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公开(公告)号：US4403039A
公开(公告)日：1983-09-06
申请号：US309905
申请日：1981-10-09
CPC分类号： G01N30/96 , G01N27/06 , G01N2030/965
摘要： A method of analyzing a sample solution containing an ionic species of interest paired with an ionic species of the opposite sign comprises introducing the sample solution into a separation column with an eluant solution, introducing an eluate from the separation column into the inner passage of a diffusion type deionizer of the double tubular construction which is defined by a tube of an ion exchange composition, while a scavenger solution is introduced into the outer passage of the deionizer in a direction of flow opposite to that of the eluate in the inner passage, whereby the ionic species of the opposite sign is removed from the eluate into the scavenger solution, and measuring the electric conductivity of the eluate from the deionizer to thereby determine the concentration of the ionic species of interest in the sample solution. An apparatus for carrying out this method is also disclosed.
摘要翻译： 分析含有与相反符号的离子种类相关的目的离子物质的样品溶液的方法包括将样品溶液用洗脱剂溶液引入分离柱，将洗脱液从分离塔引入扩散物的内部通道 由离子交换组合物管定义的双管状结构的型离子发生器，同时将清流剂溶液沿与内部通道中的洗脱液的流动方向相反的方向引入去离子发生器的外部通道中，由此， 将相反符号的离子物质从洗脱液中除去到清除剂溶液中，并测量去离子器的洗脱液的电导率，从而确定样品溶液中感兴趣的离子物质的浓度。 还公开了一种用于执行该方法的装置。
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公开(公告)号：US4981804A
公开(公告)日：1991-01-01
申请号：US479814
申请日：1990-02-14
CPC分类号： G01N30/96 , G01N30/44 , G01N2030/965 , Y10T436/25125 , Y10T436/255
摘要： A method and apparatus for determining, by use of ion chromatography, a microconstituent contained in a major constituent as impurities present in the major constituent. The invention causes only that portion of the effluent from the detector, shown on an ion chromatograph, that corresponds to the neighborhood of the microconstituent to be led again to the collecting valve. Thus, the microconstituent of the solution can be determined quickly and easily, without reference to the kind of microconstituent being tested.
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公开(公告)号：US4952126A
公开(公告)日：1990-08-28
申请号：US721563
申请日：1985-04-10
CPC分类号： G01N30/96 , G01N30/44 , G01N2030/965 , Y10T436/25125 , Y10T436/255
摘要： A method and apparatus for determining, by use of ion chromatography, a microconstituent contained in a major constituent as impurities present in the major constituent. The invention causes only that portion of the effluent from the detector, shown on an ion chromatograph, that corresponds to the neighborhood of the microconstituent to be led again to the collecting valve. Thus, the microconstituent of the solution can be determined quickly and easily, without reference to the kind of microconstituent being tested.
摘要翻译： 通过使用离子色谱法测定主要成分中所含的微量成分作为主要成分中存在的杂质的方法和装置。 本发明仅导致来自检测器（在离子色谱仪上显示）的部分流出物对应于微型成分附近再次被引导到收集阀。 因此，可以快速而容易地测定溶液的微组分，而不考虑被测试的微型成分的种类。
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公开(公告)号：US4584276A
公开(公告)日：1986-04-22
申请号：US701996
申请日：1985-02-15
CPC分类号： G01N30/96 , G01N2030/965 , Y10T436/25125 , Y10T436/255
摘要： Method and apparatus for analysis, by ion chromatography, of anions, in a sample solution, wherein accurate analysis of anions in the sample solution is obtained by passing carbonic acid, through a prescribed membrane, into the sample solution, thereby completely eliminating or sharply lessening the so-called water dip effect. The method and apparatus are further directed to enabling anions in the sample solution to be accurately analyzed by passing prescribed cations, through a prescribed membrane, into the sample solution, thereby depriving the sample solution of interfering anions otherwise abundantly present therein.
摘要翻译： 通过离子色谱法分析阴离子在样品溶液中的方法和装置，其中通过将碳酸通过规定的膜通过样品溶液而获得样品溶液中的阴离子的准确分析，从而完全消除或急剧减少 所谓的水浸效应。 该方法和装置进一步涉及通过将规定的阳离子通过规定的膜通过规定的阳离子，使样品溶液中的阴离子进行准确分析，从而剥离其中大量存在的干扰阴离子的样品溶液。
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公开(公告)号：US4533518A
公开(公告)日：1985-08-06
申请号：US385570
申请日：1982-06-07
IPC分类号： G01N30/02 , G01N27/06 , G01N30/60 , G01N30/84 , G01N30/96 , G01N31/04 , B01D13/00 , G01N31/08
CPC分类号： G01N30/96 , G01N2030/965 , Y10T436/25125 , Y10T436/255
摘要： Method and apparatus for analysis, by ion chromatography, of anions, in a sample solution, wherein accurate analysis of anions in the sample solution is obtained by passing carbonic acid, through a prescribed membrane, into the sample solution, thereby completely eliminating or sharply lessening the so-called water dip effect. The method and apparatus are further directed to enabling anions in the sample solution to be accurately analyzed by passing prescribed cations, through a prescribed membrane, into the sample solution, thereby depriving the sample solution of interfering anions otherwise abundantly present therein.
摘要翻译： 通过离子色谱法分析阴离子在样品溶液中的方法和装置，其中通过将碳酸通过规定的膜通过样品溶液而获得样品溶液中的阴离子的准确分析，从而完全消除或急剧减少 所谓的水浸效应。 该方法和装置进一步涉及通过将规定的阳离子通过规定的膜通过规定的阳离子，使样品溶液中的阴离子进行准确分析，从而剥离其中大量存在的干扰阴离子的样品溶液。
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6.发明授权Multi-layer ion exchanger for use in ion-exchange chromatography and method of producing the same 失效用于离子交换层析的多层离子交换剂及其制备方法
公开(公告)号：US4447559A
公开(公告)日：1984-05-08
申请号：US397060
申请日：1982-07-12
IPC分类号： C08F8/00 , B01J20/281 , B01J20/285 , B01J41/08 , B01J41/14 , B01J41/20 , C08F4/04 , C08F8/32 , G01N30/88 , G01N30/96 , C08J5/20
摘要： An ion exchanger comprising a carrier comprising a synthetic resin having no ion exchange group and having one or more particles of a predetermined size, and a plurality of ion exchange particles disposed on the surface of the carrier and bonded thereto by a binder, wherein the plurality of ion exchange particles are of sizes smaller than the sizes of the carrier particles, and wherein the binder is of a synthetic resin having the same or similar composition as that of the carrier. The ion exchanger is useable in ion chromatography systems.
摘要翻译： 一种离子交换器，其包含载体，所述载体包含不具有离子交换基团的合成树脂并具有一种或多种预定尺寸的颗粒，以及多个离子交换颗粒，其设置在所述载体的表面上并通过粘合剂结合到所述载体上，其中所述多个 的离子交换颗粒的尺寸小于载体颗粒的尺寸，并且其中粘合剂是具有与载体相同或相似组成的合成树脂。 离子交换剂可用于离子色谱系统。
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