公开(公告)号：US10103314B2

公开(公告)日：2018-10-16

申请号：US15563899

申请日：2016-03-24

Applicant: CANON KABUSHIKI KAISHA

Inventor： Kaoru Miura ,  Miki Ueda ,  Takayuki Watanabe ,  Shunsuke Murakami ,  Jumpei Hayashi ,  Makoto Kubota

IPC: H01L27/20 ,  H01L41/187 ,  H01L41/083 ,  B41J2/14 ,  C04B35/626

Abstract: The piezoelectric material of the present invention includes a main component composed of a perovskite-type metal oxide represented by Formula (1), at least one of Mn and Ni, and Mg. The content of Ni is 0 mol or more and 0.05 mol or less based on 1 mol of the perovskite-type metal oxide, and the content of Mn is 0 mol or more and 0.005 mol or less based on 1 mol of the perovskite-type metal oxide, provided that the content of Mn and the content of Ni are not simultaneously 0 mol. The content of Mg is 0.001 mol or more and 0.020 mol or less based on 1 mol of the perovskite-type metal oxide.Formula (1): (NaxBa1-y)(NbyTi1-y)O3 (where x is 0.83 or more and 0.95 or less, y is 0.85 or more and 0.95 or less, and x/y is 0.95 or more and 1.05 or less).

公开(公告)号：US10074796B2

公开(公告)日：2018-09-11

申请号：US15563892

申请日：2016-03-24

Applicant: CANON KABUSHIKI KAISHA

Inventor： Miki Ueda ,  Kaoru Miura ,  Takayuki Watanabe ,  Shunsuke Murakami ,  Jumpei Hayashi ,  Makoto Kubota

IPC: H01L41/04 ,  H01L41/187 ,  C04B35/626 ,  H01L41/083

CPC classification number: H01L41/1873 ,  B08B7/028 ,  B41J2/14274 ,  B41J2202/03 ,  C04B35/495 ,  C04B35/62695 ,  C04B2235/3201 ,  C04B2235/3206 ,  C04B2235/3215 ,  C04B2235/3232 ,  C04B2235/3267 ,  C04B2235/3284 ,  C04B2235/6025 ,  C04B2235/6567 ,  C04B2235/72 ,  C04B2235/77 ,  C04B2235/786 ,  C04B2235/80 ,  C04B2237/34 ,  C04B2237/68 ,  H01L41/083 ,  H01L41/0973 ,  H01L41/43 ,  H02N2/106 ,  H02N2/163

Abstract: The piezoelectric material of the present invention includes a main component composed of a perovskite-type metal oxide represented by Formula (1), Zn, and Mg. The content of Zn is 0.005 mol or more and 0.050 mol or less based on 1 mol of the perovskite-type metal oxide, and the content of Mg is 0.001 mol or more and 0.020 mol or less based on 1 mol of the perovskite-type metal oxide.Formula (1): (NaxBa1-y)(NbyTi1-y)O3 (where x is 0.83 or more and 0.95 or less, y is 0.85 or more and 0.95 or less, and x/y is 0.95 or more and 1.05 or less).

公开(公告)号：US09981292B2

公开(公告)日：2018-05-29

申请号：US14723870

申请日：2015-05-28

Applicant: CANON KABUSHIKI KAISHA

Inventor： Takanori Matsuda ,  Takayuki Watanabe ,  Shunsuke Murakami ,  Hiroshi Saito ,  Tatsuo Furuta

IPC: H01L41/00 ,  B08B7/02 ,  G02B7/10 ,  G02B27/00 ,  B41J2/14 ,  B41J2/16 ,  H01L41/43 ,  H01L41/187 ,  H01L41/257 ,  H01L41/273 ,  H01L41/047 ,  H02N2/10

CPC classification number: B08B7/02 ,  B41J2/14233 ,  B41J2/14274 ,  B41J2/161 ,  B41J2/1612 ,  B41J2/1632 ,  B41J2/1637 ,  B41J2/1642 ,  B41J2/1646 ,  B41J2202/03 ,  G02B7/10 ,  G02B27/0006 ,  H01L41/0471 ,  H01L41/1871 ,  H01L41/257 ,  H01L41/273 ,  H01L41/43 ,  H02N2/103 ,  Y10T29/43

Abstract: The present invention can provide a lead-free piezoelectric material having a high piezoelectric constant in the room temperature range. The present invention for this purpose is a piezoelectric material including a main component containing a perovskite metal oxide represented by following general formula (1), Baa(Ti1-xZrx)O3  (1) where 0.02≤x≤0.13 and 0.986≤a≤1.02, a first auxiliary component containing Mn, and a second auxiliary component containing trivalent Bi, wherein an amount of the contained Mn is 0.0020 moles or more and 0.0150 moles or less relative to 1 mole of the metal oxide, and an amount of the contained Bi is 0.00042 moles or more and 0.00850 moles or less relative to 1 mole of the metal oxide.

