公开(公告)号：US07341762B2

公开(公告)日：2008-03-11

申请号：US10338520

申请日：2003-01-08

申请人： Daniel Bode ,  Timothy I. Memmer ,  Deborah L. Howard

发明人： Daniel Bode ,  Timothy I. Memmer ,  Deborah L. Howard

IPC分类号： B05D7/14

CPC分类号： C09D5/00 ,  C08L23/00 ,  C08L23/06 ,  C08L91/06 ,  C08L91/08 ,  C09D7/65 ,  C09D163/00 ,  C08L2666/02 ,  C08L2666/04

摘要： A protective coating composition and a method for coating a metal substrate are provided. The composition and method are particularly suitable for coating can ends. The coating composition includes a film-forming polymer that includes an epoxy-based resin, a lubricant system, and a solvent or water component or mixture of solvent and water. The lubricant system includes a first surface modifier that reduces the coefficient of friction and a second surface modifier that reduces the abrasion of the cured coating.

摘要翻译： 提供保护涂料组合物和涂覆金属基材的方法。 组合物和方法特别适用于涂覆罐端。 涂料组合物包括包含环氧基树脂，润滑剂体系和溶剂或水组分或溶剂和水的混合物的成膜聚合物。 润滑剂系统包括减少摩擦系数的第一表面改性剂和减少固化涂层的磨损的第二表面改性剂。

公开(公告)号：US20080139716A1

公开(公告)日：2008-06-12

申请号：US12021379

申请日：2008-01-29

申请人： Daniel Bode ,  Timothy I. Memmer ,  Deborah L. Howard

发明人： Daniel Bode ,  Timothy I. Memmer ,  Deborah L. Howard

IPC分类号： C09D163/00 ,  C09D123/10 ,  C09D123/04 ,  C09D123/02

CPC分类号： C09D5/00 ,  C08L23/00 ,  C08L23/06 ,  C08L91/06 ,  C08L91/08 ,  C09D7/65 ,  C09D163/00 ,  C08L2666/02 ,  C08L2666/04

摘要： A protective coating composition and a method for coating a metal substrate are provided. The composition and method are particularly suitable for coating can ends. The coating composition includes a film-forming polymer that includes an epoxy-based resin, a lubricant system, and a solvent or water component or mixture of solvent and water. The lubricant system includes a first surface modifier that reduces the coefficient of friction and a second surface modifier that reduces the abrasion of the cured coating.

摘要翻译： 提供保护涂料组合物和涂覆金属基材的方法。 组合物和方法特别适用于涂覆罐端。 涂料组合物包括包含环氧基树脂，润滑剂体系和溶剂或水组分或溶剂和水的混合物的成膜聚合物。 润滑剂系统包括减少摩擦系数的第一表面改性剂和减少固化涂层的磨损的第二表面改性剂。

公开(公告)号：US20130281574A1

公开(公告)日：2013-10-24

申请号：US13996600

申请日：2011-12-28

申请人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

发明人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

IPC分类号： C09D133/04

CPC分类号： C09D133/04 ,  B65D25/14 ,  C08F2/001 ,  C08F2/22 ,  C08F265/06 ,  C09D5/20 ,  C09D133/062 ,  C09D133/068 ,  C09D151/003 ,  C08F220/18 ,  C08F220/32 ,  C08F220/28

摘要： Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.

摘要翻译： 公开了可用于形成不具有水敏性的涂料组合物的乳胶乳液，其具有良好的抗沾红和耐蒸煮性能。 在一些实施方案中，涂料组合物用于涂覆底物例如罐和包装材料以储存食品和饮料。 本发明的涂料组合物可以通过在载体中聚合至少一种烯键式不饱和单体组分，包含强酸和引发剂的稳定剂以形成乳液，使乳液与至少一种不同的烯属不饱和单体组分聚合以制备 复合胶乳乳液，并使复合胶乳乳液与中和剂反应形成涂料组合物。 还公开了用涂料组合物涂布基材的方法和涂覆有涂料组合物的基材。

公开(公告)号：US09181448B2

公开(公告)日：2015-11-10

申请号：US13996600

申请日：2011-12-28

申请人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

发明人： Cathy Li ,  Tiffany Weidendorf ,  Timothy I. Memmer ,  Daniel Bode

IPC分类号： C09D151/00 ,  C08F6/14 ,  C08F2/00 ,  C08F2/22 ,  C09D133/06 ,  B65D25/14 ,  C09D133/04 ,  C09D5/20 ,  C08F265/06

CPC分类号： C09D133/04 ,  B65D25/14 ,  C08F2/001 ,  C08F2/22 ,  C08F265/06 ,  C09D5/20 ,  C09D133/062 ,  C09D133/068 ,  C09D151/003 ,  C08F220/18 ,  C08F220/32 ,  C08F220/28

摘要： Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.

