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1.发明授权
公开(公告)号：US3864076A
公开(公告)日：1975-02-04
申请号：US28517372
申请日：1972-08-31
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
IPC: D06M15/673 , B27K3/15 , C07F9/54 , C08L61/32 , D06M15/431 , D06M15/667 , D06M1/00
CPC classification number: D06M15/667 , B27K3/15 , B27K2240/30 , C07F9/54 , C08L61/32 , D06M15/431 , Y10S428/921 , Y10T428/2938
Abstract: The subject of the invention is a process for the manufacture of condensation products of hydroxymethylphosphonium compounds and guanidines, characterised in that (a) 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.5 mol, preferably 0.1 to 0.3 mol, of guanidine, guanidine salt, guanylurea, guanylurea salt or methylolated guanidine or guanylurea at 40* to 120*C, optionally in the presence of formaldehyde or a formaldehyde-donating agent and optionally in the presence of an inert organic solvent, optionally subsequently further condensed at temperatures of 100* to 150*C and, if appropriate, free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.
Abstract translation: 本发明的主题是制备羟甲基鏻化合物和胍的缩合产物的方法，其特征在于：（a）1摩尔四（羟甲基）鏻化合物与（b）0.02至0.5摩尔，优选 0.1至0.3mol的胍，胍盐，脒基脲，脒基脲盐或羟甲基化胍或脒基脲，任选在甲醛或甲醛给药剂存在下，任选在惰性有机溶剂存在下，于40℃至120℃ 任选地随后在100至150℃的温度下进一步冷凝，如果合适的话，游离羟基与至少一种具有1-4个碳原子的链烷醇至少部分醚化，如果合适，将缩合产物的盐转化为 相应的氢氧化物。
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2.发明授权Stable preparations of reaction products of epoxides, fatty amines and dicarboxylic acids 失效环氧化物，脂肪胺和二羧酸的反应产物的稳定制备
公开(公告)号：US3909494A
公开(公告)日：1975-09-30
申请号：US36025273
申请日：1973-05-14
Applicant: CIBA GEIGY AG
Inventor： TOEPFL ROSEMARIE , ABEL HEINZ , MAEDER ARTHUR
Abstract: Stable preparations are provided containing reaction products obtained by reacting in the presence of an organic solvent (a) (a) epoxides containing at least two epoxide groups per molecule with (b) fatty amines with 12 to 24 carbon atoms and (c) aliphatic dicarboxylic acids with at least 7 carbon atoms and optionally (c'') anhydrides of aromatic dicarboxylic acids or aliphatic monocarboxylic or dicarboxylic acids, (d) aliphatic diols with 2 to 22 carbonatoms (e) polyfunctional compounds containing halogen atoms, vinyl, ester, acid, nitrile hydroxyl or epoxide groups and (f) an aminoplast precondensate containing alkylether groups. Said reaction products contain free carboxyl groups and optionally ammonia or an organic base is added so that a sample of the reaction mixture - after adding some water to enable a pH-reading - has a pH-value of 7.5 to 12. The stable preparations are useful to finishing textile materials, especially to rendering wool non-felting.
Abstract translation: 含有通过在有机溶剂（a）（a）每分子含有至少两个环氧基团的环氧化物存在下反应获得的反应产物，（b）具有12至24个碳原子的脂肪胺和（c）脂族二羧酸 具有至少7个碳原子的酸和芳香族二羧酸或脂肪族单羧酸或二羧酸的任选（c'）酸酐，（d）具有2至22个碳原子的脂肪族二醇（e）含有卤素原子的多官能化合物，乙烯基，酯，酸， 腈羟基或环氧基团和（f）含有烷基醚基团的氨基塑料预缩合物。 所述反应产物含有游离羧基，任选地加入氨或有机碱，使得反应混合物样品 - 加入一些水以进行pH读数后，pH值为7.5至12.稳定的制剂是 用于整理纺织材料，特别是使羊毛不起毛。
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3.发明授权
公开(公告)号：US3903336A
公开(公告)日：1975-09-02
申请号：US28515072
申请日：1972-08-31
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
IPC: D06M15/673 , D06M15/415 , D06M15/431 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/16 , D06M101/30 , D06M101/32 , C09D1/00 , C09D3/52 , C09D5/18
CPC classification number: D06M15/431 , D06M15/415
Abstract: The subject of the invention is the use of watersoluble condensation products of (a) 1 mol of a tetrakis-(hydroxymethyl)-phosphonium compound and (b) 0.02 to 1 mol, preferably 0.2 to 1 mol or especially 0.3 to 0.6 mol, of methylolated urea or its alkyl-ethers, preferably dimethylolurea, as flameproofing agents for fibre mixtures of polyester and cellulose.
