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公开(公告)号:US20150194611A1
公开(公告)日:2015-07-09
申请号:US14666143
申请日:2015-03-23
Applicant: Thedford Keith Hollis , Xiaofei Zhang
Inventor: Thedford Keith Hollis , Xiaofei Zhang
CPC classification number: H01L51/0077 , C07F15/006 , C07F15/0086 , C09K11/06 , C09K2211/1007 , C09K2211/1044 , C09K2211/183 , C09K2211/185 , H01L51/0083 , H01L51/0084 , H01L51/0087 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H05B33/10 , H05B33/14 , Y02E10/549 , Y02P70/521
Abstract: We report the synthesis and characterization of four novel CCC—NHC pincer platinum(II) and palladium(II) complexes, which adopt a distorted square planar configuration. These complexes emit bright blue light in the solid state under UV irradiation with emissions that are stable in ambient atmosphere (O2 and H2O) for extended periods. We also report the synthesis and characterization of CCC—NHC pincer ligand nickel complexes, and solid state fluorescence spectra have been collected for two of the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Finally, we report the synthesis and characterization of CCC—NHC pincer ligand complexes for abnormal carbenes, triazole, and BIA.
Abstract translation: 我们报告了四种新型CCC-NHC钳状铂(II)和钯(II)配合物的合成和表征,其采用变形的正方形平面构型。 这些配合物在紫外线照射下在固体状态下发出明亮的蓝色光,其排放物在环境大气(O 2和H 2 O)中长时间稳定。 我们还报道了CCC-NHC钳配体镍络合物的合成和表征,并且已经收集了报道的两种络合物的固态荧光光谱。 代表性化合物的X射线结构分析表现出扭曲的平面几何形状。 最后,我们报告了CCC-NHC钳配体配合物异构卡宾,三唑和BIA的合成和表征。
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2.
公开(公告)号:US08699253B2
公开(公告)日:2014-04-15
申请号:US12676639
申请日:2008-09-05
Applicant: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
Inventor: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
IPC: H02M7/5387 , G05F1/40
CPC classification number: H02M7/538 , H02M2007/4811 , Y02B70/1441 , Y10T307/76
Abstract: The present invention discloses a control method for a soft switch circuit in a switch power source, which generates an alternating primary power filter current by controlling first and second primary power switching devices to be closed and opened, and generates an intermittent alternating resonant current in the same direction as the primary power filter current in a resonant branch by controlling forward and backward auxiliary switching devices to be closed and opened to thereby achieve closing of the first and second primary power switching devices at a zero voltage, and which generates a balance current with the same magnitude as and in the opposite direction to the resonant current in the resonant branch in at least a period of time during the resting of the resonant current by further controlling the forward and backward auxiliary switching devices to be closed and opened to thereby achieve an average current of zero across the resonant branch in a switching cycle. Without any additional balance circuit, this control method can address the imbalance problem of output power of the positive and negative direct current input voltage sources in a soft switch circuit of an existing switch power source.
Abstract translation: 本发明公开了一种用于开关电源中的软开关电路的控制方法,其通过控制第一和第二主电源开关器件闭合和断开来产生交流的一次电力滤波器电流,并且在所述开关电源中产生间歇的交流谐振电流 通过控制向前和向后的辅助开关装置闭合和断开来共振分支中的主要功率滤波器电流相同的方向,从而在零电压下实现第一和第二主要功率开关装置的闭合,并且其产生与 通过进一步控制正向和反向辅助开关装置关闭和打开,在谐振电流静止期间的至少一段时间内与谐振支路中的谐振电流相同的幅度和相反方向,从而实现 在开关周期中谐振支路的平均电流为零。 没有任何额外的平衡电路,该控制方法可以解决现有开关电源的软开关电路中正,负直流输入电压源的输出功率不平衡问题。
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公开(公告)号:US20120205554A1
公开(公告)日:2012-08-16
申请号:US13502330
申请日:2010-10-19
Applicant: Thedford Keith Hollis , Xiaofei Zhang
Inventor: Thedford Keith Hollis , Xiaofei Zhang
CPC classification number: H01L51/0077 , C07F15/006 , C07F15/0086 , C09K11/06 , C09K2211/1007 , C09K2211/1044 , C09K2211/183 , C09K2211/185 , H01L51/0083 , H01L51/0084 , H01L51/0087 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H05B33/10 , H05B33/14 , Y02E10/549 , Y02P70/521
Abstract: We report the synthesis and characterization of four novel CCC—NHC pincer platinum(II) and palladium(II) complexes, which adopt a distorted square planar configuration. These complexes emit bright blue light in the solid state under UV irradiation with emissions that are stable in ambient atmosphere (O2 and H2O) for extended periods. We also report the synthesis and characterization of CCC—NHC pincer ligand nickel complexes, and solid state fluorescence spectra have been collected for two of the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Finally, we report the synthesis and characterization of CCC—NHC pincer ligand complexes for abnormal carbens, triazole, and BIA.
