公开(公告)号：US06310265B1

公开(公告)日：2001-10-30

申请号：US09432006

申请日：1999-11-01

申请人： Arthur W. Chester ,  David C. Calabro ,  Sandeep S. Dhingra ,  Jean W. Beeckman ,  Timothy J. Fiebig ,  Glenn R. Sweeten ,  Terry E. Helton ,  Charles T. Kresge ,  Richard F. Socha ,  Simon C. Weston

发明人： Arthur W. Chester ,  David C. Calabro ,  Sandeep S. Dhingra ,  Jean W. Beeckman ,  Timothy J. Fiebig ,  Glenn R. Sweeten ,  Terry E. Helton ,  Charles T. Kresge ,  Richard F. Socha ,  Simon C. Weston

IPC分类号： C07C522

CPC分类号： C07C5/2702 ,  C07C5/2724 ,  C07C9/00

摘要： This invention relates to a process for isomerizing paraffins comprising the step of contacting a feed containing paraffins with a catalyst comprising a synthetic porous crystalline material, designated MCM-68, which exhibits a distinctive X-ray diffraction pattern and has a unique crystal structure which contains at least one channel system, in which each channel is defined by a 12-membered ring of tetrahedrally coordinated atoms, and at least two further, independent channel systems, in each of which each channel is defined by a 10-membered ring of tetrahedrally coordinated atoms, wherein the number of unique 10-membered ring channels is twice the number of 12-membered ring channels.

摘要翻译： 本发明涉及异构烷烃的方法，其包括使含有链烷烃的进料与包含合成多孔结晶材料的催化剂（称为MCM-68）的催化剂接触，该催化剂表现出独特的X射线衍射图并具有独特的晶体结构，其含有 至少一个通道系统，其中每个通道由四面体配位的原子的12元环定义，以及至少两个独立的通道系统，每个通道系统的每个通道由四面体配位的10元环 原子，其中唯一的10元环通道的数目是12元环通道数目的两倍。

公开(公告)号：US07326818B2

公开(公告)日：2008-02-05

申请号：US10641604

申请日：2003-08-15

申请人： Jean W. Beeckman ,  William G. Borghard ,  Arthur W. Chester ,  Robert A. Crane ,  Owen C. Feeley ,  John C. Fried ,  Dominick N. Mazzone ,  Glenn R. Sweeten

发明人： Jean W. Beeckman ,  William G. Borghard ,  Arthur W. Chester ,  Robert A. Crane ,  Owen C. Feeley ,  John C. Fried ,  Dominick N. Mazzone ,  Glenn R. Sweeten

IPC分类号： C07C5/00

CPC分类号： B01J29/40 ,  B01J2229/12 ,  B01J2229/18 ,  B01J2229/40 ,  B01J2229/42 ,  C07C6/123 ,  C07C2521/08 ,  C07C2529/40 ,  Y02P20/52 ,  Y10S585/906 ,  C07C15/08

摘要： In a process for preparing a selectivated catalyst composition useful in the disproportionation of toluene, a catalyst comprising an acidic molecular sieve is contacted with a boron compound at a temperature in excess of 500° C.; and the resultant catalyst is then contacted with a medium containing hydrogen ions to at least partially restore the acid activity of the molecular sieve.

摘要翻译： 在制备可用于甲苯歧化的选择性催化剂组合物的方法中，包含酸性分子筛的催化剂在硼氢化合物与超过500℃的温度下接触; 然后使得到的催化剂与含有氢离子的介质接触，至少部分地恢复分子筛的酸活性。

公开(公告)号：US07572749B2

公开(公告)日：2009-08-11

申请号：US11189665

申请日：2005-07-26

申请人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

发明人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

IPC分类号： B01J29/06

CPC分类号： B01J37/0018 ,  B01J20/183 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/65 ,  B01J37/0009 ,  B01J2229/42 ,  C04B35/18 ,  C04B38/0022 ,  C04B2111/00793 ,  C08L83/04 ,  C10G45/04 ,  C10G49/02 ,  C04B38/0006 ,  C04B38/0054 ,  C08L2666/54 ,  C08L2666/58

摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.

