Process for the preparation of C.sub.1 -C.sub.4 -alkyl nitrites
    3.
    发明授权
    Process for the preparation of C.sub.1 -C.sub.4 -alkyl nitrites 失效
    制备C1-C4烷基亚硝酸盐的方法

    公开(公告)号:US5649322A

    公开(公告)日:1997-07-15

    申请号:US571625

    申请日:1995-12-11

    CPC分类号: C07C201/04

    摘要: C.sub.1 -C.sub.4 -Alkyl nitrites can be prepared by reaction of C.sub.1 -C.sub.4 -alkanols with nitrogen oxides with the participation of oxygen in a reactor designed as a scrubber column, nitrogen oxides having a proportion of more than 50% of NO of the total amount of gram atoms of N of the nitrogen oxides, oxygen and optionally inert gas being fed into the lower part of the reactor. 5 to 60% of the total amount of C.sub.1 -C.sub.4 -alkanol used is likewise fed into the lower part of the reactor in vaporous or atomized form, while the remaining C.sub.1 -C.sub.4 -alkanol is delivered to the column head.

    摘要翻译: C1-C4烷基亚硝酸盐可以通过在设计为洗涤塔的反应器中将C1-C4-链烷醇与氮氧化物反应而制备,氧化反应设计为总量超过NO的50% 的氮原子的氮原子的克原子,氧和任选的惰性气体被供给到反应器的下部。 使用的C 1 -C 4烷醇的总量的5-60%同样以蒸气或雾化的形式进料到反应器的下部,而剩余的C1-C4-链烷醇被输送到塔头。