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    Process for hydroshifting dimethyl ether
    1.
    发明授权
    Process for hydroshifting dimethyl ether 失效
    氢化二甲醚的方法

    公开(公告)号：US5498370A

    公开(公告)日：1996-03-12

    申请号：US356492

    申请日：1994-12-15

    申请人： Alakananda Bhattacharyya ,  Arunabha Basu

    发明人： Alakananda Bhattacharyya ,  Arunabha Basu

    IPC分类号： C01B3/38 ,  C01B3/32 ,  F02C3/22 ,  C07C1/00 ,  C07C1/02

    CPC分类号： C01B3/326 ,  C01B3/323 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1076 ,  Y02P20/52

    摘要： A process for hydroshifting dimethyl ether is described which comprises passing a feed stream which includes dimethyl ether and steam to a hydroshifting reaction zone including an essentially alkali metal-free catalytic composition substantially composed of copper or nickel in elemental form. The process produces a hydroshifted product stream which is relatively rich in hydrogen, carbon monoxide, and carbon dioxide.The feed stream can be transported relatively easily in liquid form at comparatively low pressures. The hydroshifting reaction zone can include a hydrolysis reaction zone and a water-gas shift reaction zone. The hydrolyzed product and the water-gas shift product can be recovered to obtain hydrogen and carbon dioxide, respectively. Additionally, the hydroshifted product stream can be blended with an oxidizing stream and combusted to drive a turbine in order to generate mechanical energy.

    摘要翻译： 描述了一种用于氢化二甲醚的方法，其包括将包括二甲醚和蒸汽的进料流传送到包含基本上不含碱金属的催化剂组合物的水移动反应区，所述催化组合物基本上由元素形式的铜或镍组成。 该方法产生氢转移产物流，其相对富含氢，一氧化碳和二氧化碳。 进料流可以在相当低的压力下相对容易地以液体形式输送。 加氢反应区可包括水解反应区和水煤气变换反应区。 可以回收水解产物和水煤气变换产物以分别获得氢气和二氧化碳。 此外，氢化转化产物流可与氧化流混合并燃烧以驱动涡轮以产生机械能。

    Method of generating power in a dry low NOx combustion system
    2.
    发明授权
    Method of generating power in a dry low NOx combustion system 失效
    在干燥低NOx燃烧系统中发电的方法

    公开(公告)号：US06324827B1

    公开(公告)日：2001-12-04

    申请号：US08886352

    申请日：1997-07-01

    申请人： Arunabha Basu ,  Theo H. Fleisch ,  Carl A. Udovich ,  Alakananda Bhattacharyya ,  Michael J. Gradassi

    发明人： Arunabha Basu ,  Theo H. Fleisch ,  Carl A. Udovich ,  Alakananda Bhattacharyya ,  Michael J. Gradassi

    IPC分类号： F02C324

    CPC分类号： C10L1/02

    摘要： A method of generating power by passing a dimethyl ether-containing fuel to a dry low NOx combustor of a fired turbine-combustor in the presence of an oxygen-containing gas for combustion in the combustor to form flue gas, and then passing the flue gas to the turbine to generate power, wherein the fuel comprises a mixture of dimethyl ether, at least one alcohol and, optionally, a component selected from the group consisting of water and C1-C6 alkanes. The fuel composition used in the inventive method permits a safe and highly efficient operation of a dry low NOx combustion system, while at the same time, minimizing the generation of NOx and carbon monoxide emissions.

    摘要翻译： 一种通过使含二甲醚的燃料在燃烧的涡轮机燃烧器的干燥低NOx燃烧器中，在含氧气体存在下在燃烧器中燃烧以形成烟道气，然后通过烟气 到所述涡轮机以产生动力，其中所述燃料包括二甲醚，至少一种醇和任选的选自水和C 1 -C 6烷烃的组分的混合物。 在本发明方法中使用的燃料组合物允许干燥的低NOx燃烧系统的安全和高效的操作，同时使NOx和一氧化碳排放的产生最小化。

    Process for abatement of nitrogen oxides in exhaust from gas turbine power generation
    3.
    发明授权
    Process for abatement of nitrogen oxides in exhaust from gas turbine power generation 失效
    减少燃气轮机发电废气中氮氧化物的方法

    公开(公告)号：US5740667A

    公开(公告)日：1998-04-21

    申请号：US701387

    申请日：1996-08-22

    申请人： Alakananda Bhattacharyya ,  Arunabha Basu

    发明人： Alakananda Bhattacharyya ,  Arunabha Basu

    IPC分类号： B01D53/56 ,  C01B3/32 ,  C01B3/38 ,  F02C3/22 ,  F02C3/30 ,  F02C7/26 ,  F02B43/00

    CPC分类号： C01B3/326 ,  C01B3/323 ,  F02C3/30 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1076 ,  Y02P20/52 ,  Y02T10/16

    摘要： Emissions of nitrogen oxides in exhaust from gas turbine systems are reduced, in accordance with the invention, by introducing, into the combustor, a supplementary gaseous stream comprising dihydrogen, carbon monoxide and carbon dioxide, and a stream of gaseous fuel and/or mixtures thereof, with a source of dioxygen to form a combustible gaseous mixture; combusting the mixture to produce heat and a combustion product stream; and driving a turbine with the combustion product stream to produce an exhaust stream and to generate mechanical power. Supplementary gaseous streams are, advantageously, formed by a process for hydroshifting dimethyl ether, i.e. formed by a process which comprises passing a feed stream which includes dimethyl ether and steam to a hydroshifting, reaction zone including an essentially alkali metal-free catalytic composition substantially composed of copper or nickel in elemental form. This process produces a hydroshifted product stream which is, advantageously, relatively rich in dihydrogen, carbon monoxide, and carbon dioxide.