摘要翻译： 本发明涉及在没有添加的有机溶剂与颗粒状无机材料形成结构体的情况下使用颗粒状有机硅树脂，特别是分子筛含结构体的用途。 有机硅树脂以平均粒径小于700μm的颗粒形式使用。 煅烧后，将有机硅树脂转化为二氧化硅作为粘合剂。

公开(公告)号：US07902103B2

公开(公告)日：2011-03-08

申请号：US12459307

申请日：2009-06-30

申请人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

发明人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

IPC分类号： B01J29/06 ,  B01J31/00

CPC分类号： B01J37/0018 ,  B01J20/183 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/65 ,  B01J37/0009 ,  B01J2229/42 ,  C04B35/18 ,  C04B38/0022 ,  C04B2111/00793 ,  C08L83/04 ,  C10G45/04 ,  C10G49/02 ,  C04B38/0006 ,  C04B38/0054 ,  C08L2666/54 ,  C08L2666/58

摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.

摘要翻译： 本发明涉及在没有添加的有机溶剂与颗粒状无机材料形成结构体的情况下使用颗粒状有机硅树脂，特别是分子筛含结构体的用途。 有机硅树脂以平均粒径小于700μm的颗粒形式使用。 煅烧后，将有机硅树脂转化为二氧化硅作为粘合剂。

公开(公告)号：US20090270246A1

公开(公告)日：2009-10-29

申请号：US12459307

申请日：2009-06-30

申请人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

发明人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Arthur W. Chester ,  John P. McWilliams ,  Dominick N. Mazzone

IPC分类号： B01J29/04

CPC分类号： B01J37/0018 ,  B01J20/183 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/65 ,  B01J37/0009 ,  B01J2229/42 ,  C04B35/18 ,  C04B38/0022 ,  C04B2111/00793 ,  C08L83/04 ,  C10G45/04 ,  C10G49/02 ,  C04B38/0006 ,  C04B38/0054 ,  C08L2666/54 ,  C08L2666/58

摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.

公开(公告)号：US07686949B2

公开(公告)日：2010-03-30

申请号：US11205606

申请日：2005-08-17

申请人： Stephen J. McCarthy ,  Jean W. Beeckman ,  Sylvain S. Hantzer ,  Geoffrey L. Woolery ,  Glenn R. Sweeten

发明人： Stephen J. McCarthy ,  Jean W. Beeckman ,  Sylvain S. Hantzer ,  Geoffrey L. Woolery ,  Glenn R. Sweeten

IPC分类号： C07C5/10

CPC分类号： B01J29/043 ,  B01J29/0308 ,  B01J29/0325 ,  B01J29/041 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/10 ,  C07C2521/04 ,  C10G45/62 ,  C10G45/64 ,  C10G65/08 ,  C10G2400/10

摘要： An improved hydrotreating process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof, a mesoporous support, and a binder.

摘要翻译： 改进的加氢处理方法，其利用含有选自第VIII族贵金属及其混合物的氢化 - 脱氢组分的催化剂，中孔载体和粘合剂，用于润滑油沸程进料流。

公开(公告)号：US20090216056A1

公开(公告)日：2009-08-27

申请号：US12070861

申请日：2008-02-21

申请人： Jean W. Beeckman ,  Theodore E. Datz ,  Glenn R. Sweeten ,  Jason Wu

发明人： Jean W. Beeckman ,  Theodore E. Datz ,  Glenn R. Sweeten ,  Jason Wu

IPC分类号： B29C47/00 ,  B01J21/00 ,  C07C2/00

CPC分类号： B01J37/0009 ,  B01J21/08 ,  B01J23/04 ,  B01J29/06 ,  B01J29/40 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J2229/42 ,  C04B35/14 ,  C04B35/16 ,  C04B35/6263 ,  C04B35/62695 ,  C04B2235/3201 ,  C04B2235/6021

摘要： In a method of forming a shaped body, a mixture is formed comprising a particulate silica-rich material, water and a potassium base or basic salt, wherein the total solids content of the mixture is from about 20 to about 90 weight percent. The mixture is extruded into extrudates and the extrudates are dried and heated to a temperature of from about 300° C. to about 800° C. to form the shaped body.

