公开(公告)号：US20240355673A1

公开(公告)日：2024-10-24

申请号：US18136970

申请日：2023-04-20

Applicant: Applied Materials, Inc.

Inventor： Wei LEI ,  Sahil PATEL ,  Yixiong YANG ,  Yu LEI ,  Shiyu YUE ,  Yi XU ,  Tuerxun AILIHUMAER ,  Juhyun OH ,  Xianmin TANG ,  Rongjun WANG

IPC: H01L21/768 ,  H01L23/522 ,  H01L23/532

CPC classification number: H01L21/76843 ,  H01L21/76877 ,  H01L23/5226 ,  H01L23/53266 ,  C23C14/18 ,  H01L21/02063 ,  H01L21/28568

Abstract: Semiconductor devices and methods for molybdenum fill in semiconductor devices are provided. In one aspect, a method for processing a semiconductor device substrate is provided. The method includes exposing at least one feature formed in a dielectric layer to a grain modification layer deposition process to deposit a grain modification layer over at least a portion of the at least one feature. The at least one feature is defined by sidewall surfaces formed in the dielectric layer and a bottom surface extending between the sidewall surfaces. The method further includes exposing the at least one feature to a molybdenum deposition process to form a molybdenum-fill layer on the grain modification layer, wherein the grain modification layer comprises a metal different from molybdenum.