as a process for preparing tris(3-mercaptopropyl)isocyanurate using the said compound as an intermediate.

摘要翻译： 本发明公开了一种可用作制备用作聚合反应调节剂，交联剂，固化剂，润滑剂助剂等的三（3-巯基丙基）异氰脲酸酯的中间体的新型化合物三（3-乙酰基硫代丙基）异氰脲酸酯。 ，以及制备所述化合物的方法，以及使用所述化合物作为中间体制备三（3-巯基丙基）异氰脲酸酯的方法。

公开(公告)号：US4731475A

公开(公告)日：1988-03-15

申请号：US43323

申请日：1987-04-28

申请人： Fumio Tanimoto ,  Hisao Kitano

发明人： Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07C65/03 ,  B01J23/00 ,  B01J23/72 ,  C07B61/00 ,  C07C51/00 ,  C07C51/093 ,  C07C67/00 ,  C07C65/01

CPC分类号： C07C51/00 ,  C07C51/093

摘要： The present invention provides a method for preparing solid p-disodium hydroxybenzoate which is characterized by comprising the steps of reacting phenol, carbon tetrachloride in an amount of 0.9 to 1.2 moles per mole of phenol and sodium hydroxide in an amount of 7 to 20 moles per mole of phenol prior to the reaction in an aqueous liquid containing 10 to 40% by weight of p-disodium hydroxybenzoate and/or sodium chloride in the presence of a transition metal powder in an amount of 0.01 to 1.00% by weight based on the weight of a reaction system at a reaction temperature of 50.degree. to 150.degree. C.; cooling the resulting reaction mixture to a level of -20.degree. to +20.degree. C.; and separating said p-disodium hydroxybenzoate therefrom.

公开(公告)号：US4341665A

公开(公告)日：1982-07-27

申请号：US240953

申请日：1981-03-05

申请人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Yoshiharu Inoue ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07D317/72 ,  C07D319/08 ,  C07D321/00 ,  C11B9/00 ,  C07D319/04

CPC分类号： C07D317/72 ,  C07D319/08 ,  C07D321/00 ,  C11B9/0088

摘要： An acylnorbornanone acetal is represented by the formula: ##STR1## (wherein R.sub.1 is a saturated hydrocarbon group having 2 to 7 carbon atoms and R.sub.2 is a hydrogen atom or a hydrocabon group having 1 to 10 carbon atoms). The acylnorbornanone acetal is prepared by oxidizing an .alpha.-hydroxyalkylnorbornanone acetal represented by the formula: ##STR2## (wherein R.sub.2 is a hydrogen atom or a hydrocarbon group having 2 to 7 carbon atoms). The perfume composition contains as a perfume component the acylnorbornanone acetal as represented above.

摘要翻译： 酰基降冰片酮缩醛由下式表示：其中R1为碳原子数2〜7的饱和烃基，R2为氢原子或碳原子数为1〜10的氢可卡波基。 通过氧化由下式表示的α-羟基烷基降冰片酮缩醛（其中R 2是氢原子或具有2至7个碳原子的烃基）来制备酰基降冰片酮缩醛。 香料组合物含有如上所述的酰基降冰片酮缩醛作为香料组分。

公开(公告)号：US4056547A

公开(公告)日：1977-11-01

申请号：US726205

申请日：1976-09-24

申请人： Yoshiaki Tanaka ,  Susumu Handa ,  Atsushi Nishibata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Masahiro Saito ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Yoshiaki Tanaka ,  Susumu Handa ,  Atsushi Nishibata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Masahiro Saito ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/28 ,  C07C67/00 ,  C07C241/00 ,  C07C263/02 ,  C07C265/00 ,  C07C265/08 ,  C07C118/00

CPC分类号： C07C263/00

摘要： A process for preparing organic isocyanate compounds characterized by reacting a chloromethyl group-containing compound having the formula:(X).sub.n RCH.sub.2 Clwherein X, which can be the same or different, is chlorine, alkyl, cycloalkyl, alkenyl, phenyl, chloromethylphenyl or chloromethyl, n is 0 or an integer of 1 to 3, and R is an aromatic hydrocarbon radical or an olefin radical,With an alkali cyanate, in the presence of a catalyst composition comprising (a) a cuprous salt in an amount of 0.1 to 20% by weight, based on said chloromethyl group-containing compound, and (b) a tertiary amine compound or quaternary ammonium compound in an amount equivalent to 0.05 to 1.25 gram atoms of nitrogen per gram mole of said cuprous salt, in a high-boiling-point solvent having a dieelectric constant (.epsilon.) not higher than 20, at a reaction temperature of 150.degree. to 250.degree. C, for 0.1 to 10 hours.

