公开(公告)号：US20190144585A1

公开(公告)日：2019-05-16

申请号：US16098010

申请日：2017-05-03

Applicant: BASF SE

Inventor： Tanja ROST ,  Roelof BALK ,  Immanuel WILLERICH ,  Sebastian ENCK ,  Joost LESWIN ,  Wolfgang GASCHLER ,  Martin Robert SCHEUBLE

IPC: C08F220/18 ,  C08F220/06 ,  C08F212/08 ,  C08F2/22 ,  C08K3/22 ,  C09D133/02 ,  C09D133/12

Abstract: Disclosed herein is a process for preparing an aqueous polymer latex by polymerising a monomer composition M by a radical emulsion polymerisation, where at least 95% of the monomer composition M is metered during a period P to the polymerisation reaction under polymerisation conditions, such that during at least one period P(n) within the period P, the relative amount of monomers M2, which are metered to the polymerisation reaction during the periods P(n), to the total amount of the monomer composition M, which is metered to the polymerisation reaction during said period P(n), is at least 1% by weight higher than the relative amount of monomers M2, which are metered to the polymerisation reaction outside of each of said periods P(n), to the total amount of the monomer composition M, which is metered to the polymerisation reaction outside of each of said periods P(n).

公开(公告)号：US20250026867A1

公开(公告)日：2025-01-23

申请号：US18711652

申请日：2022-11-22

Applicant: BASF SE

Inventor： Martin Robert SCHEUBLE ,  Immanuel WILLERICH ,  Joerg-Alexander DIMMER ,  Jochen GATTERMAYER ,  Felix LAUTERBACH

IPC: C08F2/26 ,  C08F265/06 ,  C09D7/41 ,  C09D151/00

Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising using a first aqueous mixture M(1) and a second aqueous mixture M(2), an aqueous polymer dispersion obtainable or obtained by said process and a use of said dispersion as a binder, preferably for decorative coatings. Further, the present invention relates to a coating, such as paint and paint formulation comprising said dispersion.

公开(公告)号：US20240425628A1

公开(公告)日：2024-12-26

申请号：US18274038

申请日：2022-01-26

Applicant: BASF SE

Inventor： Martin Robert SCHEUBLE ,  Ivan CABRERA ,  Joerg Alexander DIMMER ,  Immanuel WILLERICH

IPC: C08F212/08 ,  C08F2/26 ,  C08K3/22 ,  C08K3/26 ,  C08K3/34 ,  C09D7/61 ,  C09D125/14

Abstract: The present invention relates to aqueous polymer latexes of film-forming copolymer particles obtainable by aqueous emulsion polymerisation of monoethylenically monomers M, which mainly comprise non-ionic monomers of the group consisting of alkyl(meth)acrylates, cycloalkyl(meth)acrylates and monovinylaromatic hydrocarbon monomers and which additionally comprise 0.01 to 1% by weight, based on the total weight of monomers M, of at least one monoethylenically unsaturated monomer M2 having a hydrolysable silane group; and 0.1 to 2% by weight, based on the total weight of monomers M, of at least one monoethylenically unsaturated monomer M3 having an acidic phosphate group, or a salt thereof and where the copolymer particles in the polymer latex have volume median particle diameter of at least 250 nm, as determined by dynamic light scattering according to the ISO 13321:1996 standard. The polymer latexes are particularly suitable as binders in coating compositions having high pigment volume concentration (PVC) of preferably above 60% and provide good wet scrub resistance and opacity to coatings obtained therefrom. The present invention also relates to a process for producing such polymer latexes, to waterborne coating compositions containing these latexes and to the use of said polymer latexes for improving the wet scrub resistance and the opacity of coating compositions having a pigment volume concentration (PVC) of preferably above 60%.

