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1.发明授权Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals 有权用于通过环状缩醛和缩酮的气相氢解制备羟基醚烃的镍改性催化剂公开(公告)号：US09382179B2
公开(公告)日：2016-07-05
申请号：US14307956
申请日：2014-06-18
IPC分类号： C07C41/28
摘要： Catalyst compositions of alumina supports containing palladium and nickel are selective in a vapor phase hydrogenolyzis reaction to convert cyclic acetal compounds and/or cyclic ketal compounds in the presence of hydrogen to their corresponding hydroxy ether hydrocarbon reaction products.
摘要翻译： 包含钯和镍的氧化铝载体的催化剂组合物在气相氢解反应中是选择性的，以在氢存在下将环状缩醛化合物和/或环状缩酮化合物转化成其相应的羟基醚烃反应产物。
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公开(公告)号：US09975833B2
公开(公告)日：2018-05-22
申请号：US15253316
申请日：2016-08-31
发明人： Thomas James Devon
CPC分类号： C07C41/30 , C07C1/326 , C07C2523/755 , C07C2531/22 , C07C15/14 , C07C43/205
摘要： The disclosure relates to the efficient preparation of aromatic hydrocarbons useful as intermediates for di-, tri-, tetra- and poly-dentate organophosphorus ligands having value in particular as hydroformylation catalysts. The use of triarylphosphine halide catalysts have been found to be more efficient in forming these intermediates by the use of excess triarylphosphine in an amount beyond what is required to form a coordination complex.
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3.发明申请NICKEL MODIFIED CATALYST FOR THE PRODUCTION OF HYDROXY ETHER HYDROCARBONS BY VAPOR PHASE HYDROGENOLYSIS OF CYCLIC ACETALS AND KETALS 审中-公开用于生产羟基醚的镍改性催化剂通过循环乙醇和水的蒸气相氢化公开(公告)号：US20140303404A1
公开(公告)日：2014-10-09
申请号：US14307956
申请日：2014-06-18
IPC分类号： C07C41/28
摘要： Catalyst compositions of alumina supports containing palladium and nickel are selective in a vapor phase hydrogenolysis reaction to convert cyclic acetal compounds and/or cyclic ketal compounds in the presence of hydrogen to their corresponding hydroxy ether hydrocarbon reaction products.
摘要翻译： 含有钯和镍的氧化铝载体的催化剂组合物在气相氢解反应中是选择性的，以在氢气存在下将环状缩醛化合物和/或环状缩酮化合物转化成其相应的羟基醚烃反应产物。
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公开(公告)号：US20180057435A1
公开(公告)日：2018-03-01
申请号：US15253316
申请日：2016-08-31
发明人： Thomas James Devon
CPC分类号： C07C41/30 , C07C1/326 , C07C2523/755 , C07C2531/22 , C07C15/14 , C07C43/205
摘要： The disclosure relates to the efficient preparation of aromatic hydrocarbons useful as intermediates for di-, tri-, tetra- and poly-dentate organophosphorus ligands having value in particular as hydroformylation catalysts. The use of triarylphosphine halide catalysts have been found to be more efficient in forming these intermediates by the use of excess triarylphosphine in an amount beyond what is required to form a coordination complex.
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公开(公告)号：US09687837B1
公开(公告)日：2017-06-27
申请号：US15253342
申请日：2016-08-31
发明人： Thomas James Devon
CPC分类号： B01J31/2409 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/5027 , C07F9/5031 , C07F9/65515 , C07F9/65522 , C07F9/65683 , C07F17/02 , C07C47/02
摘要： A new stable, catalytically active, tetradentate organophosphorus modified rhodium hydroformylation catalyst has been discovered that is capable of producing aldehyde products with a high linear/branched product ratio from linear olefins. The tetradentate organophosphorus modifier is a tetrasubstituted 2,2′,2″,5′-tetramethyl-1,1′:4′-1″-terphenyl, whereby, each methyl group has one hydrogen substituted by an R, R′-diorganophosphine moiety. The R, R′ may comprise aromatic, alkyl, arylalkyl and alkylaryl groups. The precursor 2,2′,2″,5′-tetramethyl-1,1′:4′,1″-terphenyl hydrocarbon may be prepared from para-xylene and toluene derivatives.
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