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公开(公告)号:US20220406850A1
公开(公告)日:2022-12-22
申请号:US17884532
申请日:2022-08-09
申请人: FUJIFILM Corporation
发明人: Masashi ONO , Hirotaka SATOU , Toshihiro ISE
摘要: There is provided a photodetector element including a first electrode layer; a second electrode layer; a photoelectric conversion layer provided between the first electrode layer and the second electrode layer; an electron transport layer provided between the first electrode layer and the photoelectric conversion layer; and a hole transport layer provided between the photoelectric conversion layer and the second electrode layer, in which the photoelectric conversion layer contains an aggregate of semiconductor quantum dots that contain a metal atom and contains a ligand coordinated to the semiconductor quantum dot, the hole transport layer contains an organic semiconductor, and the second electrode layer is formed of a metal material containing at least one metal atom selected from Au, Pt, Ir, Pd, Cu, Pb, Sn, Zn, Ti, W, Mo, Ta, Ge, Ni, Cr, or In. There is also provided an image sensor including the photodetector element.
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公开(公告)号:US20190027621A1
公开(公告)日:2019-01-24
申请号:US16141254
申请日:2018-09-25
申请人: FUJIFILM Corporation
发明人: Hirotaka SATO , Kenji SHIROKANE , Toshihiro ISE
IPC分类号: H01L31/0224 , H01L27/30 , H01L51/44 , H01G9/20
摘要: A photoelectric conversion element includes, in this order: a first electrode that includes a photosensitive layer containing a light absorbing agent on a conductive support; a compound layer that contains a surface treating agent and is provided on a surface of the photosensitive layer; and a second electrode, in which the light absorbing agent contains a compound having a perovskite-type crystal structure that has a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than elements of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X, and the surface treating agent is represented by a specific formula.
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公开(公告)号:US20180144877A1
公开(公告)日:2018-05-24
申请号:US15874951
申请日:2018-01-19
申请人: FUJIFILM Corporation
发明人: Hirotaka SATOU , Naoyuki HANAKI , Toshihiro ISE , Kenji SHIROKANE
IPC分类号: H01G9/20 , H01L51/42 , H01L51/44 , C07D513/04 , H01L51/00
CPC分类号: H01G9/2018 , C07D513/04 , H01G9/0029 , H01G9/2009 , H01L51/0003 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0073 , H01L51/0074 , H01L51/4273 , H01L51/442 , Y02E10/542 , Y02E10/549
摘要: Provided is a photoelectric conversion element including at least a first electrode that includes a conductive support, a photosensitive layer that contains a light absorbing agent, a hole transport layer that contains an organic hole transporting material, and a second electrode. At least one of the photosensitive layer or the hole transport layer is provided on the conductive support to constitute the first electrode in combination with the conductive support. The photosensitive layer includes at least a compound having a perovskite-type crystal structure that includes a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than elements of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X as the light absorbing agent. The hole transport layer includes at least a compound represented by the following Formula 1 as the organic hole transporting material.
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公开(公告)号:US20170330694A1
公开(公告)日:2017-11-16
申请号:US15658995
申请日:2017-07-25
申请人: FUJIFILM Corporation
CPC分类号: H01G9/2059 , H01G9/2027 , H01L51/0047 , H01L51/0094 , H01L51/422 , Y02E10/549 , Y02P70/521
摘要: Provided are a photoelectric conversion element including a first electrode having a photosensitive layer including a light absorber on a conductive support and a second electrode facing the first electrode, in which the light absorber includes a compound having a perovskite-type crystal structure including organic cations, cations of a metallic atom other than elements belonging to Group I of the periodic table, and anions, and at least some of the organic cations constituting the compound are organic cations having a silyl group and a solar cell using the photoelectric conversion element.Also provided is a composition containing a compound represented by Formula (1a) and a halogenated metal. R13Si-L-NR23Hal Formula (1a) In the formula, R1, R2, and L are specific groups. Hal represents a halogen atom.