公开(公告)号：US20170373244A1

公开(公告)日：2017-12-28

申请号：US15625209

申请日：2017-06-16

Applicant: CANON KABUSHIKI KAISHA

Inventor： Hisato Yabuta ,  Toshihiro Ifuku ,  Takanori Matsuda ,  Takayuki Watanabe ,  Makoto Kubota ,  Tatsuo Furuta ,  Hidenori Tanaka

IPC: H01L41/187 ,  B08B7/02 ,  H02N2/10 ,  H01L41/047 ,  G02B27/00 ,  C04B35/64 ,  G02B7/09 ,  H04N5/225 ,  B41J2/14 ,  C04B35/475 ,  C04B35/626 ,  C04B35/634 ,  H04R17/00 ,  G02B7/14

Abstract: A piezoelectric material including a perovskite-type metal oxide represented by the following general formula (1); Bi; and Mn, wherein the content of Bi is 0.1-0.5 mol % with respect to 1 mol of the metal oxide, the content of Mn is 0.3-1.5 mol % with respect to 1 mol of the metal oxide, and the piezoelectric material satisfies (L4−L5)/L5≧0.05 and (L8−L9)/L9≧0.05 when the lengths of twelve Bi—O bonds with Bi that is located at a 12-fold site with respect to O in a perovskite-type unit cell as a starting point are taken to be L1 to L12 in length order: (Ba1-xM1x)(Ti1-yM2y)O3  (1) wherein 0≦x≦0.2, 0≦y≦0.1, and M1 and M2 are mutually different metal elements which have a total valence of +6 and are selected from other elements than Ba, Ti, Bi and Mn.

公开(公告)号：US20170018701A1

公开(公告)日：2017-01-19

申请号：US15280678

申请日：2016-09-29

Applicant: CANON KABUSHIKI KAISHA

Inventor： Miki Ueda ,  Takayuki Watanabe ,  Shunsuke Murakami

IPC: H01L41/187 ,  H01L41/273 ,  B06B1/06 ,  H02N2/00 ,  G02B7/04 ,  G02B27/00 ,  H01L41/083 ,  B41J2/14

CPC classification number: H01L41/1871 ,  B06B1/06 ,  B41J2/14201 ,  B41J2/14233 ,  B41J2202/03 ,  C04B35/495 ,  C04B35/62685 ,  C04B35/6455 ,  C04B2235/3201 ,  C04B2235/3215 ,  C04B2235/3232 ,  C04B2235/3236 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3267 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/449 ,  C04B2235/652 ,  C04B2235/6567 ,  C04B2235/6581 ,  C04B2235/6584 ,  C04B2235/667 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/81 ,  C04B2235/85 ,  C04B2235/96 ,  G02B7/08 ,  G02B7/102 ,  G02B27/0006 ,  H01L41/0471 ,  H01L41/0477 ,  H01L41/083 ,  H01L41/09 ,  H01L41/0973 ,  H01L41/1873 ,  H01L41/273 ,  H01L41/277 ,  H01L41/297 ,  H01L41/333 ,  H01L41/43 ,  H02N2/001 ,  H02N2/10 ,  H02N2/106 ,  H02N2/163

Abstract: The present invention provides a piezoelectric material not containing lead and potassium, showing satisfactory insulation and piezoelectricity, and having a high Curie temperature. The invention relates to a piezoelectric material includes a main component containing a perovskite-type metal oxide represented by Formula (1): (NaxBa1-y)(NbyTi1-y)O3 (wherein, 0.80≦x≦0.94 and 0.83≦y≦0.94), and an additive component containing at least one element selected from Mn and Ni, wherein the content of the Ni is 0 mol or more and 0.05 mol or less based on 1 mol of the perovskite-type metal oxide, and the content of the Mn is 0 mol or more and 0.005 mol or less based on 1 mol of the perovskite-type metal oxide.

