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公开(公告)号:US12104001B2
公开(公告)日:2024-10-01
申请号:US18196110
申请日:2023-05-11
申请人: BOREALIS AG
发明人: Alexander Reznichenko , Jari-Jussi Ruskeeniemi , Joseph Thorman , Xiao Dong Chen , Victor Sumerin
IPC分类号: C08F4/651 , B01J2/04 , B01J4/00 , B01J4/02 , C08F4/02 , C08F4/654 , C08F210/16 , B01D1/18 , B01D1/20
CPC分类号: C08F4/651 , B01J2/04 , B01J4/002 , C08F4/022 , C08F4/6543 , C08F210/16 , B01D1/18 , B01D1/20 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要: The present invention relates to a process for producing of solid particulate olefin polymerisation catalyst or catalyst carrier comprising forming a solution of the catalyst or a catalyst carrier in a solvent, subjecting the solution into an atomization by spraying the solution via a capillary vibrating spray nozzle with a capillary orifice having a diameter of 5 to 100 μm generating a laminar jet of liquid, which disintegrates into liquid droplets entering into the spray-dryer, transforming the droplets with aid of a gas to solid particulate catalyst or carrier in the spray-dryer and recovering the solid particulate olefin polymerisation catalyst or carrier having particle size distribution defined by a volumetric SPAN of 0.7 or less. The invention further relates to the catalyst produced by the methods, and use thereof in olefin polymerisation process.
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公开(公告)号:US11897975B2
公开(公告)日:2024-02-13
申请号:US17273325
申请日:2019-09-19
申请人: BOREALIS AG
IPC分类号: C08F10/02 , C08F2/00 , C08F2/34 , C08F4/02 , C08F4/64 , C08F210/02 , C08F210/06 , C08F210/14
CPC分类号: C08F2/001 , C08F2/34 , C08F4/022 , C08F4/64 , C08F210/02 , C08F210/06 , C08F210/14
摘要: The present invention relates to a multi-stage process for producing a C2 to C8 olefin polymer composition in a process comprising at least two reactors, wherein a pre-polymerized solid Ziegler-Natta catalyst is prepared by carrying out an off-line pre-polymerization of a solid Ziegler-Natta catalyst component with a C2 to C4 olefin monomer before feeding to the polymerization process.
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公开(公告)号:US20230340240A1
公开(公告)日:2023-10-26
申请号:US18004987
申请日:2021-07-07
申请人: Borealis AG
发明人: Andrey Buryak , Victor Sumerin , Anna Maria Hartl
CPC分类号: C08L23/06 , F16L9/12 , C08L2203/18 , C08L2314/02 , C08L2205/025
摘要: The present invention relates to a polyethylene composition comprising a base resin which comprises a first ethylene homo- or copolymer fraction (A) having a melt flow rate MFR2 from 1 to 150 g/10 min, preferably from 5 to 100 g/10 min, and a second ethylene copolymer fraction (B) having a content of units derived from a comonomer from 0.30 to 1.00 mol %, preferably of from 0.40 to 0.85 mol % and more preferably of from 0.45 to 0.70 mol %, wherein fraction (A) has a lower molecular weight than fraction (B) and wherein fraction (B) is present in an amount of from 45 to 70 wt. %, preferably 47 to 67 wt. %, more preferably 49 to 65 wt. %, even more preferably 50 to 62 wt. % based on the total weight of the base resin; and wherein the polyethylene composition has a melt flow rate MFR5 from 0.10 to 0.35 g/10 min, preferably from 0.10 to 0.25 g/10 min and a strain hardening modulus from 50 to 150 MPa.
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公开(公告)号:US10961334B2
公开(公告)日:2021-03-30
申请号:US16306296
申请日:2017-05-29
申请人: BOREALIS AG
发明人: Yi Liu , Victor Sumerin , Ravindra Tupe
摘要: A polyethylene composition comprising a base resin is disclosed herein. The base resin includes an ethylene homo- or copolymer fraction (A1), and an ethylene homo- or copolymer fraction (A2). Fraction (A1) has a lower weight average molecular weight than fraction (A2). The base resin has a melt flow rate MFR21 of equal to or less than 8.0 g/10 min and a density of 930 to 950 kg/m3. The polyethylene composition has a melt flow rate MFR5 of 0.01 to 0.3 g/10 min, a flow rate ratio FRR21/5 of equal to or more than 20 and a ratio of the weight average molecular weight and the number average molecular weight (Mw/Mn) of equal to or less than 30. Also the polyethylene composition has a tensile modulus of less than 1000 MPa. Also a process for the production of a polyethylene composition comprising polyethylene base resin is disclosed herein.
