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公开(公告)号：US11370853B2
公开(公告)日：2022-06-28
申请号：US16461839
申请日：2016-12-30
Applicant: DOW GLOBAL TECHNOLOGIES LLC , ROHM AND HAAS COMPANY
Inventor： Chang-Soo Lee , Collin H. Martin , Daryl J. Gisch , Christopher R. Eicher
IPC: B01D15/10 , B01J20/26 , B01J20/28 , B01J20/289 , C07H1/06 , C08F8/42 , C13B20/12 , B01J20/30 , B01D15/18
Abstract: A method of processing an aqueous solution, wherein the aqueous solution comprises one or more dissolved sugar, one or more dissolved sugar alcohol, or a mixture thereof, wherein the method comprises bringing the aqueous solution into contact with a collection of resin beads, wherein the resin beads comprise functional groups of structure (S1).
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2.发明申请公开(公告)号：US20180257003A1
公开(公告)日：2018-09-13
申请号：US15542128
申请日：2016-02-26
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor： Daryl J. Gisch , Christopher R. Eicher , Stephen Pease , Gongwei Pu
CPC classification number: B01D15/362 , B01J39/05 , B01J39/20 , B01J39/26 , C13K1/00 , C13K1/08 , C13K11/00
Abstract: A method for chromatographically separating a first saccharide from a liquid eluent comprising the first saccharide and a second saccharide by passing the liquid eluent through a bed including a polymeric macroporous alkylene-bridged resin in calcium form.
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3.发明授权公开(公告)号：US10258903B2
公开(公告)日：2019-04-16
申请号：US15542128
申请日：2016-02-26
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor： Daryl J. Gisch , Christopher R. Eicher , Stephen Pease , Gongwei Pu
Abstract: A method for chromatographically separating a first saccharide from a liquid eluent comprising the first saccharide and a second saccharide by passing the liquid eluent through a bed including a polymeric macroporous alkylene-bridged resin in calcium form.
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公开(公告)号：US20150096412A1
公开(公告)日：2015-04-09
申请号：US14241746
申请日：2013-04-23
Applicant: Dow Global Technologies LLC
Inventor： Charles R. Marston , Christopher R. Eicher
CPC classification number: C22B23/043 , C22B3/08 , C22B3/42 , C22B23/0453 , C22B23/0461 , C22B23/0484 , C25C1/08 , Y02P10/234
Abstract: A method for recovering nickel and cobalt from a product liquor solution by processing the product liquor solution through a continuous ion exchange process including a plurality of ion exchange beds containing nickel selective ion exchange resin that pass through individual process zones as part of a nickel recovery circuit, wherein the method includes the following steps: (a) passing the product liquor solution through an ion exchange bed to load nickel onto the ion exchange resin and produce a cobalt-containing raffinate solution, (b) passing a sulfuric acid solution through the loaded ion exchange bed to strip nickel from the exchange resin and produce a nickel-containing eluate, (c) passing a rinse solution through the stripped ion exchange bed, (d) adjusting the pH of the cobalt-containing raffinate solution to a pH of at least 2.3, (e) passing the cobalt-containing raffinate solution through an ion exchange bed to pre-load cobalt on the ion exchange resin, (f) repeating step (a) though (e) until the cobalt concentration of the cobalt-containing raffinate solution increases to at least twice that of the product liquor solution, and (g) removing a first portion of the cobalt-containing raffinate solution of step (d) from the nickel recovery circuit for subsequent cobalt recovery, and (h) passing a second portion of the cobalt-containing raffinate solution from step (d) to step (e).
Abstract translation: 一种从产品液体溶液中回收镍和钴的方法，该方法是通过连续的离子交换方法处理产物液体溶液，所述连续离子交换方法包括多个离子交换床，所述离子交换床包含镍选择性离子交换树脂，其通过作为镍回收回路的一部分的各个工艺区 其中所述方法包括以下步骤：（a）使产物液溶液通过离子交换床以将镍负载到离子交换树脂上并产生含钴萃余液，（b）使硫酸溶液通过所加载的 离子交换床以从交换树脂中剥离镍，并产生含镍洗脱液，（c）使冲洗溶液通过剥离的离子交换床，（d）将含钴萃余液溶液的pH调节至 至少2.3，（e）使含钴萃余液通过离子交换床以在离子交换树脂上负载钴，（f）重复步骤（a） 尽管（e），直到含钴萃余液溶液的钴浓度增加至产物液溶液的钴浓度的至少两倍，和（g）从镍中除去步骤（d）的含钴萃余液溶液的第一部分 用于随后的钴回收的回收回路，和（h）将来自步骤（d）的第二部分含钴萃余液溶液通到步骤（e）。
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