摘要翻译： 公开了乳胶乳液，其可用于形成不具有水敏感性，具有良好抗腮红性和耐蒸煮性的涂料组合物。 在一些实施方案中，涂料组合物用于涂覆底物例如罐和包装材料以储存食品和饮料。 本发明的涂料组合物可以通过在载体中聚合至少一种烯键式不饱和单体组分，包含强酸和引发剂的稳定剂以形成乳液，使乳液与至少一种不同的烯属不饱和单体组分聚合以制备 复合胶乳乳液，并使复合胶乳乳液与中和剂反应形成涂料组合物。 还公开了用涂料组合物涂布基材的方法和涂覆有涂料组合物的基材。

公开(公告)号：US4609706A

公开(公告)日：1986-09-02

申请号：US716699

申请日：1985-03-27

申请人： Daniel Bode ,  Henry J. DeGraaf

发明人： Daniel Bode ,  Henry J. DeGraaf

IPC分类号： C08G18/42 ,  C08G18/81 ,  C08L33/06 ,  C08L67/08 ,  C09D133/06 ,  C09D167/08 ,  C08L33/08

CPC分类号： C09D133/062 ,  C08G18/4288 ,  C08G18/8108 ,  C09D167/08 ,  C08L2205/02 ,  C08L33/062 ,  C08L67/08

摘要： High solids alkyd resin coatings are prepared by reacting at least a portion of the available hydroxyl groups on a resin with an ethylenically unsaturated monoisocyanate monomer. The new products, useful both as the major vehicle resin in high solids coatings and as a cure modifier for oxidatively curable alkyd, polyester and acrylic resins, impart improved drying and weathering properties to coatings while maintaining low paint viscosity.

摘要翻译： 通过使树脂上的至少一部分可用的羟基与烯属不饱和单异氰酸酯单体反应来制备高固含量的醇酸树脂涂料。 作为高固含量涂料中的主要载体树脂和用于氧化可固化的醇酸树脂，聚酯和丙烯酸树脂的固化改性剂的新产品在保持低涂料粘度的同时赋予涂料更好的干燥和耐候性能。

公开(公告)号：US5418292A

公开(公告)日：1995-05-23

申请号：US158655

申请日：1993-11-29

申请人： Daniel Bode ,  Perry A. Toman ,  Henry J. DeGraaf ,  Susan M. Miller

发明人： Daniel Bode ,  Perry A. Toman ,  Henry J. DeGraaf ,  Susan M. Miller

IPC分类号： C08L67/00 ,  C09D133/06 ,  C08L37/00

CPC分类号： C09D133/068 ,  C08L67/00 ,  Y10S525/934

摘要： Clear and pigmented powder paint coatings are based on a thermosetting polymeric binder comprising low molecular weight, carboxylic acid functional, crystalline polyester and a coreactive glycidyl functional addition copolymer, preferably and glycidyl functional acrylic copolymer.

摘要翻译： 透明和着色的粉末涂料基于包含低分子量羧酸官能的结晶聚酯和核心缩水甘油基官能加成共聚物，优选和缩水甘油基官能丙烯酸共聚物的热固性聚合物粘合剂。

公开(公告)号：US4683273A

公开(公告)日：1987-07-28

申请号：US867050

申请日：1986-05-27

申请人： Daniel Bode

发明人： Daniel Bode

IPC分类号： C09D151/08 ,  C09D163/00 ,  C08L63/10

CPC分类号： C09D151/08 ,  C09D163/00

摘要： Polymer composition particularly useful as protective surface coatings comprise an aqueous mixture of epoxy-acrylic graft copolymers combined with a functional low molecular weight polyester and minor amounts of an amine derivative crosslinking resin. The low molecular weight polyester contains reactive hydroxyl or carboxyl functional groups and a molecular weight less than about 2,000.

摘要翻译： 特别可用作保护性表面涂层的聚合物组合物包含与功能性低分子量聚酯和少量胺衍生物交联树脂结合的环氧 - 丙烯酸接枝共聚物的水性混合物。 低分子量聚酯含有反应性羟基或羧基官能团，分子量小于约2,000。

公开(公告)号：US08247051B2

公开(公告)日：2012-08-21

申请号：US11497003

申请日：2006-08-01

申请人： Daniel Bode ,  Cathy Li ,  Kenneth J. Gardner

发明人： Daniel Bode ,  Cathy Li ,  Kenneth J. Gardner

IPC分类号： B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/38

CPC分类号： C09D163/00 ,  C08L61/20 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/24802 ,  Y10T428/24851 ,  Y10T428/24893 ,  Y10T428/24901 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31515 ,  Y10T428/31522 ,  Y10T428/31529 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31938 ,  C08L2666/16

摘要： A coating composition is provided for use in laminate substrates useful in packaging of liquids and solids where the coating provides and increased resistance to the permeability of gases such as oxygen and carbon dioxide. In one embodiment the coating composition is a dispersion or a solution that comprises at least one hydroxyl functional polyetheramine, phosphoric acid and a defoamer. The backbone of the polyetheramine has diglycidyl ether linkages that comprise about 5 to about 70 mole percent resorcinol diglycidyl ether. The coating composition can be applied to substrates by coating applications such as spraying, rolling reverse and direct, rolling direct and reverse gravure, kiss coat, flow coating, brushing, dipping and curtain-wall coating, for example.

