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公开(公告)号:US10538623B2
公开(公告)日:2020-01-21
申请号:US15533585
申请日:2015-12-01
Applicant: BASF SE
Inventor: Gazi Tuerkoglu , Juergen Detering , Dietrich Fehringer , Christian Benz
Abstract: Compositions including polyaspartic acid and methods for preparing polyaspartic acid using a precondensate of aspartic acid and polyaspartimide are provided herein. Uses for such compositions are also described.
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公开(公告)号:US20170321008A1
公开(公告)日:2017-11-09
申请号:US15533585
申请日:2015-12-01
Applicant: BASF SE
Inventor: Gazi Tuerkoglu , Juergen Detering , Dietrich Fehringer , Christian Benz
Abstract: Compositions including polyaspartic acid and methods for preparing polyaspartic acid using a precondensate of aspartic acid and polyaspartimide are provided herein. Uses for such compositions are also described.
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公开(公告)号:US20170114154A1
公开(公告)日:2017-04-27
申请号:US15125220
申请日:2015-03-11
Applicant: BASF SE
Inventor: Natalia Shabelina , Helmut Witteler , Juergen Detering , Ulrich Schneider , Jessica Neumann
CPC classification number: C08B37/0054 , C11D3/226 , C11D3/39 , C11D11/0017 , C11D11/0023
Abstract: The invention relates to a carboxylate ester of polysaccharide characterised in that it possesses ester bonds with trimellitic anhydride and is soluble in water. The polysaccharide is esterified with trimellitic anhydride and the degree of substitution of the polysaccharide lies in the range of from 0.5 to 3. The invention further relates to methods for the manufacture of these polysaccharides esters in organic solvents, in water or in an extruder or a kneader and to their use in fabric and home care formulations.
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公开(公告)号:US20200079922A1
公开(公告)日:2020-03-12
申请号:US16469792
申请日:2017-12-07
Applicant: BASF SE
Inventor: Yannick Fuchs , Juergen Detering , Markus Meise , Helmut Witteler , Benjamin Schmidt-Hansberg , Claudia Esper , Marcel Schmitt , Maria De Moragas
Abstract: Described herein is a process for producing a water-soluble foil, wherein the water-soluble foil includes at least one layer S1) including a polymer composition P1) obtainable by free-radical polymerization of a monomer composition M1) including at least one monomer A) selected from α,β-ethylenically unsaturated mono- and dicarboxylic acids, salts of α,β-ethylenically unsaturated mono- and dicarboxylic acids, anhydrides, of α,β-ethylenically unsaturated mono- and dicarboxylic acids and mixtures thereof, in the presence of at least one polyether component PE) selected from polyetherols having a number-average molecular weight of at least 200 g/mol, mono- and di(C1-C6-alkyl) ethers of such polyetherols, surfactants containing polyether groups, and mixtures thereof, where the foil may also include further layers, and where the layers are cast onto a carrier material.
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公开(公告)号:US20190077895A1
公开(公告)日:2019-03-14
申请号:US16084712
申请日:2017-03-15
Applicant: BASF SE
Inventor: Yannick Fuchs , Juergen Detering , Markus Meise , Benjamin Schmidt-Hansberg , Claudia Esper
IPC: C08F220/06 , C08F222/02 , C08L71/02 , C08F2/06 , C08F2/10 , C08J5/18 , C11D17/00 , C11D3/37
Abstract: A washing- and cleaning-active polymer film is disclosed. The washing- and cleaning-active polymer film includes a polymer composition obtainable by a free-radical polymerization of a monomer composition. The monomer composition includes at least one α,β-ethylenically unsaturated carboxylic acid or acid salt. The monomer composition is subjected to a free-radical polymerization in the presence of at least one polyether component. A process for producing the washing- and cleaning-active polymer film is further disclosed. A use of the polymer film and a covering or coating for a detergent or cleaner portion including the polymer film is disclosed.
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公开(公告)号:US10167347B2
公开(公告)日:2019-01-01
申请号:US15125220
申请日:2015-03-11
Applicant: BASF SE
Inventor: Natalia Shabelina , Helmut Witteler , Juergen Detering , Ulrich Schneider , Jessica Neumann
Abstract: The invention relates to a carboxylate ester of polysaccharide characterized in that it possesses ester bonds with trimellitic anhydride and is soluble in water. The polysaccharide is esterified with trimellitic anhydride and the degree of substitution of the polysaccharide lies in the range of from 0.5 to 3. The invention further relates to methods for the manufacture of these polysaccharides esters in organic solvents, in water or in an extruder or a kneader and to their use in fabric and home care formulations.
