公开(公告)号：US20240199514A1

公开(公告)日：2024-06-20

申请号：US18573216

申请日：2022-06-27

申请人： ENI S.P.A. ,  BASF SE

发明人： Giacomo FILIPPINI ,  Gianluca FIORI ,  Thomas PASINI ,  Laura Annamaria PELLEGRINI ,  Steffen MADER ,  Stephanie Sybille LINKE ,  Stefan KOTREL ,  Thomas HEIDEMANN ,  Dagmar Pascale KUNSMANN-KEITEL

IPC分类号： C07C29/60 ,  C07C29/84 ,  C07C31/08 ,  C07C31/10

CPC分类号： C07C29/60 ,  C07C29/84 ,  C07C31/08 ,  C07C31/10

摘要： A process to produce propanol and iso-propanol (bio-propanol), a biocomponent for gasoline relates to the conversion of bio-glycerin to bio-propanol and bio-iso-propanol.
In particular, a process is related for the conversion of glycerin, in particular glycerin from renewable sources, to propanols, the process including the following steps:



(a) hydrogenating a glycerin phase with a Co—Cu—Mn—Mo based hydrogenation catalyst to give an effluent containing water and an organic mixture of more than 40 wt % of a mixture of ethanol, 1-propanol and 2-propanol and the rest being unreacted propanediols and glycerin, with traces of ethylene glycol;
(b) separating by mainly distillation the ethanol, 1-propanol and 2-propanol mixture from the other components in the effluent of step a); and (c)
optionally, recycling all or part of the unreacted propandiols and glycerin deriving from steps a) and/or b) to the hydrogenation step a).

公开(公告)号：US20240052102A1

公开(公告)日：2024-02-15

申请号：US18268991

申请日：2021-12-22

申请人： BASF SE

发明人： Gereon Antonius SOMMER ,  Guenter SCHERR ,  Stephan WINKOETZ ,  Jean-Pierre Berkan LINDNER ,  Dagmar Pascale KUNSMANN-KEITEL ,  Ralph LUNKWITZ ,  David TUERP

IPC分类号： C08G69/26 ,  C08G69/10 ,  C08K5/07 ,  C08L97/02 ,  B27N3/00 ,  B27N3/02

CPC分类号： C08G69/265 ,  C08G69/10 ,  C08K5/07 ,  C08L97/02 ,  B27N3/002 ,  B27N3/02

摘要： The present invention relates to a binder composition comprising



a) component A comprising polymer(s) A1 having primary and/or secondary amino groups wherein polymer(s) A1 has(have) a primary and secondary amine group nitrogen content (NCps) of at least 1 wt.-% and
b) component B comprising hydroxyacetone.

公开(公告)号：US20200010395A1

公开(公告)日：2020-01-09

申请号：US16460402

申请日：2019-07-02

申请人： BASF SE

发明人： Dagmar Pascale KUNSMANN-KEITEL ,  Georg Heinrich GROSCH ,  Jan-Dirk ARNDT ,  Gauthier Luc Maruice AVERLANT ,  Wolf-Steffen WEISSKER ,  Marcus Georg SCHREMS ,  Dan-Tam Daniel TANG

IPC分类号： C07C45/64 ,  C07C49/17 ,  C07C45/83

摘要： Method for preparing a β-hydroxyketone having 4 to 8 carbon atoms by reacting formaldehyde with a branched or unbranched dialkyl ketone having 3 to 7 carbon atoms in the liquid phase in a reactor in the presence of a basic component at a temperature of 50 to 150° C. and a pressure of 0.2 to 10 MPa abs, in which (a) a trialkylamine having 1 to 4 carbon atoms per alkyl group is used as basic component and the reaction (b) is carried out in the presence of 1 to 25% by weight water, based on the liquid phase, and (c) at a molar ratio of trialkylamine to formaldehyde in the liquid phase of from 1 to 5.