Abstract translation: 本发明提供一种不含铅和钾的压电材料，具有令人满意的绝缘和压电性，并具有很高的居里温度。 本发明涉及包含由式（1）表示的钙钛矿型金属氧化物的主要成分：（NaxBa1-y）（NbyTi1-y）O3（其中，0.80≤x≤0.94,0.83≤y≤0.94 ）和含有选自Mn和Ni中的至少一种元素的添加成分，其中，Ni的含量相对于1摩尔钙钛矿型金属氧化物为0摩尔以上且0.05摩尔以下， 基于1摩尔钙钛矿型金属氧化物，Mn为0摩尔以上且0.005摩尔以下。

公开(公告)号：US09496484B2

公开(公告)日：2016-11-15

申请号：US14423687

申请日：2013-08-21

Applicant: CANON KABUSHIKI KAISHA

Inventor： Miki Ueda ,  Takayuki Watanabe ,  Shunsuke Murakami

IPC: H01L41/187 ,  C04B35/495 ,  C04B35/626 ,  C04B35/645 ,  H01L41/43 ,  H01L41/083 ,  H01L41/09 ,  H01L41/273 ,  H02N2/10 ,  H02N2/16 ,  B41J2/14 ,  H01L41/047 ,  H01L41/277 ,  H01L41/297 ,  H01L41/333

CPC classification number: H01L41/1871 ,  B06B1/06 ,  B41J2/14201 ,  B41J2/14233 ,  B41J2202/03 ,  C04B35/495 ,  C04B35/62685 ,  C04B35/6455 ,  C04B2235/3201 ,  C04B2235/3215 ,  C04B2235/3232 ,  C04B2235/3236 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3267 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/449 ,  C04B2235/652 ,  C04B2235/6567 ,  C04B2235/6581 ,  C04B2235/6584 ,  C04B2235/667 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/81 ,  C04B2235/85 ,  C04B2235/96 ,  G02B7/08 ,  G02B7/102 ,  G02B27/0006 ,  H01L41/0471 ,  H01L41/0477 ,  H01L41/083 ,  H01L41/09 ,  H01L41/0973 ,  H01L41/1873 ,  H01L41/273 ,  H01L41/277 ,  H01L41/297 ,  H01L41/333 ,  H01L41/43 ,  H02N2/001 ,  H02N2/10 ,  H02N2/106 ,  H02N2/163

Abstract: The present invention provides a piezoelectric material not containing lead and potassium, showing satisfactory insulation and piezoelectricity, and having a high Curie temperature. The invention relates to a piezoelectric material includes a main component containing a perovskite-type metal oxide represented by Formula (1): (NaxBa1-y)(NbyTi1-y)O3 (wherein, 0.80≦x≦0.94 and 0.83≦y≦0.94), and an additive component containing at least one element selected from Mn and Ni, wherein the content of the Ni is 0 mol or more and 0.05 mol or less based on 1 mol of the perovskite-type metal oxide, and the content of the Mn is 0 mol or more and 0.005 mol or less based on 1 mol of the perovskite-type metal oxide.

Abstract translation: 本发明提供一种不含铅和钾的压电材料，具有令人满意的绝缘和压电性，并具有很高的居里温度。 本发明涉及包含由式（1）表示的钙钛矿型金属氧化物的主要成分：（NaxBa1-y）（NbyTi1-y）O3（其中，0.80≤x≤0.94,0.83≤y≤0.94 ）和含有选自Mn和Ni中的至少一种元素的添加成分，其中，Ni的含量相对于1摩尔钙钛矿型金属氧化物为0摩尔以上且0.05摩尔以下， 基于1摩尔钙钛矿型金属氧化物，Mn为0摩尔以上且0.005摩尔以下。

公开(公告)号：US20160005952A1

公开(公告)日：2016-01-07

申请号：US14795786

申请日：2015-07-09

Applicant: CANON KABUSHIKI KAISHA

Inventor： Hidenori Tanaka ,  Takayuki Watanabe ,  Shunsuke Murakami ,  Tatsuo Furuta ,  Hisato Yabuta

IPC: H01L41/187 ,  B41J2/16 ,  H04N5/217 ,  H02N2/00 ,  B06B1/06 ,  H04N5/225 ,  H01L41/277 ,  G02B27/00

CPC classification number: H01L41/1871 ,  B06B1/06 ,  B06B1/0644 ,  B41J2/045 ,  B41J2/14 ,  B41J2/14233 ,  B41J2/1607 ,  B41J2/164 ,  B41J2202/03 ,  C04B35/4682 ,  C04B2235/3203 ,  C04B2235/3208 ,  C04B2235/3236 ,  C04B2235/3244 ,  C04B2235/3248 ,  C04B2235/3262 ,  C04B2235/3263 ,  C04B2235/3293 ,  C04B2235/3298 ,  C04B2235/3409 ,  C04B2235/3418 ,  C04B2235/365 ,  C04B2235/449 ,  C04B2235/79 ,  C04B2235/80 ,  G02B27/0006 ,  H01L41/0477 ,  H01L41/083 ,  H01L41/09 ,  H01L41/0973 ,  H01L41/183 ,  H01L41/277 ,  H02N2/10 ,  H02N2/106 ,  H02N2/16 ,  H02N2/163 ,  H02N2/22 ,  H04N5/2171 ,  H04N5/2253