摘要翻译： 提供涂料组合物用于层压基材，其可用于包装液体和固体，其中涂层提供并增加对诸如氧气和二氧化碳的气体的渗透性的抵抗性。 在一个实施方案中，涂料组合物是包含至少一种羟基官能聚醚胺，磷酸和消泡剂的分散体或溶液。 聚醚胺的主链具有包含约5至约70摩尔％间苯二酚二缩水甘油醚的二缩水甘油醚键。 涂料组合物可以通过例如喷涂，滚轧，直接轧制，直接和逆向凹版，接触涂层，流涂，刷涂，浸涂和幕墙涂覆等涂布应用于基材。

公开(公告)号：US20070031673A1

公开(公告)日：2007-02-08

申请号：US11497003

申请日：2006-08-01

申请人： Daniel Bode ,  Cathy Li ,  Kenneth Gardner

发明人： Daniel Bode ,  Cathy Li ,  Kenneth Gardner

IPC分类号： B32B27/34 ,  B32B27/36 ,  B32B27/32

CPC分类号： C09D163/00 ,  C08L61/20 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/24802 ,  Y10T428/24851 ,  Y10T428/24893 ,  Y10T428/24901 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31515 ,  Y10T428/31522 ,  Y10T428/31529 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31938 ,  C08L2666/16

摘要： A coating composition is provided for use in laminate substrates useful in packaging of liquids and solids where the coating provides and increased resistance to the permeability of gases such as oxygen and carbon dioxide. In one embodiment the coating composition is a dispersion or a solution that comprises at least one hydroxyl functional polyetheramine, phosphoric acid and a defoamer. The backbone of the polyetheramine has diglycidyl ether linkages that comprise about 5 to about 70 mole percent resorcinol diglycidyl ether. The coating composition can be applied to substrates by coating applications such as spraying, rolling reverse and direct, rolling direct and reverse gravure, kiss coat, flow coating, brushing, dipping and curtain-wall coating, for example.

摘要翻译： 提供涂料组合物用于层压基材，其可用于包装液体和固体，其中涂层提供并增加对诸如氧气和二氧化碳的气体的渗透性的抵抗性。 在一个实施方案中，涂料组合物是包含至少一种羟基官能聚醚胺，磷酸和消泡剂的分散体或溶液。 聚醚胺的主链具有包含约5至约70摩尔％间苯二酚二缩水甘油醚的二缩水甘油醚键。 涂料组合物可以通过例如喷涂，滚轧，直接轧制，直接和逆向凹版，接触涂层，流涂，刷涂，浸涂和幕墙涂覆等涂布应用于基材。

公开(公告)号：US06306934B1

公开(公告)日：2001-10-23

申请号：US09280639

申请日：1999-03-29

申请人： Daniel Bode ,  Deborah Howard ,  Christopher Bradley ,  Martin Belton

发明人： Daniel Bode ,  Deborah Howard ,  Christopher Bradley ,  Martin Belton

IPC分类号： C08K318

CPC分类号： C08F290/144 ,  C09D151/003 ,  C08L2666/02

摘要： A protective coating composition for coating interior surfaces of beer, beverage, and food containers, as well as interior and exterior surfaces of can ends, comprises a polymeric binder of emulsion copolymerized ethylenic monomers in the presence of an unsaturated polyester dispersed into water with an aqueous dispersed epoxy-acrylic graft copolymer dispersant. The preferred polymeric binder comprises by weight between 0.1% and 40% unsaturated polyester, between 20% and 80% emulsion copolymerized ethylenic unsaturated monomers, and at least 20% dispersant, where the emulsion copolymerized monomers crosslink with the water dispersed unsaturated polyester.

摘要翻译： 用于涂覆啤酒，饮料和食品容器的内表面以及罐端部的内表面和外表面的保护性涂料组合物包含在分散于水中的不饱和聚酯与水分散的乳液共聚乙烯类单体的聚合物粘合剂 分散环氧丙烯酸接枝共聚物分散剂。 优选的聚合物粘合剂包含重量百分比为0.1％至40％的不饱和聚酯，20％至80％的乳液共聚的烯属不饱和单体和至少20％的分散剂，其中乳液共聚单体与水分散的不饱和聚酯交联。