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公开(公告)号：US09783516B2
公开(公告)日：2017-10-10
申请号：US15188075
申请日：2016-06-21
发明人： Paul Bloom , Alexandra Sanborn
IPC分类号： C07D307/54 , C09K3/00 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/44 , C08K5/06 , C07D307/16
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
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公开(公告)号：US20160297788A1
公开(公告)日：2016-10-13
申请号：US15188075
申请日：2016-06-21
发明人： Paul Bloom , Alexandra Sanborn
IPC分类号： C07D307/54 , C09K3/00 , C07D307/44 , C07D307/16 , C07D307/12
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
摘要翻译： 描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。 衍生物可以在2'碳上的5'碳和甲醇上具有含有烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。 合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。 还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。
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公开(公告)号：US20140200299A1
公开(公告)日：2014-07-17
申请号：US14215264
申请日：2014-03-17
发明人： Paul Bloom , Alexandra Sanborn
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5″ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
摘要翻译： 描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。 衍生物可以在5“碳和2'碳上的甲醇上具有与烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。 合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。 还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。
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公开(公告)号：US10253132B2
公开(公告)日：2019-04-09
申请号：US15548844
申请日：2016-02-09
发明人： Paul Bloom , Erik Hagberg
IPC分类号： C08F242/00 , C08F8/18 , C08F293/00 , C11C3/00 , C08L95/00 , C09F7/00
摘要： Compositions comprising renewable source derived polymer oil polymerization macroinitiators and multiblock polymer compositions derived therefrom by atom transfer radical polymerization are disclosed. Hard, glossy multiblock copolymers, thermoset multiblock copolymers, thermoplastic block copolymer elastomers, and methods of making and using these types of materials are disclosed.
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公开(公告)号：US10968305B2
公开(公告)日：2021-04-06
申请号：US16807116
申请日：2020-03-02
发明人： Paul Bloom , Erik Hagberg
IPC分类号： C08F293/00 , C08F242/00 , C11C3/00 , C09F7/00 , C08L95/00
摘要： Compositions comprising renewable source derived polymer oil polymerization macroinitiators and multiblock polymer compositions derived therefrom by atom transfer radical polymerization are disclosed. Hard, glossy multiblock copolymers, thermoset multiblock copolymers, thermoplastic block copolymer elastomers, and methods of making and using these types of materials are disclosed.
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6.发明申请公开(公告)号：US20190185607A1
公开(公告)日：2019-06-20
申请号：US16286093
申请日：2019-02-26
发明人： Paul Bloom , Erik Hagberg
IPC分类号： C08F293/00 , C08L95/00 , C09F7/00 , C08F242/00 , C11C3/00
CPC分类号： C08F293/005 , C08F242/00 , C08F2438/01 , C08L95/00 , C08L2555/32 , C08L2555/82 , C08L2555/84 , C09F7/00 , C11C3/00
摘要： Compositions comprising renewable source derived polymer oil polymerization macroinitiators and multiblock polymer compositions derived therefrom by atom transfer radical polymerization are disclosed. Hard, glossy multiblock copolymers, thermoset multiblock copolymers, thermoplastic block copolymer elastomers, and methods of making and using these types of materials are disclosed.
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7.发明申请公开(公告)号：US20190023632A1
公开(公告)日：2019-01-24
申请号：US16066758
申请日：2016-12-08
发明人： Paul Bloom , Chi Cheng Ma , Kevin Martin , Brennan Smith
IPC分类号： C07C29/149 , C07C67/08 , B01J25/00 , B01J25/02 , B01J23/72
摘要： A process is described for producing 1,3-butanediol, wherein an ester of poly-(R)-3-hydroxybutyrate such as formed by transesterification with an alcohol is reduced by hydrogenation in the presence of a skeletal copper-based catalyst to provide 1,3-butanediol. The 1,3-butanediol may be transesterified by reaction with additional poly-(R)-3-hydroxybutyrate ester to produce (R)-3-hydroxybutyl (R)-3-hydroxybutyrate.
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公开(公告)号：US09422258B2
公开(公告)日：2016-08-23
申请号：US14215157
申请日：2014-03-17
发明人： Paul Bloom , Alexandra Sanborn
IPC分类号： C07D307/54 , C07D307/16 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/44 , C08K5/06
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
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9.发明申请公开(公告)号：US20180030193A1
公开(公告)日：2018-02-01
申请号：US15548844
申请日：2016-02-09
发明人： Paul Bloom , Erik Hagberg
IPC分类号： C08F293/00 , C11C3/00 , C08L95/00
CPC分类号： C08F293/005 , C08F242/00 , C08F2438/01 , C08L95/00 , C08L2555/32 , C08L2555/82 , C08L2555/84 , C09F7/00 , C11C3/00
摘要： Compositions comprising renewable source derived polymer oil polymerization macroinitiators and multiblock polymer compositions derived therefrom by atom transfer radical polymerization are disclosed. Hard, glossy multiblock copolymers, thermoset multiblock copolymers, thermoplastic block copolymer elastomers, and methods of making and using these types of materials are disclosed.
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公开(公告)号：US09416119B2
公开(公告)日：2016-08-16
申请号：US14215264
申请日：2014-03-17
发明人： Paul Bloom , Alexandra Sanborn
IPC分类号： C07C41/26 , C07D307/54 , C07C43/13 , C07D307/12 , C07D307/44 , C08K5/06 , C07D307/16
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
摘要翻译： 描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。 衍生物可以在2'碳上的5'碳和甲醇上具有含有烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。 合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。 还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。
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