公开(公告)号：US11560537B2

公开(公告)日：2023-01-24

申请号：US16607259

申请日：2018-04-16

Applicant: BASF SE

Inventor： Marta Reinoso Garcia ,  Verena Mormul ,  Thomas Schmidt ,  Jeremy T Manning

IPC: C11D3/26 ,  C11D3/33 ,  C11D17/04 ,  B29D22/00 ,  B65B53/02 ,  B65D65/46 ,  B65D75/00 ,  C11D3/39 ,  C11D11/00 ,  C11D7/32 ,  B29K29/00

Abstract: The present application is related to a container made of a polymer and containing a single unit dose of a detergent composition. The detergent composition contains at least two complexing agents (A) dissolved in an aqueous medium. The complexing agents (A) are (A1) at least one alkali metal salt of methyl glycine diacetic acid (MGDA), and (A2) at least one alkali metal salt of glutamic acid diacetic acid (GLDA). The complexing agents (A1) and (A2) are partially neutralized with alkali and the weight ratio of (A1) and (A2) ranges from 1:9 to 9:1. The aqueous medium contains at least 25% by weight of water relative to the entire liquid phase.

公开(公告)号：US10676700B2

公开(公告)日：2020-06-09

申请号：US16086931

申请日：2017-03-29

Applicant: BASF SE

Inventor： Thomas Schmidt ,  Marta Reinoso Garcia ,  Carsten Sueling ,  Verena Mormul

IPC: C11D1/00 ,  C11D11/00 ,  C11D3/33 ,  C07C227/26 ,  C11D17/00

Abstract: The present invention is directed towards mixtures comprising (A) 90 to 99.999% by weight of racemic methyl glycine diacetic acid (MGDA) or of MGDA with predominantly the L-isomer in an enantiomeric excess of up to 9.5% or their respective mono-, di- or trialkali metal or mono-, di- or triammonium salts, and (B) in total 0.001 to 10% by weight of the diacetic acid derivative of aspartate as free acid or as mono-, di-, tri- or tetraalkali metal salt or as mono-, di-, tri- or tetraammonium salt, percentages referring to the sum from (A) and (B).

公开(公告)号：US09868927B2

公开(公告)日：2018-01-16

申请号：US15518936

申请日：2015-10-07

Applicant: BASF SE

Inventor： Marta Reinoso Garcia ,  Thomas Schmidt

IPC: C11D3/33 ,  C07C227/42 ,  C07C229/24 ,  C11D17/04 ,  C11D3/37 ,  C11D11/00 ,  C11D3/39 ,  C11D3/40 ,  B65D65/46 ,  B65B3/02 ,  B65B7/02 ,  B65D75/30

CPC classification number: C11D17/045 ,  B65B3/02 ,  B65B7/02 ,  B65D65/46 ,  B65D75/30 ,  C11D3/33 ,  C11D3/3753 ,  C11D3/3942 ,  C11D3/40 ,  C11D11/0017 ,  C11D11/0023 ,  C11D17/042 ,  C11D17/043 ,  C11D17/046

Abstract: Container comprising a single unit dose of a detergent composition containing at least one complexing agent (A) dissolved in an aqueous medium, said complexing agent (A) being a mixture of the L-and D-enantiomers of methyl glycine diacetic acid (MGDA) or its respective mono-, di- or trialkali metal or mono-, di- or triammonium salts, said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 5 to 85%, wherein said container is made from a polymer.

公开(公告)号：US09056853B2

公开(公告)日：2015-06-16

申请号：US14293288

申请日：2014-06-02

Applicant: BASF SE

Inventor： Thomas Schmidt ,  Michael Puhl ,  Joachim Dickhaut ,  Henricus Maria Martinus Bastiaans ,  Michael Rack ,  Deborah L. Culbertson ,  Douglas D. Anspaugh ,  Franz-Josef Braun ,  Toni Bucci ,  Henry Van Tuyl Cotter ,  David G. Kuhn ,  Hassan Oloumi-Sadeghi

IPC: C07D401/04 ,  C07D409/14 ,  A01N43/84 ,  C07D413/14 ,  A01N43/56 ,  C07D401/14

CPC classification number: C07D401/04 ,  A01N43/56 ,  A01N43/84 ,  C07D401/14 ,  C07D409/14 ,  C07D413/14

Abstract: N-Thio-anthranilamid compounds of formula (I) wherein A is A1 wherein the variables and the indices are as defined per the description, processes for preparing the compounds I, pesticidal compositions comprising compounds I, use of compounds I for the control of insects, acarids or nematodes, and methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites by use of compounds of formula I.