摘要翻译： 在形成成形体的方法中，形成包含颗粒二氧化硅的材料，水和钾碱或碱式盐的混合物，其中混合物的总固体含量为约20至约90重量％。 将混合物挤出成挤出物，并将挤出物干燥并加热至约300℃至约800℃的温度以形成成形体。

公开(公告)号：US07553790B2

公开(公告)日：2009-06-30

申请号：US11258440

申请日：2005-10-25

申请人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Daria N. Lissy ,  David L. Stern ,  Stephen J. McCarthy ,  Dominick N. Mazzone ,  Christine N. Elia

发明人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Daria N. Lissy ,  David L. Stern ,  Stephen J. McCarthy ,  Dominick N. Mazzone ,  Christine N. Elia

IPC分类号： B01J29/06

CPC分类号： B01J29/40 ,  B01J2229/42

摘要： The present invention describes a method to increase the activity of a catalyst by first performing an ion exchange step with a potassium ion, followed by performing an ion-exchange step with an ammonium ion. Specifically, the present invention describes a method to increase the acidity of a zeolite by incorporating a potassium salt ion-exchange prior to an ammonium salt ion-exchange step. Even more specifically, the present invention is drawn to a method of increasing the activity of a zeolite by employing more than one potassium ion exchanges followed by at least one ammonium ion exchange. The present invention also describes a method to reduce the amount of sodium normally found in commercially produced zeolite by employing any of these methods. The present invention is also drawn to the catalysts produced by any of these methods.

摘要翻译： 本发明描述了通过首先用钾离子进行离子交换步骤，然后用铵离子进行离子交换步骤来提高催化剂活性的方法。 具体地，本发明描述了通过在铵盐离子交换步骤之前引入钾盐离子交换来提高沸石的酸度的方法。 更具体地说，本发明涉及通过使用多于一种的钾离子交换，然后进行至少一种铵离子交换来提高沸石的活性的方法。 本发明还描述了一种通过使用任何这些方法来减少通常在商业生产的沸石中发现的钠的量的方法。 本发明还涉及通过任何这些方法制备的催化剂。

公开(公告)号：US08343335B2

公开(公告)日：2013-01-01

申请号：US12070861

申请日：2008-02-21

申请人： Jean W. Beeckman ,  Theodore E. Datz ,  Glenn R. Sweeten ,  Jason Wu

发明人： Jean W. Beeckman ,  Theodore E. Datz ,  Glenn R. Sweeten ,  Jason Wu

IPC分类号： C10G11/00

CPC分类号： B01J37/0009 ,  B01J21/08 ,  B01J23/04 ,  B01J29/06 ,  B01J29/40 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J2229/42 ,  C04B35/14 ,  C04B35/16 ,  C04B35/6263 ,  C04B35/62695 ,  C04B2235/3201 ,  C04B2235/6021

摘要： In a method of forming a shaped body, a mixture is formed comprising a particulate silica-rich material, water and a potassium base or basic salt, wherein the total solids content of the mixture is from about 20 to about 90 weight percent. The mixture is extruded into extrudates and the extrudates are dried and heated to a temperature of from about 300° C. to about 800° C. to form the shaped body.

公开(公告)号：US20080253959A1

公开(公告)日：2008-10-16

申请号：US11731870

申请日：2007-03-30

申请人： Ivy D. Johnson ,  Glenn R. Sweeten ,  Robert A. Crane

发明人： Ivy D. Johnson ,  Glenn R. Sweeten ,  Robert A. Crane

IPC分类号： C01B33/20 ,  C01B39/00

CPC分类号： C01B37/00 ,  C01B39/00

摘要： In a process for synthesizing a crystalline molecular sieve, an aqueous synthesis mixture is produced capable of forming the crystalline molecular sieve. Crystallization of the synthesis mixture is induced so as to form crystals of said molecular sieve in the synthesis mixture and, when crystallization is complete, the molecular sieve crystals are allowed or caused to separate from the remainder of the synthesis mixture to produce a solid phase comprising said molecular sieve crystals and a supernatant liquid phase. The supernatant liquid phase is then decanted from the solid phase to recover the molecular sieve crystals and the crystals are dried without initially being subjected to washing or filtration.

摘要翻译： 在合成结晶分子筛的方法中，制备能够形成结晶分子筛的水性合成混合物。 诱导合成混合物的结晶，以便在合成混合物中形成所述分子筛的晶体，并且当结晶完成时，使分子筛结晶与合成混合物的其余部分分离以产生包含 所述分子筛晶体和上清液相。 然后从固相中倾析出上清液相，回收分子筛晶体，并将晶体干燥，最初不进行洗涤或过滤。