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公开(公告)号:US20180122587A1
公开(公告)日:2018-05-03
申请号:US15852291
申请日:2017-12-22
申请人: FUJIFILM Corporation
发明人: Hirotaka SATOU , Naoyuki HANAKI , Toshihiro ISE , Kenji SHIROKANE
IPC分类号: H01G9/20
CPC分类号: H01G9/2059 , H01G9/2027 , H01G9/2077 , H01L51/44 , Y02E10/549
摘要: Provided is a photoelectric conversion element including a first electrode that includes a photosensitive layer, which includes a light absorbing agent, and a second electrode. The light absorbing agent includes a compound having a perovskite-type crystal structure that includes a cation of a cationic organic group A, a cation of a metal atom M other than the element of Group 1, and an anion of an anionic atom X. A hole transport layer, which includes an organic hole transporting material, is provided between the first electrode and the second electrode. The organic hole transporting material has a molecular weight of 6,000 or less and includes halogen, a halogenated alkyl group, or a group represented by RA—X—*, where X represents S, NRB, or O, RA and RB represent a halogenated alkyl group, and * represents a bonding position.
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公开(公告)号:US20190189944A1
公开(公告)日:2019-06-20
申请号:US16285846
申请日:2019-02-26
申请人: FUJIFILM Corporation
发明人: Kenji SHIROKANE , Hirotaka SATOU , Toshihiro ISE
IPC分类号: H01L51/44 , H01L51/42 , H01L31/0224 , C07F7/08 , C07F9/6553 , C07C211/17 , C07C211/27 , C07D333/20
CPC分类号: H01L51/445 , C07C211/17 , C07C211/27 , C07D333/20 , C07F7/0812 , C07F9/655345 , H01G9/20 , H01L31/022425 , H01L51/4206 , H01L51/44 , H01L51/447 , Y02E10/542 , Y02E10/549
摘要: Provided is a photoelectric conversion element, including a first electrode that has a photosensitive layer containing a light absorbing agent on a conductive support, in which the light absorbing agent contains a compound having a perovskite-type crystal structure that has an organic cation represented by Formulas (1) and (2), a cation of a metal atom, and an anion; and a solar cell which is formed of this photoelectric conversion element. C(R1)(R2)(R3)—N(R1a)3+ Formula (1) R4—NR2a3+ Formula (2) R1, R2, R3, and R4 represent specific substituent that may be different from each other. R1a and R2a represent a hydrogen atom or a specific substituent.
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公开(公告)号:US20180122585A1
公开(公告)日:2018-05-03
申请号:US15852753
申请日:2017-12-22
申请人: FUJIFILM Corporation
发明人: Hirotaka SATOU , Naoyuki HANAKI , Toshihiro ISE , Kenji SHIROKANE
IPC分类号: H01G9/20 , C07D513/04 , H01L51/00 , C07D495/04 , C07D495/22 , C07D495/14 , C07D517/04 , C07D498/04 , C07D493/04 , C07D487/04 , H01L51/42
CPC分类号: H01G9/2009 , C07D487/04 , C07D493/04 , C07D495/04 , C07D495/14 , C07D495/22 , C07D498/04 , C07D513/04 , C07D517/04 , H01G9/2031 , H01L51/0061 , H01L51/0065 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0073 , H01L51/0074 , H01L51/4253 , Y02E10/542 , Y02E10/549
摘要: Provided is a photoelectric conversion element including a first electrode that includes a photosensitive layer, which includes a light absorbing agent, and a second electrode. The light absorbing agent includes a compound having a perovskite-type crystal structure including a cationic organic group A, a cation of a metal atom M other than the element of Group 1, and an anion of an anionic atom X, a hole transport layer, which includes a hole transporting material, is provided between the first electrode and the second electrode, the hole transporting material includes a compound including a condensed polycyclic aromatic group having a number of rings of 4 or greater, at least two rings thereof are hetero rings, and the condensed polycyclic aromatic group includes at least one structure selected from the group consisting of benzene, naphthalene, and phenanthrene.
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8.
