Abstract:
The instant invention is directed to a separator for a high energy rechargeable lithium battery and the corresponding battery. The separator includes a ceramic composite layer and a polymeric microporous layer. The ceramic layers includes a mixture of inorganic particles and a matrix material. The ceramic layer is adapted, at least, to block dendrite growth and to prevent electronic shorting. The polymeric layer is adapted, at least, to block ionic flow between the anode and the cathode in the event of thermal runaway.
Abstract:
A battery separator is a microporous membrane. The membrane has a major volume of a thermoplastic polymer and a minor volume of an inert particulate filler. The filler is dispersed throughout the polymer. The membrane exhibits a maximum Z-direction compression of 95% of the original membrane thickness. Alternatively, the battery separator is a microporous membrane having a TMA compression curve with a first substantially horizontal slope between ambient temperature and 125° C., a second substantially horizontal slope at greater than 225° C. The curve of the first slope has a lower % compression than the curve of the second slope. The curve of the second slope is not less than 5% compression. The TMA compression curve is graphed so that the Y-axis represents % compression from original thickness and the X-axis represents temperature.
Abstract:
A battery separator is a microporous membrane. The membrane has a major volume of a thermoplastic polymer and a minor volume of an inert particulate filler. The filler is dispersed throughout the polymer. The membrane exhibits a maximum Z-direction compression of 95% of the original membrane thickness. Alternatively, the battery separator is a microporous membrane having a TMA compression curve with a first substantially horizontal slope between ambient temperature and 125° C., a second substantially horizontal slope at greater than 225° C. The curve of the first slope has a lower % compression than the curve of the second slope. The curve of the second slope is not less than 5% compression. The TMA compression curve is graphed so that the Y-axis represents % compression from original thickness and the X-axis represents temperature.
Abstract:
A lithium ion rechargeable battery comprises: a negative electrode adapted to give up electrons during discharge, a positive electrode adapted to gain electrons during discharge, a microporous separator sandwiched between said positive electrode and said negative electrode, an organic electrolyte being contained within said separator and being in electrochemical communication with said positive electrode and said negative electrode, and an oxidative barrier interposed between said separator and said positive electrode, and thereby preventing oxidation of said separator.
Abstract:
A battery separator is a microporous membrane. The membrane has a major volume of a thermoplastic polymer and a minor volume of an inert particulate filler. The filler is dispersed throughout the polymer. The membrane exhibits a maximum Z-direction compression of 95% of the original membrane thickness. Alternatively, the battery separator is a microporous membrane having a TMA compression curve with a first substantially horizontal slope between ambient temperature and 125° C., a second substantially horizontal slope at greater than 225° C. The curve of the first slope has a lower % compression than the curve of the second slope. The curve of the second slope is not less than 5% compression. The TMA compression curve is graphed so that the Y-axis represents % compression from original thickness and the X-axis represents temperature.
Abstract:
A steam generator includes a heat exchanger, a liquid header and a steam header. The heat exchanger is assembled by several heat exchanging subassemblies with the same structure. The heat exchanging subassembly includes a spiral heat transmission pipe bundle, a central cylinder and a sleeve. The spiral heat transmission pipes with different radii are concentrically and spirally arranged in an annular space between the central cylinder and the sleeve, to form one or more concentric heat exchanging pillar surfaces. One end of the liquid header is connected with a main water feeding pipe, and the other end of the liquid header is connected with the spiral heat transmission pipe bundle. One end of the steam header is connected with a main steam pipe, and the other end of the steam header is connected with the spiral heat transmission pipe bundle.
Abstract:
A multi-layer microporous battery separator which comprises: a high molecular weight polypropylene layer having a melt flow index of ≦1.2 measured at layer; a polyethylene layer; and a high molecular weight polypropylene layer having a melt flow index of ≦1.2 measured at layer. The resulting microporous battery separator which is formed by a dry stretch process produces the microporous battery separator which has a porosity of ≦37% while maintaining a gurley from 13-25 seconds and a thickness of ≦25 microns.
Abstract:
The invention is a method for preventing short circuiting in a lithium ion battery. The battery has an anode made of intercalation compound, a cathode made of an intercalation compound, and a separator having a thickness of 25 microns or less sandwiched between the anode and the cathode. The method includes the steps of rounding or beveling the edge portion of the cathode, so that during charging when the anode and cathode expand and squeeze the separator, the rounded or beveled edge portion of the cathode cannot cut the separator.
Abstract:
The instant invention is directed to a separator for a high energy rechargeable lithium battery and the corresponding battery. The separator includes a ceramic composite layer and a polymeric microporous layer. The ceramic layers includes a mixture of inorganic particles and a matrix material. The ceramic layer is adapted, at least, to block dendrite growth and to prevent electronic shorting. The polymeric layer is adapted, at least, to block ionic flow between the anode and the cathode in the event of thermal runaway.
Abstract:
A battery separator is a microporous membrane. The membrane has a major volume of a thermoplastic polymer and a minor volume of an inert particulate filler. The filler is dispersed throughout the polymer. The membrane exhibits a maximum Z-direction compression of 95% of the original membrane thickness. Alternatively, the battery separator is a microporous membrane having a TMA compression curve with a first substantially horizontal slope between ambient temperature and 125° C., a second substantially horizontal slope at greater than 225° C. The curve of the first slope has a lower % compression than the curve of the second slope. The curve of the second slope is not less than 5% compression. The TMA compression curve is graphed so that the Y-axis represents % compression from original thickness and the X-axis represents temperature.