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公开(公告)号:US20230279206A1
公开(公告)日:2023-09-07
申请号:US18023931
申请日:2021-10-25
申请人: Borealis AG
发明人: Qizheng Dou , Victor Sumerin , Elena Pomakhina , Jari Äärilä
CPC分类号: C08L23/0815 , B29C48/022 , B29C48/09 , C08F10/02 , B29K2023/08 , C08L2314/02
摘要: The invention relates to a polyethylene (PE) composition comprising a base resin which comprises (A) a first ethylene homo- or copolymer fraction, wherein fraction (A) has melt flow rate, MFR2, from 100 to 600 g/10 min; and (B) a second ethylene-1-hexene copolymer fraction, wherein fraction (A) has a lower molecular weight than fraction (B) and wherein fraction (B) is present in an amount of from 50.0 to 58.0 wt.% based on the total weight of the base resin; wherein the base resin has a content of units derived from 1-hexene from 0.44 to 0.79 mol% based on the total amount of base resin; wherein the base resin has a molecular weight distribution, being the ratio of Mw/Mn, from 32 to 40 and the base resin has a Z average molecular weight, Mz, of more than 1,500 kg/mol; wherein the polyethylene composition has a melt flow rate MFR5 from 0.10 to 0.25 g/10 min; and a melt flow rate ratio, FRR21/5, from 30 to 42; and wherein the polyethylene composition has a critical temperature, Tc, in the rapid crack propagation test of -10° C. or lower and not less than -25° C. The invention also relates to a PE composition obtainable by a multistage process, an article comprising a PE composition, a pipe and use of a PE composition comprising a base resin for producing an article.
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公开(公告)号:US20230117202A1
公开(公告)日:2023-04-20
申请号:US17914080
申请日:2021-04-09
申请人: Borealis AG
发明人: Victor Sumerin , Markku Vahteri
IPC分类号: C08F110/02 , C08L23/08 , C08F2/00 , C08F4/651 , C08F4/654
摘要: The present application relates to a process for producing ethylene polymer in a polymerization process comprising polymerisation of ethylene, optionally with comonomers selected from C3-C20-alpha-olefins, preferably selected from C4-C10-alpha-olefins, in the presence of a Ziegler-Natta catalyst under polymerisation conditions in at least one polymerisation stage carried out in a solution, slurry or gas-phase reactor or in combinations thereof, wherein the Ziegler-Natta catalyst comprises (A) a solid Ziegler-Natta catalyst component and (B) a cocatalyst, wherein the solid Ziegler-Natta catalyst component (A) comprises a solid support of a Mg compound, a transition metal of Group 4 to 6 and an internal electron donor.
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公开(公告)号:US20220380496A1
公开(公告)日:2022-12-01
申请号:US17764235
申请日:2020-10-01
申请人: Borealis AG
发明人: Victor Sumerin , Georgy Kipiani
IPC分类号: C08F210/16 , C07C43/10 , C07D307/12 , C07D307/42
摘要: The present invention relates to optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and more particularly to their use as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally substituted 1,3-dimethoxypropanes and 3-methoxypropylamines, and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components, as well as a method for preparing the same and their use in providing polyolefins.
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公开(公告)号:US11015003B2
公开(公告)日:2021-05-25
申请号:US16301196
申请日:2017-05-29
申请人: BOREALIS AG
发明人: Anna Hjärtfors , Yi Liu , Ravindra Tupe , Victor Sumerin
IPC分类号: C08F210/16 , H01B3/44 , C08L23/08 , C08F2/00 , C08K3/04
摘要: The present invention relates to a multimodal ethylene copolymer composition having a density of 920 to 949 kg/m3 and a flexural modulus, wherein said flexural modulus is following the equation: Flexural modulus [MPa]
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公开(公告)号:US20210095108A1
公开(公告)日:2021-04-01
申请号:US16499352
申请日:2018-04-06
申请人: Borealis AG
发明人: Anna Hjärtfors , Yi Liu , Joseph Thorman , Victor Sumerin
IPC分类号: C08L23/08 , C08F210/16 , G02B6/44 , H01B3/44
摘要: The present invention relates to a cable jacket composition comprising a multimodal olefin copolymer, said copolymer having density of 0.935-0.960 g/cm3 and MFR2 of 2.2-10.0 g/10 min and said composition having ESCR of at least 2000 hours and a cable shrinkage of 0.70% or lower. The invention further relates to the process for preparing said composition and its use as outer jacket layer for a cable, preferably a communication cable, most preferably a fiber optic cable.
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公开(公告)号:US11591455B2
公开(公告)日:2023-02-28
申请号:US16499356
申请日:2018-04-06
申请人: Borealis AG
发明人: Anna Hjärtfors , Yi Liu , Victor Sumerin , Joseph Thorman
IPC分类号: C08F10/02 , C08F2/00 , C08F210/08 , C08F4/649 , C08F4/651 , C08F4/655 , C08K3/013 , C08L23/04 , C08L23/22 , H01B3/44 , C08K3/04
摘要: The present invention relates to a cable jacket composition comprising a multimodal olefin copolymer, wherein said olefin copolymer has a density of 0.935-0.960 g/cm3 and MFR2 of 1.5-10.0 g/10 min and comprises a bimodal polymer mixture of a low molecular weight homo- or copolymer and a high molecular weight copolymer wherein the composition has ESCR of at least 2000 hours and wherein the numerical values of cable wear index and composition MFR2 (g/10 min) follow the correlation: Wear index
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