公开(公告)号:US20170092434A1
公开(公告)日:2017-03-30
申请号:US15372471
申请日:2016-12-08
申请人: FUJIFILM Corporation
CPC分类号: H01G9/2059 , C07F15/0053 , C09B23/105 , C09B57/10 , H01G9/2018 , H01G9/2022 , H01G9/2027 , H01L51/0086 , Y02E10/542
摘要: A photoelectric conversion element having an electrically conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by the following Formula (1), and a dye-sensitized solar cell; and a metal complex dye and a dye solution, each of which is used in the photoelectric conversion element and the dye-sensitized solar cell, ML1L2(X)n1.CImY Formula (1) in the formula, M represents a metal ion, L1 represents a tridentate ligand having a group LV represented by the following Formula (LV-1) or (LV-2); L2 represents a bidentate or tridentate ligand including at least one of aromatic ring groups having a specific sp2 carbon atom to which a substituent is bonded; X represents a monodentate ligand; n1 represents 0 or 1; CI represents a required counterion; and mY represents an integer of 0 to 3, —RV1═RV2—RV31 Formula (LV-1) —C≡C—RV32 Formula (LV-2) in the formulae, RV1 and RV2 each independently represent a nitrogen atom or CRV4, RV4 represents a hydrogen atom or a substituent, RV31 represents a fused polycyclic aromatic ring group or a fused polycyclic heterocyclic group, and RV32 represents a fused polycyclic aromatic ring group or a heteroaryl group.
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公开(公告)号:US20150255636A1
公开(公告)日:2015-09-10
申请号:US14715614
申请日:2015-05-19
申请人: FUJIFILM CORPORATION
发明人: Seiji YAMASHITA , Toshihiro ISE
IPC分类号: H01L31/0272 , H01L31/117
CPC分类号: H01L31/0272 , H01L27/14676 , H01L31/085 , H01L31/095 , H01L31/115 , H01L31/117 , H01L31/20 , H01L51/0037 , H01L51/0046 , H01L51/4213 , H01L2031/0344 , Y02E10/549
摘要: A radiation detector (10) which has a multilayer structure that includes: a first electrode (34); a second electrode (49) that is disposed so as to face the first electrode; a selenium layer (48) that is disposed between the first electrode and the second electrode and contains amorphous selenium; a first blocking organic layer (38) that is adjacent to the selenium layer, between the first electrode and the selenium layer, and that contains a hole transport material having an electron affinity of 3.7 eV or less; and a second blocking organic layer (37) that is adjacent to the selenium layer, between the second electrode and the selenium layer, and that contains an electron transport material having an ionization potential of 5.9 eV or more. This radiation detector (10) has low dark current, excellent durability, and less afterimages.
摘要翻译: 一种具有多层结构的放射线检测器(10),包括:第一电极(34); 设置成与第一电极相对的第二电极(49); 设置在第一电极和第二电极之间并含有非晶硒的硒层(48); 位于第一电极和硒层之间的与硒层相邻的第一阻挡有机层(38),并且包含电子亲和力为3.7eV以下的空穴传输材料; 以及与第二电极和硒层之间的硒层相邻的第二阻挡有机层(37),并且包含电离势为5.9eV以上的电子传输材料。 该辐射检测器(10)具有低暗电流,优异的耐久性和较少的残影。
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10.
公开(公告)号:US20220238809A1
公开(公告)日:2022-07-28
申请号:US17715080
申请日:2022-04-07
申请人: FUJIFILM Corporation
发明人: Hiroki SUGIURA , Toshihiro ISE
摘要: An object of the present invention is to provide an organic thin film transistor having excellent atmospheric stability. Another object of the present invention is to provide a polymer, a composition, an organic semiconductor film, and a compound.
The organic thin film transistor of the present invention has an organic semiconductor film which includes a polymer having a partial structure represented by Formula (1). In Formula (1), X1 represents a sulfur atom or a selenium atom, X2 to X4 each independently represent a sulfur atom, an oxygen atom, or a selenium atom, Y1 to Y4 each independently represent a group represented by —CR1═ or a nitrogen atom, where at least one of Y1 to Y4 represents a nitrogen atom, R1 represents a hydrogen atom or a substituent, and * represents a bonding position.
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