摘要翻译： 一种制备有机异氰酸酯化合物的方法，其特征在于使具有下式的含氯甲基的化合物：

公开(公告)号：US5122191A

公开(公告)日：1992-06-16

申请号：US655866

申请日：1991-02-15

申请人： Masahiro Morozumi ,  Yasuhiko Yoshioka ,  Takashi Iwashimizu ,  Masahiro Yamashita ,  Kenji Hayashi ,  Yukihiro Tanigawa ,  Hisao Kitano ,  Fumio Tanimoto

发明人： Masahiro Morozumi ,  Yasuhiko Yoshioka ,  Takashi Iwashimizu ,  Masahiro Yamashita ,  Kenji Hayashi ,  Yukihiro Tanigawa ,  Hisao Kitano ,  Fumio Tanimoto

IPC分类号： C04B14/10

CPC分类号： C04B14/10

摘要： An admixture for cement compositions is prepared by calcining at 630.degree. to 870.degree. C. at least one substance selected from the group consisting of natural kaolin, halloysite and synthetic kaolin, effecting classification so that amorphous portions of alumina/silica having a mixing ratio of 0.5 to 1.3 form main components, with all particles having diameters up to 8 .mu.m and an average diameter of 0.5 to 2 .mu.m, and a specific gravity ranging from 2.45 to 2.55. This admixture is used to produce a cement composition such as mortar or concrete, which realizes excellent fluidity to promote workability, and a high strength structure.

摘要翻译： 通过在630℃至870℃下煅烧至少一种选自天然高岭土，多水高岭土和合成高岭土的物质来制备水泥组合物的混合物，进行分级，使得具有混合比例的氧化铝/二氧化硅的非晶部分 0.5〜1.3构成主要成分，所有颗粒直径达8μm，平均直径为0.5〜2μm，比重为2.45〜2.55。 该混合物用于生产诸如砂浆或混凝土的水泥组合物，其实现了优异的流动性以提高加工性和高强度结构。

公开(公告)号：US4074052A

公开(公告)日：1978-02-14

申请号：US749053

申请日：1976-12-09

申请人： Susumu Handa ,  Yoshiaki Tanaka ,  Atsushi Nishihata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Susumu Handa ,  Yoshiaki Tanaka ,  Atsushi Nishihata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： B01J27/00 ,  C07B61/00 ,  C07D251/34

CPC分类号： C07D251/34

摘要： Isocyanuric acid triesters are prepared by isomerization of the corresponding cyanuric acid triesters. The starting cyanuric acid esters are dissolved in a polar solvent which is free of active hydrogen atoms, which contains a nitrogen or sulfur atom in the molecule and which has a boiling point not higher than 260.degree. C. The solution may optionally contain an alkali metal halide, an alkaline earth metal halide or an ammonium halide. Isomerization is carried out at a temperature of from 50.degree. to 200.degree. C.

摘要翻译： 异氰脲酸三酯通过相应的氰尿酸三酯的异构化制备。 将起始的氰尿酸酯溶解在不含活性氢原子的极性溶剂中，所述活性氢原子在分子中含有氮或硫原子，沸点不高于260℃。该溶液可任选地含有碱金属 卤化物，碱土金属卤化物或卤化铵。 异构化在50〜200℃的温度下进行。

公开(公告)号：US4059610A

公开(公告)日：1977-11-22

申请号：US686381

申请日：1976-05-14

申请人： Susumu Handa ,  Yoshiaki Tanaka ,  Atsushi Nishibata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Masahiro Saito ,  Fumio Tanimoto ,  Hisao Kitano

发明人： Susumu Handa ,  Yoshiaki Tanaka ,  Atsushi Nishibata ,  Sadashi Ueda ,  Yoshiaki Inamoto ,  Masahiro Saito ,  Fumio Tanimoto ,  Hisao Kitano

IPC分类号： C07C67/00 ,  C07C241/00 ,  C07C263/02 ,  C07C265/00 ,  C07C265/08 ,  C07D251/34 ,  C08G18/00 ,  C07C118/00

CPC分类号： C07D251/34 ,  C07C263/00

摘要： Isocyanic acid derivatives are prepared by reacting an organic halogen compound with an alkali cyanate in N,N-disubstituted organic acid amides, N,N-disubstituted sulfonic acid amides, sulfoxides, sulfones or macrocyclic polyethers, at 70.degree. to 200.degree. C, in the presence of organic polyhalogen compounds selected from compounds having dihalogenomethyl group, dihalogenomethylene group, or trihalogenomethyl group and tetrahalogenomethane, in an amount in the range of from 1 to 20 weight percent based on the weight of said organic halogen compounds.

摘要翻译： 异氰酸衍生物通过在N，N-二取代有机酰胺，N，N-二取代磺酸酰胺，亚砜，砜或大环聚醚中的有机卤素化合物与碱金属氰酸盐在70℃至200℃下反应来制备， 基于所述有机卤素化合物的重量，选自具有二卤代甲基，二卤代亚甲基或三卤代甲基的化合物的有机多卤素化合物的存在量为1至20重量％。