公开(公告)号：US20240043617A1

公开(公告)日：2024-02-08

申请号：US18269028

申请日：2021-12-22

申请人： BASF SE

发明人： Gereon Antonius SOMMER ,  Stephan WEINKOETZ ,  David TUERP ,  Guenter SCHERR ,  Jessica Nadine HAMANN ,  Joaquim Henrique TELES ,  Ralph LUNKWITZ ,  Thomas SERVAY ,  Jean-Pierre Berkan LINDNER ,  Dagmar Pascale KUNSMANN-KEITEL

IPC分类号： C08G69/10 ,  C08K5/07 ,  C08K5/1545 ,  C08L97/02 ,  B27N3/00 ,  B27N3/04

CPC分类号： C08G69/10 ,  C08K5/07 ,  C08K5/1545 ,  C08L97/02 ,  B27N3/002 ,  B27N3/04

摘要： The present invention relates to a binder composition comprising component A comprising polymer(s) A1 and optionally component B comprising component B1 which is selected from the group consisting of a mono-saccharides, disaccharides, droxyacetone, glycolaldehyde and mixtures thereof, wherein polymer(s) A1 comprises at least 70 wt.-% poly(amino acid)s based on the total weight of the polymers) A1 and has (have) a total weight average molecular weight Mw, total of 800 g/mol to 10.000 g/mol, wherein the binder composition comprises 60 to 100 wt.-% polymer(s) A1, and 0 to 40 wt.-% component B1, based on the total weight of the sum of polymer(s) Al and component B1, wherein the weight amounts of the polymer(s) Al and component B1 are selected such that the total weight of the sum of polymer(s) A1 and component B1 is 100 wt.-%.

公开(公告)号：US20240043616A1

公开(公告)日：2024-02-08

申请号：US18269022

申请日：2021-12-22

申请人： BASF SE

发明人： Gereon Antonius SOMMER ,  Stephan WEINKOETZ ,  David TUERP ,  Ralph LUNKWITZ, IV ,  Claus FUEGER ,  Guenter SCHERR ,  Jessica Nadine HAMANN ,  Joequim Henrique TELES ,  Jean-Pierre Berkan LINDNER ,  Dagmar Pascale KUNSMANN-KEITEL ,  Thomas SERVAY

IPC分类号： C08G69/10 ,  C08L97/02 ,  B27N3/00 ,  B27N3/02

CPC分类号： C08G69/10 ,  C08L97/02 ,  B27N3/002 ,  B27N3/02

摘要： The present invention relates to a binder composition comprising



a) Component A comprising amino acid polymer(s) A1 and
b) Component B comprising component B1 selected from the group consisting of pentoses, hexoses, disaccharides of pentoses and/or hexoses and mixtures thereof,
wherein the amino acid polymer(s) A1 has(have) a total weight average molecular weight Mw, total of at least 800 g/mol and at most 10.000 g/mol and wherein the binder composition comprises at least 55 wt.-% amino acid polymer(s) A1 based on the total weight of the amino acid polymer(s) A1 and component B1.

公开(公告)号：US20210395558A1

公开(公告)日：2021-12-23

申请号：US17279369

申请日：2019-09-20

申请人： BASF SE

发明人： Giovanni D'ANDOLA ,  Andre FUCHS ,  Edouard LOISEL ,  Dagmar Pascale KUNSMANN-KEITEL ,  Erhard GUENTHER

IPC分类号： C09D139/04 ,  B33Y10/00 ,  B33Y80/00 ,  B33Y70/00 ,  B29C64/124

摘要： The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R1, R2, R3 and R4 are independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa·s, preferably 10 to 1500 mPa·s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.

公开(公告)号：US20200010394A1

公开(公告)日：2020-01-09

申请号：US16460327

申请日：2019-07-02

申请人： BASF SE

发明人： Dagmar Pascale KUNSMANN-KEITEL ,  Georg Heinrich GROSCH ,  Jan-Dirk ARNDT ,  Gauthier Luc Maruice AVERLANT ,  Wolf-Steffen WEISSKER ,  Marcus Georg SCHREMS ,  Dan-Tam Daniel TANG

IPC分类号： C07C45/64 ,  C07C45/83 ,  C07C49/17

摘要： Method for preparing 1-hydroxy-2-methyl-3-pentanone (I) by reacting formaldehyde with diethyl ketone in a reactor in the presence of water and a basic component at a temperature of 50 to 150° C. and a pressure of 0.2 to 10 MPa abs, in which the basic component used is a trialkylamine from the group comprising trimethylamine, N,N-dimethylethylamine, N,N-diethylmethylamine, triethylamine, N,N-dimethyl-n-propylamine, N-ethyl-N-methyl-n-propylamine, N,N-dimethylisopropylamine, N-ethyl-N-methylisopropylamine, N,N-dimethyl-n-butylamine, N,N-dimethylisobutylamine and N,N-dimethyl-sec-butylamine, and from the reaction mixture obtained, trialkylamine as low boiler and a bottom product comprising 1-hydroxy-2-methyl-3-pentanone (I) as high boiler are separated in a distillation apparatus, wherein the distillation apparatus is operated at a top pressure of 0.2 to 1 MPa abs.