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公开(公告)号:US09840683B2
公开(公告)日:2017-12-12
申请号:US14807924
申请日:2015-07-24
Applicant: Ecolab USA Inc. , BASF SE
Inventor: Carter M. Silvernail , Erik C. Olson , Kerrie E. Walters , Juergen Detering , Arend Jouke Kingma , James S. Dailey
CPC classification number: C11D3/044 , C11D3/3707 , C11D3/3757 , C11D3/3761 , C11D3/3765 , C11D7/06 , C11D17/0008 , C11D17/0052 , C11D17/0073 , C11D17/0086 , C11D17/0091
Abstract: An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
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公开(公告)号:US20240228348A1
公开(公告)日:2024-07-11
申请号:US18561441
申请日:2022-05-23
Applicant: BASF SE
Inventor: Ahmet Uener , Stephan Nied , Juergen Detering , Achim Fessenbecker
IPC: C02F5/14 , C02F103/08
CPC classification number: C02F5/14 , C02F2103/08 , C02F2209/02 , C02F2209/44
Abstract: The invention relates to the use of an aqueous solution of acrylic acid polymer for inhibiting scale formation in a desalination system, wherein the polymer of acrylic acid obtained by a process of polymerising acrylic acid in feed operation with a free radical starter in the presence of hypophosphite in water as solvent, which comprises (i) initially charging water and aqueous hypophosphite solution and optionally acrylic acid in acidic, unneutralised form, optionally one or more ethylenically unsaturated comonomers, and optionally initiator, (ii) adding acrylic acid in acidic, unneutralised form, optionally one or more ethylenically unsaturated comonomers, aqueous free radical starter solution and aqueous hypophosphite solution, (iii) adding a base to the aqueous solution after termination of the acrylic acid feed, wherein the comonomer content does not exceed 30 wt. % based on the total monomer content, wherein the acrylic acid, the aqueous free radical starter solution and the aqueous hypophosphite solution are added such that the molar ratio x of acrylic acid to phosphorus-bound hydrogen [AA]/[P—H] over a time period in which at least 75% of the acrylic acid is converted and has a value x which is constant to within ±0.5 and is in the range from 0.8 to 2, wherein the acrylic acid polymer has a weight average molecular mass Mw of from 1000 to 3000 g/mol, wherein the desalination system comprises at least one of the group consisting of Multi Stage Flash (MSF), at least one Multi Effect Distillation (MED) and Reverse Osmosis (RO). The invention also relates to a process of desalinating saline water in a desalination system.
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公开(公告)号:US20200299426A1
公开(公告)日:2020-09-24
申请号:US16074100
申请日:2017-02-02
Applicant: BASF SE
Inventor: Johannes Barth , Gledison Fonseca , Dieter Faul , Martin Ernst , Juergen Detering , Ferdinand Leifeld , Gazi Tuerkoglu
IPC: C08F120/06 , C11D3/37 , C11D3/00
Abstract: A process for producing aqueous solutions of acrylic acid polymers by polymerization of acrylic acid in feed operation with a free-radical starter in the presence of hypophosphite in water as solvent, which comprises (i) initially charging water and optionally acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, optionally aqueous hypophosphite solution and optionally initiator, (ii) adding acrylic acid in acidic, unneutralized form, optionally one or more ethylenicaliy unsaturated comonomers, aqueous free-radical starter solution and aqueous hypophosphite solution, (iii) adding a base to the aqueous solution after termination of the acrylic acid feed, wherein the comonomer content does not exceed 30 wt % based on the total monomer content, wherein the acrylic acid, the aqueous free-radical starter solution and the aqueous hypophosphite solution are added such that the molar ratio x of acrylic acid to phosphorus-bound hydrogen [AA]/[P—H] over a time period in which at least 75% of the acrylic acid is converted has a value x which is constant to within ±0.5 and is in the range from 0.8 to 2.
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公开(公告)号:US20200086616A1
公开(公告)日:2020-03-19
申请号:US16469984
申请日:2017-12-15
Applicant: BASF SE
Inventor: Markus Meise , Yannick Fuchs , Helmut Witteler , Alejandra Garcia Marcos , Juergen Detering , Benjamin Schmidt-Hansberg
Abstract: Described herein is a multilayer film including at least one layer including a polymer composition obtainable by free-radical polymerization of a monomer composition including at least one monomer A) selected from α,β-ethylenically unsaturated mono- and dicarboxylic acids, salts of α,β-ethylenically unsaturated mono- and dicarboxylic acids, anhydrides of α,β-ethylenically unsaturated mono- and dicarboxylic acids and mixtures thereof, where the free-radical polymerization is effected in the presence of at least one polyether component. Also described herein is a process for producing the multilayer film, methods of using the multilayer film and a sheath or coating for a washing composition, cleaning composition or dishwashing composition portion including the multilayer film, and to washing compositions, cleaning compositions or dishwashing compositions including the multilayer film.
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