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    PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL
    1.
    发明申请
    PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL 审中-公开

    公开(公告)号：US20180090280A1

    公开(公告)日：2018-03-29

    申请号：US15817413

    申请日：2017-11-20

    申请人： FUJIFILM Corporation ,  Sharp Kabushiki Kaisha

    发明人： Yukio TANI ,  Katsumi KOBAYASHI ,  Ryohsuke YAMANAKA ,  Atsushi FUKUI ,  Norio MUROFUSHI

    IPC分类号： H01G9/20 ,  C09B57/10

    CPC分类号： H01G9/2004 ,  C09B57/10 ,  H01G9/2031 ,  H01G9/2059 ,  H01G9/2068 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

    摘要： Provided are a photoelectric conversion element and a dye sensitized solar cell having a supporting substrate, a conductive layer, a power generating layer having a porous semiconductor layer onto which a metal complex dye represented by Formula (1) is adsorbed, a porous insulating layer, and a counter electrode conductive layer, in which the layers are laminated in this order on the supporting substrate, and voids that each of the power generating layer, the porous insulating layer, and the counter electrode conductive layer has are filled with an electrolyte. R represents a hydrogen atom, an alkyl group, or an aryl group. G represents a group represented by any one of Formulae (G-1) to (G-4). A1 to A3 each represent a hydrogen atom, a carboxyl group, or a salt thereof. At least one of A1 to A3 is a carboxyl group or a salt thereof. X1 and X2 each represent —O—, —S—, and others. Ra represents an alkyl group and the like. Rb to Re each represent a hydrogen atom or a substituent. na represents 1 to 3. (G-1) to (G-4) are bonded to a pyridine ring in the portion of *.

    METAL-COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, AND DYE SOLUTION CONTAINING METAL-COMPLEX DYE
    2.
    发明申请
    METAL-COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, AND DYE SOLUTION CONTAINING METAL-COMPLEX DYE 有权
    金属复合染料，光电转换元件，透明光敏元件和含有金属复合染料的染料溶液

    公开(公告)号：US20160012977A1

    公开(公告)日：2016-01-14

    申请号：US14860001

    申请日：2015-09-21

    申请人： FUJIFILM Corporation

    发明人： Yukio TANI ,  Katsumi KOBAYASHI

    IPC分类号： H01G9/20 ,  C09B57/10 ,  H01L51/00 ,  C07F15/00

    CPC分类号： H01G9/2059 ,  C07F15/0026 ,  C07F15/0053 ,  C09B23/005 ,  C09B23/105 ,  C09B23/145 ,  C09B57/10 ,  H01L51/0086 ,  H01L51/0088 ,  Y02E10/542 ,  Y02E10/549

    摘要： A photoelectric conversion element, a photoelectric conversion element, a dye-sensitized solar cell and a dye solution, having an electrically conductive support, a photoconductor layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode, wherein the photoconductor layer contains semiconductor fine particles carrying a metal complex dye; and wherein the metal complex dye has at least a carboxyl group and a salt of the carboxyl group, the salt being selected from the group consisting of a potassium salt, a lithium salt, and a cesium salt, and the ratio α of the number of the salt of the carboxyl group divided by the total number of the carboxyl group and the salt of the carboxyl group to be found in one molecule of the metal complex dye, lying in the range of 0.1 to 0.9:

    摘要翻译： 具有导电性载体的光电转换元件，光电转换元件，染料敏化太阳能电池和染料溶液，含有电解质的感光体层，含有电解质的电荷转移层和对电极，其中光电导体 层含有载有金属络合染料的半导体细颗粒; 并且其中所述金属络合物染料至少具有羧基和所述羧基的盐，所述盐选自钾盐，锂盐和铯盐，并且所述盐的数量的比率α 羧基的盐除以在一分子金属配合物染料中发现的羧基总数和羧基的盐的比例在0.1至0.9的范围内：

    PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ADSORBED ELECTRODE, AND METHOD FOR PRODUCING DYE-SENSITIZED SOLAR CELL
    3.
    发明申请
    PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ADSORBED ELECTRODE, AND METHOD FOR PRODUCING DYE-SENSITIZED SOLAR CELL 审中-公开
    光电转换元件，透明致密太阳能电池，金属复合染料，染料溶液，染料电极以及用于生产透明的太阳能电池的方法

    公开(公告)号：US20150248969A1

    公开(公告)日：2015-09-03

    申请号：US14713341

    申请日：2015-05-15

    申请人： FUJIFILM Corporation

    发明人： Kousuke WATANABE ,  Yukio TANI ,  Kouitsu SASAKI ,  Hirotaka SATOU ,  Kazuhiro TSUNA ,  Katsumi KOBAYASHI