Abstract: There is provided a piezoelectric material not containing any lead component, having stable piezoelectric characteristics in an operating temperature range, a high mechanical quality factor, and satisfactory piezoelectric characteristics. The piezoelectric material according to the present invention includes a main component containing a perovskite-type metal oxide that can be expressed using the following general formula (1), and subcomponents containing Mn, Li, and Bi. When the metal oxide is 100 parts by weight, the content of Mn on a metal basis is not less than 0.04 parts by weight and is not greater than 0.36 parts by weight, content α of Li on a metal basis is equal to or less than 0.0012 parts by weight (including 0 parts by weight), and content β of Bi on a metal basis is not less than 0.042 parts by weight and is not greater than 0.850 parts by weight (Ba1-xCax)a(Ti1-y-zZrySnz)O3  (1) (in the formula (1), 0.09≦x≦0.30, 0.025≦y≦0.085, 0≦z≦0.02, and 0.986≦a≦1.02).

Abstract translation: 提供了不包含任何铅成分的压电材料，在工作温度范围内具有稳定的压电特性，高机械品质因数和令人满意的压电特性。 根据本发明的压电材料包括含有可以使用以下通式（1）表示的钙钛矿型金属氧化物的主要成分，以及含有Mn，Li和Bi的亚成分。 当金属氧化物为100重量份时，以金属为基准的Mn含量为0.04重量份以上且不大于0.36重量份，金属基上的Li的含量α等于或小于 0.0012重量份（包括0重量份）和含量＆bgr; 的金属不低于0.042重量份且不大于0.850重量份（Ba1-xCax）a（Ti1-y-zZrySnz）O3（1）（在式（1）中，0.09＆nlE ; x和nlE; 0.30,0.025＆nlE; y＆nlE; 0.085,0和nlE; z和nlE; 0.02和0.986＆nlE; a＆nlE; 1.02）。

公开(公告)号：US20150368162A1

公开(公告)日：2015-12-24

申请号：US14764121

申请日：2014-01-24

Applicant: CANON KABUSHIKI KAISHA

Inventor： Jumpei Hayashi ,  Takayuki Watanabe ,  Shunsuke Murakami ,  Miki Ueda

IPC: C04B35/495 ,  H01L41/083 ,  H01L41/047 ,  H04N5/217 ,  H02N2/00 ,  B06B1/06 ,  G02B7/09 ,  G02B27/00 ,  H01L41/18 ,  B41J2/14

CPC classification number: C04B35/495 ,  B06B1/06 ,  B41J2/14201 ,  B41J2/14233 ,  B41J2202/03 ,  C04B2235/3201 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3232 ,  C04B2235/3236 ,  C04B2235/3255 ,  C04B2235/3281 ,  C04B2235/6567 ,  C04B2235/768 ,  C04B2235/786 ,  G02B7/09 ,  G02B27/0006 ,  H01L41/0471 ,  H01L41/083 ,  H01L41/0973 ,  H01L41/18 ,  H01L41/1873 ,  H01L41/43 ,  H02N2/001 ,  H02N2/106 ,  H02N2/163 ,  H04N5/2171

Abstract: There is provided a lead- and potassium-free piezoelectric material having a high piezoelectric constant and a satisfactory insulation property and a piezoelectric element that includes the piezoelectric material. The piezoelectric material contains a perovskite-type metal oxide having the general formula (1): (NaxBa1-y)(NbyTi1-y)O3 (wherein x satisfies 0.80≦x≦0.95, and y satisfies 0.85≦y≦0.95); and at least one rare-earth element selected from La, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, wherein the rare-earth element content is more than 0 mol % and 5 mol % or less of the amount of perovskite-type metal oxide. The piezoelectric element includes the piezoelectric material.

