Abstract:
A process for preparing a thermoplastic polymer may involve reacting at least components (i) to (ii): a polyisocyanate composition including at least one diisocyanate (i); an epoxide composition comprising at least one diepoxide (ii); in the presence of a catalyst composition (iii); where epoxide composition (ii) and catalyst composition (iii) are initially charged as a mixture at a temperature in a first temperature range (T1); the polyisocyanate composition (i) is at least partially added while maintaining a temperature in the first temperature range T1; the temperature is raised to a temperature in a final temperature range (Tf); and the remaining polyisocyanate composition (i) is added in the final temperature range. A thermoplastic polymer obtainable by such a process may be used, e.g., for producing a fiber or a shaped body by injection molding, calendering, powder sintering, laser sintering, melt pressing, or extrusion, or as modifier for thermoplastic material.
Abstract:
Described herein are processes for producing moldings comprising oxazolidinone groups, where polyisocyanate (a) is mixed with at least one organic compound (b) having two or more epoxide groups, at least one catalyst (c) for the isocyanate/epoxide reaction, and optionally auxiliary and additive materials (d) to form a reaction mixture, which is introduced into or applied to a mold and reacted to give moldings including oxazolidinone groups, where the catalyst (c) for the isocyanate/epoxide reaction includes a compound of the general formula [M(R1)(R2)(R3)(R4)]+ [X In]−, where M is a nitrogen atom or a phosphorus atom, R1, R2, R3 and R4 are an organic radical, X is fluorine, chlorine, bromine or iodine, I is iodine, and n stands for rational numbers from 0.1 to 10.
Abstract:
Cured epoxy resins are widespread because of their excellent mechanical and chemical properties. Typically, epoxy resins based on bisphenol A diglycidyl ethers or bisphenol F diglycidyl ethers are used, but these are problematic for many sectors because of their effect on the endocrine system. The present invention relates to glycidyl ethers of divinylbenzene-based diols and/or polyols, and to curable epoxy resin compositions based thereon as alternatives to the bisphenol A diglycidyl ethers or bisphenol F diglycidyl ethers, or the epoxy resin compositions based thereon.
Abstract:
Cured epoxy resins are widespread because of their excellent mechanical and chemical properties. Typically, epoxy resins based on bisphenol A diglycidyl ethers or bisphenol F diglycidyl ethers are used, but these are problematic for many sectors because of their effect on the endocrine system. The present invention relates to glycidyl ethers of limonene-based diols and/or polyols, and to curable epoxy resin compositions based thereon as alternatives to the bisphenol A diglycidyl ethers or bisphenol F diglycidyl ethers, or the epoxy resin compositions based thereon.
Abstract:
A method for preparing a thermoplastic polyoxazolidone, the method including catalytically reacting one or more aromatic diisocyanates and one or more diepoxides, wherein the one or more diepoxides comprise one or more 2-phenylpropane-1,3-diol diglycidyl ether derivatives. The one or more diepoxides further contain one or more diglycidyl ethers of aromatic diols.
Abstract:
Process for the manufacturing of a polymer with urethane groups, wherein in a first alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups and a compound B) with at least two amino groups, selected from primary or secondary amino groups and optionally a compound C) with at least one functional group that reacts with a group —SH are reacted or wherein in a second alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups or a mixture of a compound A) with a compound A1) with one five-membered cyclic monothiocarbonate group and a compound B) with at least two amino groups, selected from primary or secondary amino groups or a compound B1) with one amino group selected from primary or secondary amino groups or mixtures of compounds B) and B1) and a compound C) with at least two functional groups that react with a group —SH or in case of a carbon-carbon triple bond as functional group that react with a group —SH, a compound C) with at least one carbon-carbon triple bond. are reacted.
Abstract:
A shaped body comprising at least one solid material and a cured epoxy resin wherein the cured epoxy resin is prepared from an epoxy resin composition containing at least one epoxy resin having at least one epoxy group per molecule; at least one curing agent selected from cyanoalkylated polyamines of formula (A) A(NH—X—CN), wherein A is a group selected from aryl, arylalkyl, alkyl, and cycloalkyl, wherein A does not contain a primary amino group, X is alkylene having 1 to 10 C-atoms, and n≧2; and at least one accelerator selected from tertiary amines, imidazoles, guanidines, urea compounds, and Lewis acids.