    IPC分类号： H01G9/20 ,  C09B57/10 ,  C07F15/00

    摘要： A photoelectric conversion element, having a photoconductor layercontaining semiconductor fine particles carrying a metal complex dye of Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing the solar cell: M(LA)(LD)(LX)mX·(CI)mY  Formula (I) M represents a metal ion, LA represents a ligand of Formula (AL), LD represents a bidentate or tridentate ligand, at least one of coordinating atoms being an anion; LX represents a monodentate ligand; CI represents a counter ion; mX is 0 or 1; mY is 0 to 3; Rings A to C represent a heterocycle; Z1 and Z2 represent a carbon or nitrogen atom; Anc1 to Anc3 represent an acidic group; X1 to X3 represent a single bond or linking group; R1 to R3 represent a substituent; l1, l3, l2, m1, m3, m2, n1, n2, and n3 each are an integer.

    摘要翻译： 一种光电转换元件，具有含有承载式（I）的金属络合染料的半导体微粒的感光体层; 金属络合染料，染料溶液，染料吸附电极，染料敏化太阳能电池以及太阳能电池的制造方法：M（LA）（LD）（LX）mX·（CI）mY式 ）M表示金属离子，LA表示式（AL）的配体，LD表示二齿或三齿配体，至少一个配位原子为阴离子; LX表示单齿配体; CI表示抗衡离子; mX为0或1; mY为0〜3; 环A至C表示杂环; Z 1和Z 2表示碳或氮原子; Anc1至Anc3表示酸性基团; X1至X3表示单键或连接基团; R1至R3表示取代基; l1，l3，l2，m1，m3，m2，n1，n2，n3分别为整数。

    METAL COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, DYE SOLUTION, AND COMPOUND
    6.
    发明申请
    METAL COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, DYE SOLUTION, AND COMPOUND 有权
    金属复合染料，光电转换元件，透明度太阳能电池，染料溶液和化合物

    公开(公告)号：US20140290746A1

    公开(公告)日：2014-10-02

    申请号：US14301796

    申请日：2014-06-11

    申请人： FUJIFILM Corporation

    发明人： Yukio TANI ,  Katsumi KOBAYASHI ,  Kimiatsu NOMURA

    IPC分类号： H01G9/20 ,  C09B57/10

    CPC分类号： H01G9/2059 ,  C07D213/79 ,  C07D401/04 ,  C07D409/14 ,  C09B57/10 ,  Y02E10/542

    摘要： A photoelectric conversion element, having: an electrically-conductive support; a photoconductor layer having a semiconductor fine-particle layer adsorbed a dye; a charge transfer layer containing an electrolyte; and a counter electrode; which are provided on one side of the support in this order, in which the dye has at least one terdentate ligand having at least one acidic group; at least one ligand coordinating to a metal atom M has an sp2 carbon atom; a cyclic group binds to the sp2 carbon atom; a specific substituent R is substituted at an atom of α- or β-position to the atom of the cyclic group directly binding to the sp2 carbon atom; and with the metal atom M, an atom G1 of the α- or β-position, and an atom G2 of the substituent R, an angle θ (∠ZMG1G2) is 150° or less.

    摘要翻译： 一种光电转换元件，具有：导电支撑体; 具有吸附染料的半导体细粒层的感光体层; 含有电解质的电荷转移层; 和对电极; 其中所述染料具有至少一个具有至少一个酸性基团的特定配位体; 与金属原子M配位的至少一个配体具有sp2碳原子; 环状基团与sp2碳原子结合; 特定取代基R在直接与sp 2碳原子结合的环状基团的原子上被α-或β-位的原子取代; 并且与金属原子M一起形成α-或β-元素的原子G1，取代基R的原子G2，角度＆amp; （∠ZMG1G2）为150°以下。

    ORGANIC SEMICONDUCTOR ELEMENT, COMPOSITION, METHOD OF PURIFYING COMPOUND, AND APPLICATION THEREOF
    10.
    发明申请
    ORGANIC SEMICONDUCTOR ELEMENT, COMPOSITION, METHOD OF PURIFYING COMPOUND, AND APPLICATION THEREOF 有权

    公开(公告)号：US20210020841A1

    公开(公告)日：2021-01-21

    申请号：US17061756

    申请日：2020-10-02

    申请人： FUJIFILM Corporation

    发明人： Tetsuya WATANABE ,  Yukio TANI

    IPC分类号： H01L51/00

    摘要： Provided are an organic semiconductor element, a composition, an organic semiconductor composition, an organic semiconductor film, a method of producing a composition, a method of manufacturing an organic semiconductor element, and a method of purifying a compound. The organic semiconductor element includes an organic semiconductor film formed by forming a composition into a film, in which the composition contains a compound represented by the following formula (where R1 to R8 each independently represent a hydrogen atom or a substituent), and a total content of sodium element, potassium element, silicon element, and aluminum element in the composition is 50 ppm or less. The organic semiconductor element has high heat resistance of carrier mobility.