Abstract translation: 提供具有高压电常数和令人满意的绝缘性能的无铅和无钾的压电材料和包括压电材料的压电元件。 压电材料含有具有通式（1）：（NaxBa1-y）（NbyTi1-y）O3（其中x满足0.80＆amp; nlE; x＆lt; ll; 0.95，y满足0.85＆nlE; y＆nlE; 0.95）的钙钛矿型金属氧化物， ; 以及选自La，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu中的至少一种稀土元素，其中稀土元素含量大于0 mol％和5mol％以下的钙钛矿型金属氧化物。 压电元件包括​​压电材料。

公开(公告)号：US20150221856A1

公开(公告)日：2015-08-06

申请号：US14423687

申请日：2013-08-21

Applicant: CANON KABUSHIKI KAISHA

Inventor： Miki Ueda ,  Takayuki Watanabe ,  Shunsuke Murakami

IPC: H01L41/187 ,  H01L41/09 ,  H01L41/273 ,  H01L41/277 ,  H01L41/297 ,  H01L41/333 ,  H01L41/047 ,  B41J2/14

CPC classification number: H01L41/1871 ,  B06B1/06 ,  B41J2/14201 ,  B41J2/14233 ,  B41J2202/03 ,  C04B35/495 ,  C04B35/62685 ,  C04B35/6455 ,  C04B2235/3201 ,  C04B2235/3215 ,  C04B2235/3232 ,  C04B2235/3236 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3267 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/449 ,  C04B2235/652 ,  C04B2235/6567 ,  C04B2235/6581 ,  C04B2235/6584 ,  C04B2235/667 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/81 ,  C04B2235/85 ,  C04B2235/96 ,  G02B7/08 ,  G02B7/102 ,  G02B27/0006 ,  H01L41/0471 ,  H01L41/0477 ,  H01L41/083 ,  H01L41/09 ,  H01L41/0973 ,  H01L41/1873 ,  H01L41/273 ,  H01L41/277 ,  H01L41/297 ,  H01L41/333 ,  H01L41/43 ,  H02N2/001 ,  H02N2/10 ,  H02N2/106 ,  H02N2/163

Abstract: The present invention provides a piezoelectric material not containing lead and potassium, showing satisfactory insulation and piezoelectricity, and having a high Curie temperature. The invention relates to a piezoelectric material includes a main component containing a perovskite-type metal oxide represented by Formula (1): (NaxBa1-y)(NbyTi1-y)O3 (wherein, 0.80≦x≦0.94 and 0.83≦y≦0.94), and an additive component containing at least one element selected from Mn and Ni, wherein the content of the Ni is 0 mol or more and 0.05 mol or less based on 1 mol of the perovskite-type metal oxide, and the content of the Mn is 0 mol or more and 0.005 mol or less based on 1 mol of the perovskite-type metal oxide.

Abstract translation: 本发明提供一种不含铅和钾的压电材料，具有令人满意的绝缘和压电性，并具有很高的居里温度。 本发明涉及包含由式（1）表示的钙钛矿型金属氧化物的主要成分：（NaxBa1-y）（NbyTi1-y）O3（其中，0.80＆nlE; x＆nlE; 0.94和0.83＆nlE; y＆ ; 0.94）和含有选自Mn和Ni中的至少一种元素的添加成分，其中Ni的含量相对于1摩尔钙钛矿型金属氧化物为0摩尔以上且0.05摩尔以下，含量 的Mn为1摩尔以上的钙钛矿型金属氧化物为0摩尔以上且0.005摩尔以下。

公开(公告)号：US09050799B2

公开(公告)日：2015-06-09

申请号：US14139297

申请日：2013-12-23

Applicant: CANON KABUSHIKI KAISHA

Inventor： Takayuki Watanabe ,  Shunsuke Murakami ,  Tatsuo Furuta

IPC: H04N5/225 ,  H04N9/04 ,  H01L41/00 ,  B41J2/045 ,  B41J2/14 ,  C04B35/468 ,  H01L41/43 ,  H01L41/09 ,  H01L41/187 ,  H02N2/10 ,  H02N2/16 ,  H01L41/047 ,  C04B35/626

Abstract: A piezoelectric material includes a metal oxide represented by general formula (1) below, a Mn content is 0.04 parts by weight or more and 0.36 parts by weight or less, a Li content α is 0.0013 parts by weight or more and 0.0280 parts by weight or less, a Bi content β is 0.042 parts by weight or more and 0.850 parts by weight or less, and the contents α and β satisfy 0.5≦(α·MB)/(β·ML)≦1 (Ba1-xCax)a(Ti1-y-zZrySnz) O3 (1) (where x, y, z, and a satisfy 0.09≦x≦0.30, 0.025≦y≦0.074, 0≦z≦0.02, and 0.986≦a≦1.02).A piezoelectric material according to an embodiment of the present invention contains no lead, has a low degree of temperature dependency of piezoelectric performance within operation temperature ranges of piezoelectric elements, and good piezoelectric properties.