Abstract translation: 本发明的主题是使用（a）1摩尔四（羟基 - 甲基） - 鏻化合物和（b）0.02-1摩尔，优选0.2-1摩尔，特别是0.3-0.6摩尔的水溶性缩合产物 的羟甲基化脲或其烷基醚，优选二羟甲基脲，作为聚酯和纤维素纤维混合物的防火剂。
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公开(公告)号：US3860540A
公开(公告)日：1975-01-14
申请号：US25416672
申请日：1972-05-17
Applicant: CIBA GEIGY AG
Inventor： ABEL HEINZ , HOSTETTLER HANS , BERGER ALFRED , TOEPFL ROSEMARIE , MAEDER ARTHUR
Abstract: A process for rendering wool non-felting is provided wherein wool is treated at 20* to 100*C with aqueous preparations which contain a) reaction products of epoxides with at least two epoxide groups per molecule and fatty amines with basic polyamides or dicarboxylic acids and b) adducts of fatty amines with 12 to 22 carbon atoms and 6 to 30 mols of ethylene oxide, esterified with at least dibasic oxygen-containing acids.
Abstract translation: 提供了一种提供羊毛非毡化的方法，其中羊毛在20℃至100℃下用水性制剂处理，其含有a）每分子具有至少两个环氧基团的环氧化物的反应产物和具有碱性聚酰胺或二羧酸的脂肪胺， b）具有12至22个碳原子的脂肪胺和6至30摩尔环氧乙烷的加合物，用至少二元含氧酸酸化。
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公开(公告)号：US3887553A
公开(公告)日：1975-06-03
申请号：US28538372
申请日：1972-08-31
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
IPC: D06M15/673 , B27K3/15 , C07F9/6521 , C08L61/32 , D06M15/431 , D06M15/667 , C07D55/24
CPC classification number: D06M15/667 , B27K3/15 , B27K2240/30 , C07F9/65212 , C08L61/32 , D06M15/431 , Y10S428/921
Abstract: The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethylphosphonium compounds and a 1,3,5-triazine characterised in that (a) 1 mol of a tetrakis-(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.1 mol, preferably 0.05 to 0.1 mol of optionally methylolated 1,3,5-triazine which is substituted by at least one primary amino group, at 40* to 120*C, optionally in the presence of formaldehyde or a formaldehyde-releasing agent and optionally in the presence of an inert organic solvent, the condensation is optionally thereafter continued at temperatures of 100* to 150*C and, if appropriate, free hydroxyl groups are etherified at least partially with at least one alkanol with 1 to 4 carbon atoms and, if appropriate, the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.