Abstract translation: 式（I）的N-硫代 - 邻氨基苯甲酰胺化合物，其中A是A1，其中变量和指数如说明书所定义，制备化合物I的方法，包含化合物I的杀虫组合物，使用化合物I用于防治昆虫 ，螨虫或线虫，以及通过使用式I化合物治疗，控制，预防或保护动物免受寄生虫感染或感染的方法。

公开(公告)号：US20200062695A1

公开(公告)日：2020-02-27

申请号：US16665531

申请日：2019-10-28

Applicant: BASF SE

Inventor： Armin STAMM ,  Thomas Schmidt ,  Christopher Orr ,  Jeremy Manning

IPC: C07C227/18 ,  C11D11/00 ,  C07C229/16 ,  C01D1/04 ,  C11D3/33 ,  C09K8/035

Abstract: Process for making a chelating agent according to the general formula (I), R1—CH(COOX1)—N(CH2COOX1)2  (I) wherein R1 is selected from hydrogen, C1-C4-alkyl, phenyl, benzyl, CH2OH, and CH2CH2COOX1, X1 is (MxH1-x), M being selected from alkali metal, x is in the range of from 0.6 to 1, said process comprising the following steps: (a) providing a solid, a slurry or a solution of a compound according to general formula (II a) R1—CH(COOX2)—N(CH2CN)2  (II a) wherein X2 is (MyH1-y), M being selected from alkali metal, y is in the range of from zero to 1, (b) contacting said solid or slurry or solution with an aqueous solution of alkali metal hydroxide, wherein the molar ratio of alkali metal ions to nitrile groups is in the range of from 0.6:1 to 0.95:1, (c) reacting said compound according to general formula (II a) with said alkali metal hydroxide.

公开(公告)号：US09365543B2

公开(公告)日：2016-06-14

申请号：US14739467

申请日：2015-06-15

Applicant: BASF SE

Inventor： Thomas Schmidt ,  Michael Puhl ,  Joachim Dickhaut ,  Henricus Maria Martinus Bastiaans ,  Michael Rack ,  Deborah L. Culbertson ,  Douglas D. Anspaugh ,  Franz-Josef Braun ,  Toni Bucci ,  Henry Van Tuyl Cotter ,  David G. Kuhn ,  Hassan Oloumi-Sadeghi

IPC: C07D401/04 ,  C07D409/14 ,  C07D413/14 ,  A01N43/84 ,  A01N43/56 ,  C07D401/14

CPC classification number: C07D401/04 ,  A01N43/56 ,  A01N43/84 ,  C07D401/14 ,  C07D409/14 ,  C07D413/14

Abstract: N-Thio-anthranilamid compounds of formula (I) wherein A is A1 wherein the variables and the indices are as defined per the description, processes for preparing the compounds I, pesticidal compositions comprising compounds I, use of compounds I for the control of insects, acarids or nematodes, and methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites by use of compounds of formula I.

