公开(公告)号：US4286085A

公开(公告)日：1981-08-25

申请号：US107729

申请日：1979-12-28

Applicant: Donald B. G. Jaquiss ,  Victor Mark ,  Lawrence C. Mitchell

Inventor： Donald B. G. Jaquiss ,  Victor Mark ,  Lawrence C. Mitchell

IPC: C08G64/24 ,  C08G63/62

CPC classification number: C08G64/24

Abstract: An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a substituted pyridine or a salt of a substituted pyridine.

Abstract translation: 在催化量的取代吡啶或取代的吡啶的盐存在下，使二元酚与碳酸酯前体反应制备高分子量芳族碳酸酯聚合物的界面聚合方法。

公开(公告)号：US4277598A

公开(公告)日：1981-07-07

申请号：US107726

申请日：1979-12-28

Applicant: Walter L. Hall ,  Donald B. G. Jaquiss ,  Victor Mark

Inventor： Walter L. Hall ,  Donald B. G. Jaquiss ,  Victor Mark

IPC: C08G64/24 ,  C08G63/62

CPC classification number: C08G64/24

Abstract: An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a cyclic amidine.

Abstract translation: 通过在催化量的环状脒存在下使二元酚与碳酸酯前体反应来制备高分子量芳族聚碳酸酯的界面聚合方法。

公开(公告)号：US4262113A

公开(公告)日：1981-04-14

申请号：US107895

申请日：1979-12-28

Applicant: Donald B. G. Jaquiss ,  Victor Mark

Inventor： Donald B. G. Jaquiss ,  Victor Mark

IPC: C08G64/24 ,  C08G63/62

CPC classification number: C08G64/24

Abstract: An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of an amino amidine or amino guanidine.

Abstract translation: 通过在催化量的氨基脒或氨基胍的存在下使二元酚与碳酸酯前体反应来制备高分子量芳族聚碳酸酯的界面聚合方法。

公开(公告)号：US4262111A

公开(公告)日：1981-04-14

申请号：US107725

申请日：1979-12-28

Applicant: Walter L. Hall ,  Donald B. G. Jaquiss ,  Victor Mark

Inventor： Walter L. Hall ,  Donald B. G. Jaquiss ,  Victor Mark

IPC: C08G64/24 ,  C08G63/62

CPC classification number: C08G64/24

Abstract: An interfacial polymerization process for preparing high molecular weight polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a non-cyclic amidine.

Abstract translation: 通过在催化量的非环状脒存在下使二元酚与碳酸酯前体反应来制备高分子量聚碳酸酯的界面聚合方法。

公开(公告)号：US4201878A

公开(公告)日：1980-05-06

申请号：US876703

申请日：1978-02-10

Applicant: Victor Mark ,  Lawrence C. Mitchell ,  Charles V. Hedges

Inventor： Victor Mark ,  Lawrence C. Mitchell ,  Charles V. Hedges

IPC: C07C37/11 ,  C07C37/14 ,  C07C37/18 ,  C07C37/20 ,  C07C37/00 ,  C07C39/16

CPC classification number: C07C37/20 ,  C07C37/115 ,  C07C37/14 ,  C07C37/16 ,  C07C37/18 ,  C07C2101/14

Abstract: Bisphenols substantially free of by-products, are produced rapidly by reacting a phenol and a compound of the formulae: ##STR1## wherein R and R' are hydrogen, lower alkyl or aryl; X is lower alkoxy or the same as X'; Y is chlorine or the same as X; X' is aryloxy; Z is a 1,2- or 1,3-propylenedioxy (that may optionally carry hydroxy, lower alkyl or lower hydroxyalkyl substituents), or arylenedioxy radical; n is integer from three to nine; m is (n-1).

Abstract translation: 基本上不含副产物的双酚通过苯酚和下式的化合物反应快速生成：其中R和R'是氢，低级烷基或芳基; X是低级烷氧基或与X'相同; Y为氯或与X相同; X'是芳氧基; Z是1,2-或1,3-亚丙二氧基（可以任选地带有羟基，低级烷基或低级羟烷基取代基）或亚芳基二氧基; n为3〜9的整数; m是（n-1）。

公开(公告)号：US4608430A

公开(公告)日：1986-08-26

申请号：US687147

申请日：1984-12-28

Applicant: Victor Mark ,  John R. Campbell

Inventor： Victor Mark ,  John R. Campbell

IPC: C08G64/04 ,  C08G63/62

CPC classification number: C08G64/04

Abstract: Polycarbonates exhibiting improved heat resistances comprised of the reaction products of (i) a carbonate precursor and (ii) at least one dihydric phenol represented by the general formula ##STR1## wherein: R and R.sup.1 are independently selected from alkyl radicals;A is selected from divalent hydrocarbon radicals, ##STR2## and n is either zero or one.