Abstract translation: 本发明的主题是制备羟甲基鏻化合物和1,3,5-三嗪的水溶性缩合产物的方法，其特征在于：（a）将1摩尔四（羟甲基）鏻化合物与 （b）任选在甲醛或甲醛存在下，在40至120℃下，0.02至0.1摩尔，优选0.05至0.1摩尔任意羟基化的1,3,5-三嗪，其被至少一个伯氨基取代， 甲醛释放剂，任选地在惰性有机溶剂的存在下，任选地在100-150℃的温度下继续冷凝，如果合适的话，游离羟基至少部分用至少一种链烷醇醚化1 至4个碳原子，如果合适，则缩合产物的盐转化为相应的氢氧化物。
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Patent Agency Ranking6.发明授权
公开(公告)号：US3878245A
公开(公告)日：1975-04-15
申请号：US28529572
申请日：1972-08-31
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
IPC: D06M15/673 , B27K3/15 , C07F9/54 , C08L61/32 , D06M15/431 , D06M15/432 , D06M15/667 , C07C127/00
CPC classification number: D06M15/667 , B27K3/15 , B27K2240/30 , C07F9/54 , C07F9/5407 , C08L61/32 , D06M15/431 , D06M15/432
Abstract: The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethyl-phosphonium compounds, characterised in that (a) 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.2 mol, preferably 0.05 to 0.15 mol, of urea at 40* to 120*C and optionally in the presence of an inert organic solvent and if appropriate free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.
Abstract translation: 本发明的主题是制备羟甲基鏻化合物的水溶性缩合产物的方法，其特征在于：（a）1摩尔四（羟甲基）鏻化合物与（b）0.02至0.2 mol，优选0.05至0.15mol尿素，任选在惰性有机溶剂存在下，如果合适的游离羟基至少部分用至少一个具有1-4个碳原子的链烷醇醚化，并且 如果适当，缩合产物的盐转化成相应的氢氧化物。
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公开(公告)号：US3700403A
公开(公告)日：1972-10-24
申请号：US3700403D
申请日：1971-01-12
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
IPC: C07F9/40 , D06M13/288 , D06M13/32 , D06M15/54
CPC classification number: D06M13/288 , C07F9/4006 , Y10S8/04 , Y10S8/21 , Y10S260/24
Abstract: THE PRESENT INVENTION RELATES TO A PROCESS FOR RENDERING CELLULOSE-CONTAINING FIBROUS MATERIALS FLAMEPROOF, WHICH COMPRISES APPLYING TO SAID MATERIALS AN AQUEOUS PREPARATION CONTAINING PHOSPHORUS-CONTAINING N,N-DIMETHYLOLCARBOXYLIC ACID AMIDES. THE FLAMEPROOF FINISH IS RESISTANT TO WASHING AND DRY-CLEANING AND IMPROVES THE DRY CREASE ANGLE AND THE WET CREASE ANGLE OF THE FINISHED MATERIAL.
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公开(公告)号：US3679779A
公开(公告)日：1972-07-25
申请号：US3679779D
申请日：1970-01-22
Applicant: CIBA GEIGY AG
Inventor： HUBER-EMDEN HELMUT , ESCHLE KARL , MAEDER ARTHUR
IPC: C08L23/00 , C07F9/38 , C07F9/40 , C08K5/49 , C08K5/53 , C08K5/5353 , C08L1/00 , C08L7/00 , C08L21/00 , C08L27/00 , C08L101/00 , C09K15/32
CPC classification number: C08K5/5353 , C07F9/4006
Abstract: IN WHICH R denotes an alkyl radical with one to 18 carbon atoms and n denotes 1 or 2. These phosphonic acid dialkyl esters are used as antioxidants for plastics, especially for polypropylene, polyethylene and polyurethane, and rubber. The combined use of the phosphonic acid dialkyl esters with flameproofing agents, may increase the flameproofing action of the flameproofing agent. The use of the compounds according to the invention in combination with other antioxidants also may show advantageous effects.
