Polythiophene/Polyanion Compositions
    2.
    发明公开

    公开(公告)号:US20240279453A1

    公开(公告)日:2024-08-22

    申请号:US18567187

    申请日:2022-06-03

    申请人: Agfa-Gevaert NV

    摘要: A polythiophene dispersion including: (a) a polythiophene copolymer of a first monomer according to Formula I and a second monomer to Formula II, wherein A represents a substituted or unsubstituted C1 to C5 alkylene bridge further functionalized with at least one functional group selected from the group consisting of a sulfonic acid or salt thereof, a phosphonic acid or salt thereof, a phosphate ester or salt thereof, a sulfate ester or salt thereof and a carboxylic acid or salt thereof; B represents a substituted or unsubstituted C1 to C5 alkylene bridge with the proviso that B is not further functionalized with a pH responsive group; and a molar ratio of the first monomer to the second monomer is from 1/4 to 4/1, (b) a polymeric polyanion wherein at least 75 mol % of the monomeric units of the polymeric polyanion are functionalized with a functional group selected from the group consisting of a sulfonic acid or salt thereof, a phosphonic acid or salt thereof, a phosphate ester or salt thereof, a sulfate ester or salt thereof and a carboxylic acid or salt thereof, characterized in that a molar ratio of the functional groups of the polyanion to the sum of the first and second monomers of the polythiophene copolymer is from 1.1 to 1.75.

    Polythiophene/Polyanion Compositions
    9.
    发明公开

    公开(公告)号:US20240279489A1

    公开(公告)日:2024-08-22

    申请号:US18566238

    申请日:2022-06-03

    申请人: Agfa-Gevaert NV

    摘要: A conductive polymer dispersion comprising a polythiophene and a polyanion, characterized in that the polyanion is a homo- or copolymer of amonomer unit according to Formula (I), wherein any of R1 to R5 is selected from the group consisting of hydrogen, a halogen, an ether and a substituted or unsubstituted alkyl group with the proviso that at least one of R1 to R5 is a substituent according to Formula (II), wherein L represents a divalent linking group having less than (20) carbon atoms; n represents 0 or 1; R6 and R7 are independently selected from the group consisting of hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group and a substituted or unsubstituted aryl or heteroaryl group; any of L, R6 and R7 may represent the necessary atoms to form a 5 to 8 membered ring; M represents hydrogen or a counterion to compensate the negative charge of the sulfonate group; the dashed line represents a covalent bond to the phenyl ring of Formula (I).

    Radiation Curable Inkjet Ink for Alkaline Etching or Plating Applications

    公开(公告)号:US20220267908A1

    公开(公告)日:2022-08-25

    申请号:US17623026

    申请日:2020-06-09

    申请人: AGFA-GEVAERT NV

    发明人: Johan Loccufier

    摘要: A method of manufacturing metallic articles (6) including the steps of: —applying a radiation curable composition comprising a monomer including at least two polymerisable groups on a surface of a substrate thereby forming an image (2); —curing the image; —plating (4) or etching (3) a surface of the substrate not covered by the cured image by means of an alkaline solution; —removing (5) the cured image by means of an acidic solution; characterized in that a linking group between the polymerisable groups comprises at least one acid degradable or hydrolysable group selected from the group consisting of an acetal, a ketal, an orthoester, an orthocarbonate, a tertiary ester, a tertiary carbonate and a tertiary urethane and wherein the composition further comprises less than 10 wt % of other monomers including at least two polymerisable groups relative to the total weight of the polymerisable composition.