Abstract translation: 表现出改善的耐热性的聚碳酸酯由（i）碳酸酯前体和（ii）至少一种由通式表示的二元酚的反应产物组成，其中：R和R 1独立地选自烷基; A选自二价烃基，，n为零或一。

公开(公告)号：US4535191A

公开(公告)日：1985-08-13

申请号：US582946

申请日：1984-02-23

Applicant: Victor Mark ,  Charles V. Hedges

Inventor： Victor Mark ,  Charles V. Hedges

IPC: C08G64/06 ,  C07C39/16 ,  C07C39/24

CPC classification number: C08G64/06 ,  C07C39/16

Abstract: Novel polycarbonates are provided which exhibit rubbery and elastomeric properties which are the polymerized reaction products of:(i) a carbonate precursor; and(ii) at least one dihydric phenol represented by the general formula ##STR1## wherein R is selected from straight chain alkyl radicals containing from 8 to about 30 carbon atoms;each R.sup.1 is independently selected from halogen monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;each R.sup.2 is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals; andn and n' are independently selected from whole numbers having a value of from 0 to 4 inclusive.

Abstract translation: 提供新的聚碳酸酯，其表现出橡胶和弹性体性质，其是以下的聚合反应产物：（i）碳酸酯前体; 和（ii）由通式“IMAGE”表示的至少一种二元酚，其中R选自含有8至约30个碳原子的直链烷基; 每个R 1独立地选自卤素一价烃和一价烃氧基; 每个R 2独立地选自卤素，一价烃和一价烃氧基; n和n'独立地选自0〜4的整数。

公开(公告)号：US4490504A

公开(公告)日：1984-12-25

申请号：US522983

申请日：1983-08-15

Applicant: Victor Mark

Inventor： Victor Mark

IPC: C08G63/00 ,  C08G64/00 ,  C08G64/08 ,  C08K7/00 ,  C08K7/14 ,  C08L69/00 ,  C08K3/40

CPC classification number: C08G64/081 ,  C08K7/14

Abstract: Flame retardant and drip-retardant polycarbonate compositions exhibiting good thick section impact comprised of, in physical admixture:(i) at least one halogen-free and sulfur-containing polycarbonate resin derived from (a) at least one halogen-free, sulfur-free and non-polycyclic dihydric phenol, (b) at least one halogen-free thiodiphenol, and (c) a carbonate precursor; and(ii) fibrous glass.These compositions contain an amount of said fibrous glass and an amount of said thiodiphenol effective to render said compositions flame retardant and drip retardant.

Abstract translation: 表现出良好的厚截面冲击的阻燃和滴加聚碳酸酯组合物在物理混合物中包括：（i）至少一种不含卤素和含硫的聚碳酸酯树脂，其衍生自（a）至少一种无卤素，无硫 和非多环二元酚，（b）至少一种无卤素的硫代二酚，和（c）碳酸酯前体; 和（ii）纤维状玻璃。 这些组合物含有一定量的所述纤维状玻璃和一定量的所述硫代二酚有效地使所述组合物阻燃和滴加阻滞。

公开(公告)号：US4477632A

公开(公告)日：1984-10-16

申请号：US519485

申请日：1983-08-01

Applicant: Victor Mark

Inventor： Victor Mark

IPC: C08L23/28 ,  C08G63/00 ,  C08G63/64 ,  C08L1/00 ,  C08L27/00 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00

CPC classification number: C08L69/005

Abstract: Flame retardant and non dripping copolyester-carbonate compositions comprised of, in admixture:(i) a fluorinated polyolefin; and(ii) at least one halogen-free sulfur-containing copolyester-carbonate resin derived from (a) a carbonate precursor, (b) at least one halogen-free, sulfur-free and non-polycyclic dihydric phenol, (c) at least one halogen-free thiodiphenol, and (d) at least one difunctional carboxylic acid or a reactive derivative thereof.

Abstract translation: 阻燃和非滴落共聚酯 - 碳酸酯组合物，其包含：（i）氟化聚烯烃; 和（ii）至少一种不含卤素的含共聚酯 - 碳酸酯树脂，其衍生自（a）碳酸酯前体，（b）至少一种无卤素，无硫和非多环二元酚，（c） 至少一种无卤素的硫代二酚，和（d）至少一种双官能羧酸或其活性衍生物。

公开(公告)号：US4467121A

公开(公告)日：1984-08-21

申请号：US402165

申请日：1982-07-26

Applicant: Victor Mark ,  Charles V. Hedges

Inventor： Victor Mark ,  Charles V. Hedges

IPC: C07C37/11 ,  C07C37/20 ,  C07C39/367 ,  C07C39/16

CPC classification number: C07C37/115 ,  C07C37/16 ,  C07C37/20 ,  C07C39/367

Abstract: Fluorinated bisphenols having a fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are prepared at atmospheric pressure or at low pressures from a phenol reactant and a fluorinated aldehyde compound in the presence of gaseous hydrogen chloride or gaseous hydrogen bromide catalyst. The fluorinated bisphenols having the fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are produced in excellent yields and are used for making flame-retardant polycarbonates and polyester-carbonate copolymers.

Abstract translation: 在气态氯化氢或溴化氢气体气体催化剂存在下，在大气压或低压下由苯酚反应物和氟化醛化合物制备具有氟代烷基和亚甲基碳原子上的氢原子的氟化双酚。 具有氟代烷基和亚甲基碳原子上的氢原子的氟化双酚以优异的收率生产，并用于制备阻燃聚碳酸酯和聚酯 - 碳酸酯共聚物。