    摘要翻译： 根据本发明，通过将包含二氢，一氧化碳和二氧化碳的气态物流和/或其混合物的辅助气流引入燃烧室，减少了来自燃气轮机系统的排气中的氮氧化物的排放 与二氧源形成可燃气体混合物; 燃烧混合物以产生热量和燃烧产物流; 并且用燃烧产物流驱动涡轮以产生排气流并产生机械动力。 补充的气流有利地通过用于将二甲醚加氢的方法形成，即通过包括将包含二甲醚和蒸汽的进料流通入包含基本上不含碱金属的催化剂组合物的液力转移反应区的方法形成的方法 的铜或镍元素形式。 该方法产生氢转移产物流，其有利地是相对富含二氢，一氧化碳和二氧化碳。

    Process for hydroshifting dimethyl ether
    4.
    发明授权
    Process for hydroshifting dimethyl ether 失效
    氢化二甲醚的方法

    公开(公告)号：US5626794A

    公开(公告)日：1997-05-06

    申请号：US597209

    申请日：1996-02-06

    申请人： Alakananda Bhattacharyya ,  Arunabha Basu

    发明人： Alakananda Bhattacharyya ,  Arunabha Basu

    IPC分类号： C01B3/38 ,  C01B3/32 ,  F02C3/22 ,  C07C1/00 ,  C07C1/02

    CPC分类号： C01B3/326 ,  C01B3/323 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1076 ,  Y02P20/52

    摘要： A process for hydroshifting dimethyl ether is described which comprises passing a feed stream which includes dimethyl ether and steam to a hydroshifting reaction zone including an essentially alkali metal-free catalytic composition substantially composed of copper or nickel in elemental form. The process produces a hydroshifted product stream which is relatively rich in hydrogen, carbon monoxide, and carbon dioxide.The feed stream can be transported relatively easily in liquid form at comparatively low pressures. The hydroshifting reaction zone can include a hydrolysis reaction zone and a water-gas shift reaction zone. The hydrolyzed product and the water-gas shift product can be recovered to obtain hydrogen and carbon dioxide, respectively. Additionally, the hydroshifted product stream can be blended with an oxidizing stream and combusted to drive a turbine in order to generate mechanical energy.

    摘要翻译： 描述了一种用于氢化二甲醚的方法，其包括将包括二甲醚和蒸汽的进料流传送到包含基本上不含碱金属的催化剂组合物的水移动反应区，所述催化组合物基本上由元素形式的铜或镍组成。 该方法产生氢转移产物流，其相对富含氢，一氧化碳和二氧化碳。 进料流可以在相当低的压力下相对容易地以液体形式输送。 加氢反应区可包括水解反应区和水煤气变换反应区。 可以回收水解产物和水煤气变换产物以分别获得氢气和二氧化碳。 此外，氢化转化产物流可与氧化流混合并燃烧以驱动涡轮以产生机械能。

    Liquefaction of decarboxylated carbonaceous solids
    6.
    发明授权
    Liquefaction of decarboxylated carbonaceous solids 失效
    脱羧碳质固体的液化

    公开(公告)号：US5228982A

    公开(公告)日：1993-07-20

    申请号：US689192

    申请日：1991-04-22

    申请人： Charles G. Scouten ,  Arunabha Basu ,  Joseph T. Joseph

    发明人： Charles G. Scouten ,  Arunabha Basu ,  Joseph T. Joseph

    IPC分类号： C10G1/00

    CPC分类号： C10G1/006 ,  C10G1/00

    摘要： A composition consisting essentially of a carbonaceous solid containing at least one carboxyl group is heated with subcritical liquid water at decarboxylation conditions including a temperature of at least about 300.degree. F. to substantially decarboxylate the solid, thereby producing a stream comprising a decarboxylated solid and water. The water is separated from the decarboxylated solid prior to liquefying the solid.

    摘要翻译： 基本上由含有至少一个羧基的含碳固体组成的组合物在脱羧条件下，在包括至少约300°F的温度的脱羧条件下加热，使固体基本脱羧，从而产生包含脱羧固体和水 。 在液化固体之前，将水与脱羧固体分离。

    Aqueous process for recovering sulfur from hydrogen sulfide-bearing gas
    8.
    发明授权
    Aqueous process for recovering sulfur from hydrogen sulfide-bearing gas 有权
    从含硫化氢的气体中回收硫的水处理方法

    公开(公告)号：US09023310B1

    公开(公告)日：2015-05-05

    申请号：US14262216

    申请日：2014-04-25

    申请人： Arunabha Basu

    发明人： Arunabha Basu

    IPC分类号： C01B17/05 ,  C10L3/10 ,  B01D53/52

    CPC分类号： B01D53/52 ,  C01B17/05

    摘要： A process for recovering sulfur from a hydrogen sulfide-bearing gas utilizes an aqueous reaction medium, a temperature of about 110-150° C., and a high enough pressure to maintain the aqueous reaction medium in a liquid state. The process reduces material and equipment costs and addresses the environmental disadvantages associated with known processes that rely on high boiling point organic solvents.

    摘要翻译： 从含硫化氢的气体中回收硫的方法利用水反应介质，温度为约110-150℃，足够高的压力将水性反应介质保持在液态。 该方法降低材料和设备成本，并解决与依赖于高沸点有机溶剂的已知方法相关的环境缺点。