公开(公告)号：US20240279464A1

公开(公告)日：2024-08-22

申请号：US18560695

申请日：2022-06-03

Applicant: BASF SE

Inventor： Rainer XALTER ,  Jens CREMER ,  Martin Robert SCHEUBLE

IPC: C08L77/06 ,  B29C45/00 ,  B29C48/00 ,  B29K77/00 ,  B29L31/30 ,  C08K5/13 ,  C08K5/17 ,  C08K5/526

CPC classification number: C08L77/06 ,  B29C45/0001 ,  B29C48/022 ,  C08K5/13 ,  C08K5/17 ,  C08K5/526 ,  B29K2077/00 ,  B29K2995/0022 ,  B29K2995/0055 ,  B29K2995/0087 ,  B29K2995/0089 ,  B29L2031/30 ,  C08L2205/025

Abstract: Disclosed herein is a thermoplastic moulding composition including



a) from 50 to 96.95% by weight of polyamide containing aliphatic non-branched C10-12 building blocks, selected from polyamide 6.10 and mixtures of polyamide 6.10 with polyamide 6.12, polyamide 12.12, polyamide 11 and/or polyamide 12,
b) from 0 to 37% by weight of further polyamide different from component A);
c) from 3 to 30% by weight of polyamide-polyether block copolymer;
d) from 0.05 to 1.5% by weight of hindered amine light stabilizer,
e) from 0 to 1% by weight of sterically hindered phenol oxidation retarder;
f) from 0 to 20% by weight of further additives,
where the total of the percentages by weight of a) through f) is 100% by weight and the total of the percentages by weight of b) and c) is not more than 40% by weight.

公开(公告)号：US20210269653A1

公开(公告)日：2021-09-02

申请号：US17256431

申请日：2019-06-19

Applicant: BASF SE

Inventor： Martin Robert SCHEUBLE ,  Ivan CABRERA ,  Immanuel WILLERICH ,  Crispin AMIRI NAINI ,  Nicolas TISSIER ,  Joerg Alexander DIMMER ,  Tanja ROST

IPC: C09D5/02 ,  C09D7/61 ,  C08F212/08 ,  C08F220/06 ,  C08F220/18 ,  C08F230/08 ,  C08F2/22 ,  C08K3/013 ,  C08K3/34 ,  C08L33/08

Abstract: The present invention relates to an aqueous emulsion paint comprising a) 5% to 50% by weight of an aqueous polymer dispersion having a solids content in the range from 40% to 60% by weight, obtainable by the free-radical aqueous emulsion polymerization of a monomer mixture comprising ethylhexyl acrylate, butyl acrylate and one or more vinylaromatics, preferably styrene, b) 0.1% to 5% by weight of alkali metal alkylsiliconate and/or water-soluble silicate, c) 20% to 70% by weight of inorganic fillers, d) 0% to 30% by weight of at least one pigment, e) 0.1% to 10% by weight of customary auxiliaries, and f) water, based in each case on the total amount of the emulsion paint, the pH of the emulsion paint having a value in the range from 10 to 12, and also relates to the aqueous polymer dispersions, to a process for the preparation thereof and to the use thereof as organic binders in emulsion paints having a high pH.

公开(公告)号：US20190241762A1

公开(公告)日：2019-08-08

申请号：US16339236

申请日：2017-10-06

Applicant: BASF SE

Inventor： Immanuel WILLERICH ,  Volodymyr BOYKO ,  Bernd RECK ,  Jules MIKHAEL ,  Joost LESWIN ,  Mary THOMSON ,  Markus RUECKEL ,  Martin Robert SCHEUBLE

IPC: C09D151/00 ,  C09D5/02

CPC classification number: C09D151/003 ,  C08F2/001 ,  C08F2/22 ,  C08F2/26 ,  C08F2/44 ,  C08F265/04 ,  C09D5/022 ,  C09D5/024 ,  C09D5/027 ,  C09D5/028 ,  C08F2220/1825 ,  C08F212/08 ,  C08F220/06 ,  C08F220/14 ,  C08F222/02 ,  C08F220/56 ,  C08F2220/1858 ,  C08L33/02 ,  C08K2003/2241

Abstract: Disclosed herein is a latex paint containing i) a multistage carboxylated polymer latex binder, ii) a titanium dioxide pigment, and iii) a polymeric dispersant PD having a number average molecular weight, as determined by GPC, of at most 5500 Dalton. Also disclosed are methods for preparing the latex paint, and coatings containing the latex paint.