The subject of the invention is phosphonic acid dialkyl esters of the formulaAbstract translation: 本发明的主题是下式的膦酸二烷基酯，其中R表示具有1至18个碳原子的烷基，n表示1或2.这些膦酸二烷基酯用作塑料的抗氧化剂，特别是用于聚丙烯，聚乙烯 和聚氨酯和橡胶。 将膦酸二烷基酯与防火剂联合使用可能会增加防火剂的防火作用。 根据本发明的化合物与其它抗氧化剂的组合的使用也可以显示有益的效果。
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公开(公告)号：US3679778A
公开(公告)日：1972-07-25
申请号：US3679778D
申请日：1969-12-16
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , MAEDER ARTHUR
CPC classification number: D06M13/288 , C07F9/4006
Abstract: Phosphorus compounds are provided which correspond to the formula
WHEREIN EACH R is an alkyl, alkenyl or halogenalkyl radical, X and X'' each is a methyl radical or a hydrogen atom, Y and Y'' each is an alkyl radical or a hydrogen atom and A is an alkyl, halogenalkyl, hydroxyalkyl or a phenyl or benzyl group which both may be halogen substituted. The phosphorus compounds are manufactured from the corresponding phosphorus carboxylic acid amides and carbamates and formaldehyde. These compounds optionally together with a curable aminoplast precondensate are useful for flameproofing and creaseproofing of cellulosecontaining fiber materials.Abstract translation: 提供了对应于下式的磷化合物：其中R是烷基，烯基或卤代烷基，X和X'各自为甲基或氢原子，Y和Y'各自为烷基或氢原子，A 是烷基，卤代烷基，羟基烷基或苯基或苄基，它们都可以被卤素取代。 磷化合物由相应的磷羧酸酰胺和氨基甲酸酯和甲醛制成。 这些化合物任选地与可固化的氨基塑料预缩合物一起可用于含纤维素纤维材料的隔爆和抗皱。
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10.发明授权
公开(公告)号：US3907898A
公开(公告)日：1975-09-23
申请号：US39957673
申请日：1973-09-21
Applicant: CIBA GEIGY AG
Inventor： NACHBUR HERMANN , KERN JOERG , MAEDER ARTHUR
IPC: B27K3/15 , B27K3/50 , C08G61/12 , C08G79/06 , D06M13/285 , D06M15/431 , D06M15/667 , D06M15/673 , C11D3/26 , C07F9/28
CPC classification number: D06M15/673 , B27K3/15 , B27K2240/30 , C08G79/06 , C08K5/21 , C08K5/49 , D06M13/285 , D06M15/431 , D06M15/667 , Y10T442/2672
Abstract: The subject of the invention is a process for the manufacture of polycondensation products from hydroxymethylphosphonium compounds, characterised in that at least one anhydrous tetrakis(hydroxymethyl)-phosphonium salt or tetrakis(hydroxymethyl)phosphonium hydroxide is condensed with itself in an anhydrous medium, optionally using an acid catalyst and optionally in the presence of at least one inert organic solvent, at 100* to 150*C, preferably 120* to 150*C, the condensation being continued until 0.5 to 1.5 mols of water have been eliminated per 1 mol of phosphonium compound employed, free hydroxyl groups are, if appropriate, at least partially etherified with at least one alkanol with 1 to 4 carbon atoms, and that the salt of the polycondensation products are, where relevant, converted into the corresponding hydroxides. The polycondensation products are used for the flameproofing of organic fibre material, especially textiles. Appropriately, the procedure followed is that an aqueous preparation is applied to these materials which contains at least (1) a polycondensation product of the indicated type and (2) a polyfunctional compound, and that the material thus treated are dried and subjected to a heat treatment.
Abstract translation: 本发明的主题是由羟甲基鏻化合物制造缩聚产物的方法，其特征在于至少一种无水四（羟甲基）鏻盐或四（羟甲基） - 鏻氢氧化物与自身在无水介质中冷凝， 任选地使用酸催化剂和任选地在至少一种惰性有机溶剂的存在下，在100-150℃，优选120-150℃下，继续进行缩合，直至每1次消除0.5至1.5摩尔的水 使用的鏻化合物的摩尔数，如果合适，游离羟基与至少一种具有1至4个碳原子的链烷醇至少部分醚化，并且缩聚产物的盐在相关时转化为相应的氢氧化物。
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