METHOD FOR PRODUCING FUNCTIONAL WATER SOLUBLE FILMS

    公开(公告)号:US20200079922A1

    公开(公告)日:2020-03-12

    申请号:US16469792

    申请日:2017-12-07

    Applicant: BASF SE

    Abstract: Described herein is a process for producing a water-soluble foil, wherein the water-soluble foil includes at least one layer S1) including a polymer composition P1) obtainable by free-radical polymerization of a monomer composition M1) including at least one monomer A) selected from α,β-ethylenically unsaturated mono- and dicarboxylic acids, salts of α,β-ethylenically unsaturated mono- and dicarboxylic acids, anhydrides, of α,β-ethylenically unsaturated mono- and dicarboxylic acids and mixtures thereof, in the presence of at least one polyether component PE) selected from polyetherols having a number-average molecular weight of at least 200 g/mol, mono- and di(C1-C6-alkyl) ethers of such polyetherols, surfactants containing polyether groups, and mixtures thereof, where the foil may also include further layers, and where the layers are cast onto a carrier material.

    Carboxylate ester of polysaccharide

    公开(公告)号:US10167347B2

    公开(公告)日:2019-01-01

    申请号:US15125220

    申请日:2015-03-11

    Applicant: BASF SE

    Abstract: The invention relates to a carboxylate ester of polysaccharide characterized in that it possesses ester bonds with trimellitic anhydride and is soluble in water. The polysaccharide is esterified with trimellitic anhydride and the degree of substitution of the polysaccharide lies in the range of from 0.5 to 3. The invention further relates to methods for the manufacture of these polysaccharides esters in organic solvents, in water or in an extruder or a kneader and to their use in fabric and home care formulations.

    USE OF POLYMERS OF ACRYLIC ACID FOR SCALE INHIBITION IN DESALINATION SYSTEMS

    公开(公告)号:US20240228348A1

    公开(公告)日:2024-07-11

    申请号:US18561441

    申请日:2022-05-23

    Applicant: BASF SE

    CPC classification number: C02F5/14 C02F2103/08 C02F2209/02 C02F2209/44

    Abstract: The invention relates to the use of an aqueous solution of acrylic acid polymer for inhibiting scale formation in a desalination system, wherein the polymer of acrylic acid obtained by a process of polymerising acrylic acid in feed operation with a free radical starter in the presence of hypophosphite in water as solvent, which comprises (i) initially charging water and aqueous hypophosphite solution and optionally acrylic acid in acidic, unneutralised form, optionally one or more ethylenically unsaturated comonomers, and optionally initiator, (ii) adding acrylic acid in acidic, unneutralised form, optionally one or more ethylenically unsaturated comonomers, aqueous free radical starter solution and aqueous hypophosphite solution, (iii) adding a base to the aqueous solution after termination of the acrylic acid feed, wherein the comonomer content does not exceed 30 wt. % based on the total monomer content, wherein the acrylic acid, the aqueous free radical starter solution and the aqueous hypophosphite solution are added such that the molar ratio x of acrylic acid to phosphorus-bound hydrogen [AA]/[P—H] over a time period in which at least 75% of the acrylic acid is converted and has a value x which is constant to within ±0.5 and is in the range from 0.8 to 2, wherein the acrylic acid polymer has a weight average molecular mass Mw of from 1000 to 3000 g/mol, wherein the desalination system comprises at least one of the group consisting of Multi Stage Flash (MSF), at least one Multi Effect Distillation (MED) and Reverse Osmosis (RO). The invention also relates to a process of desalinating saline water in a desalination system.

    Method for Producing Acrylic Acid Polymers
    9.
    发明申请

    公开(公告)号:US20200299426A1

    公开(公告)日:2020-09-24

    申请号:US16074100

    申请日:2017-02-02

    Applicant: BASF SE

    Abstract: A process for producing aqueous solutions of acrylic acid polymers by polymerization of acrylic acid in feed operation with a free-radical starter in the presence of hypophosphite in water as solvent, which comprises (i) initially charging water and optionally acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, optionally aqueous hypophosphite solution and optionally initiator, (ii) adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, aqueous free-radical starter solution and aqueous hypophosphite solution, (iii) adding a base to the aqueous solution after termination of the acrylic acid feed, wherein the comonomer content does not exceed 30 wt % based on the total monomer content, wherein the acrylic acid, the aqueous free-radical starter solution and the aqueous hypophosphite solution are added such that the molar ratio x of acrylic acid to phosphorus-bound hydrogen [AA]/[P—H] over a time period in which at least 75% of the acrylic acid is converted has a value x which is constant to within ±0.5 and is in the range from 0.8 to 2.

    MULTI-LAYERED FILM , METHOD FOR THE PRODUCTION AND USE THEREOF

    公开(公告)号:US20200086616A1

    公开(公告)日:2020-03-19

    申请号:US16469984

    申请日:2017-12-15

    Applicant: BASF SE

    Abstract: Described herein is a multilayer film including at least one layer including a polymer composition obtainable by free-radical polymerization of a monomer composition including at least one monomer A) selected from α,β-ethylenically unsaturated mono- and dicarboxylic acids, salts of α,β-ethylenically unsaturated mono- and dicarboxylic acids, anhydrides of α,β-ethylenically unsaturated mono- and dicarboxylic acids and mixtures thereof, where the free-radical polymerization is effected in the presence of at least one polyether component. Also described herein is a process for producing the multilayer film, methods of using the multilayer film and a sheath or coating for a washing composition, cleaning composition or dishwashing composition portion including the multilayer film, and to washing compositions, cleaning compositions or dishwashing compositions including the multilayer film.

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