公开(公告)号：US08772289B2

公开(公告)日：2014-07-08

申请号：US13682246

申请日：2012-11-20

Applicant: BASF SE

Inventor： Thomas Schmidt ,  Michael Puhl ,  Joachim Dickhaut ,  Henricus Maria Martinus Bastiaans ,  Michael Rack ,  Deborah L. Culbertson ,  Douglas D. Anspaugh ,  Franz-Josef Braun ,  Toni Bucci ,  Henry Van Tuyl Cotter ,  David G. Kuhn ,  Hassan Oloumi-Sadeghi

IPC: A01N43/84 ,  A01N43/56 ,  C07D401/14 ,  C07D413/14 ,  C07D401/04 ,  C07D409/14

CPC classification number: C07D401/04 ,  A01N43/56 ,  A01N43/84 ,  C07D401/14 ,  C07D409/14 ,  C07D413/14

Abstract: N-Thio-anthranilamid compounds of formula (I) wherein A is A1 wherein the variables and the indices are as defined per the description, processes for preparing the compounds I, pesticidal compositions comprising compounds I, use of compounds I for the control of insects, acarids or nematodes, and methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites by use of compounds of formula I.

公开(公告)号：US11485703B2

公开(公告)日：2022-11-01

申请号：US16626026

申请日：2018-06-19

Applicant: BASF SE

Inventor： Thomas Schmidt ,  Armin Stamm ,  Marta Reinoso Garcia ,  Verena Mormul ,  Michael Klemens Mueller ,  Frank Jaekel ,  Jeremy T Manning

IPC: C07C227/26 ,  C07C229/16

Abstract: The present invention is directed towards a process for manufacturing a complexing agent, said process comprising the steps of (a) Providing a nitrile according to general formula (I a) or (I b) With M being selected from alkali metal and hydrogen and combinations thereof, (b) Saponification with a total alkali amount of 2.5 to 2.9 mol of alkali metal hydroxide per mole of nitrile according to general formula (I a) or (I b), respectively, and a pH value in the range of from 9.5 to 11.5 at the end of step (b), (c) Adding an amount of alkali metal hydroxide so that the total alkali content is 2.9 to 3.15 moles per mole nitrile according to general formula (I a) or (I b), respectively, and (d) Allowing further conversion.

公开(公告)号：US10519097B2

公开(公告)日：2019-12-31

申请号：US15573155

申请日：2016-05-03

Applicant: BASF SE

Inventor： Armin Stamm ,  Thomas Schmidt ,  Christopher Orr ,  Jeremy Manning

IPC: C07C227/18 ,  C11D3/33 ,  C01D1/04 ,  C07C229/16 ,  C11D11/00

Abstract: Process for making a chelating agent according to the general formula (I), R1—CH(COOX1)—N(CH2COOX1)2 wherein R1 is selected from hydrogen, C1-C4-alkyl, phenyl, benzyl, CH2OH, and CH2CH2COOX1, X1 is (MχH1−χ), M being selected from alkali metal, x is in the range of from 0.6 to 1, said process comprising the following steps: (a) providing a solid, a slurry or a solution of a compound according to general formula (II a) R1—CH(COOX2)—N(CH2CN)2 wherein X2 is (MyH1−y), M being selected from alkali metal, y is in the range of from zero to 1, (b) contacting said solid or slurry or solution with an aqueous solution of alkali metal hydroxide, wherein the molar ratio of alkali metal ions to nitrile groups is in the range of from 0.6:1 to 0.95:1, (c) reacting said compound according to general formula (II a) with said alkali metal hydroxide.

公开(公告)号：US09802884B2

公开(公告)日：2017-10-31

申请号：US15021398

申请日：2014-09-05

Applicant: BASF SE

Inventor： Marta Reinoso Garcia ,  Markus Hartmann ,  Kati Schmidt ,  Matthias Rauls ,  Thomas Schmidt ,  Paul Klingelhoefer ,  Alfred Oftring ,  Somnath Shivaji Kadam

IPC: C11D3/33 ,  C07C227/42 ,  C07C229/24 ,  C07C227/18 ,  C07C227/36 ,  C07C229/16 ,  C07C253/00

CPC classification number: C07C229/24 ,  C07C227/18 ,  C07C227/36 ,  C07C229/16 ,  C07C253/00 ,  C11D3/33

Abstract: Mixture of L- and D-enantiomers of methyl glycine diacetic acid (MGDA) or its respective mono-, di or trialkali metal or mono-, di- or triammonium salts, said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 10 to 75%.