Abstract translation: 我们报告了四种新型CCC-NHC钳状铂(II)和钯(II)配合物的合成和表征,其采用变形的正方形平面构型。 这些配合物在紫外线照射下在固体状态下发出明亮的蓝色光,其排放物在环境大气(O 2和H 2 O)中长时间稳定。 我们还报道了CCC-NHC钳配体镍络合物的合成和表征,并且已经收集了报道的两种络合物的固态荧光光谱。 代表性化合物的X射线结构分析表现出扭曲的平面几何形状。 最后,我们报道了CCC-NHC钳制配体配合物的异构卡宾,三唑和BIA的合成和表征。
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4.
公开(公告)号:US20100315152A1
公开(公告)日:2010-12-16
申请号:US12678030
申请日:2008-09-08
Applicant: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
Inventor: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
IPC: H03K17/687 , H02B99/00
CPC classification number: H02M7/537 , H02M3/158 , Y02B70/1425 , Y02B70/1441 , Y10T307/76
Abstract: The present invention relates to a control method for a soft switch circuit in a switch power supply, which controls first and second main power switch devices to be turned on and turned off constantly to generate an alternating main power filter current, and controls forward and backward auxiliary switch devices to be turned on and turned off to generate an intermittent alternating resonant current across a resonant branch in the same direction as the main power filter current to thereby achieve zero-voltage turn-on of the first and second main power switch devices; and further controls the forward and backward auxiliary switch devices to be turned on and turned off to generate compensation currents across the resonant branch in the opposite direction to the alternating main power filter current in at least a period of time during resting of the resonant current to thereby accomplish a charging and discharging process of resonant capacitors in a dead time. Thus, a freewheeling diode can be turned on normally, so that it is possible to avoid a damage to the devices due to an impact current and a spark voltage resulting at zero crossing of the current in the soft switch circuit.
Abstract translation: 本发明涉及一种用于开关电源中的软开关电路的控制方法,该控制方法控制第一和第二主电源开关器件不断接通和断开以产生交替的主电力滤波器电流,并且控制向前和向后 辅助开关装置导通和关断,以与主电力滤波器电流相同的方向在谐振支路上产生间歇的交流谐振电流,从而实现第一和第二主电源开关装置的零电压接通; 并且进一步控制正向和反向辅助开关器件导通和截止,以在至少一段时间内在谐振电流休止期间在与交流主功率滤波器电流相反的方向上跨谐振支路产生补偿电流 从而在死区时间内实现谐振电容器的充放电过程。 因此,续流二极管可以正常导通,使得可以避免由于冲击电流和导致软开关电路中的电流过零的火花电压而对器件的损坏。
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5.
公开(公告)号:US08416592B2
公开(公告)日:2013-04-09
申请号:US12678030
申请日:2008-09-08
Applicant: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
Inventor: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
CPC classification number: H02M7/537 , H02M3/158 , Y02B70/1425 , Y02B70/1441 , Y10T307/76
Abstract: The present invention relates to a control method for a soft switch circuit in a switch power supply, which controls first and second main power switch devices to be turned on and turned off constantly to generate an alternating main power filter current, and controls forward and backward auxiliary switch devices to be turned on and turned off to generate an intermittent alternating resonant current across a resonant branch in the same direction as the main power filter current to thereby achieve zero-voltage turn-on of the first and second main power switch devices; and further controls the forward and backward auxiliary switch devices to be turned on and turned off to generate compensation currents across the resonant branch in the opposite direction to the alternating main power filter current in at least a period of time during resting of the resonant current to thereby accomplish a charging and discharging process of resonant capacitors in a dead time. Thus, a freewheeling diode can be turned on normally, so that it is possible to avoid a damage to the devices due to an impact current and a spark voltage resulting at zero crossing of the current in the soft switch circuit.
Abstract translation: 本发明涉及一种用于开关电源中的软开关电路的控制方法,该控制方法控制第一和第二主电源开关器件不断接通和断开以产生交替的主电力滤波器电流,并且控制向前和向后 辅助开关装置导通和关断,以与主电力滤波器电流相同的方向在谐振支路上产生间歇的交流谐振电流,从而实现第一和第二主电源开关装置的零电压接通; 并且进一步控制正向和反向辅助开关器件导通和截止,以在至少一段时间内在谐振电流休止期间在与交流主功率滤波器电流相反的方向上跨谐振支路产生补偿电流 从而在死区时间内实现谐振电容器的充放电过程。 因此,续流二极管可以正常导通,使得可以避免由于冲击电流和导致软开关电路中的电流过零的火花电压而对器件的损坏。
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公开(公告)号:US09029804B2
公开(公告)日:2015-05-12
申请号:US13502330
申请日:2010-10-19
Applicant: Thedford Keith Hollis , Xiaofei Zhang
Inventor: Thedford Keith Hollis , Xiaofei Zhang
CPC classification number: H01L51/0077 , C07F15/006 , C07F15/0086 , C09K11/06 , C09K2211/1007 , C09K2211/1044 , C09K2211/183 , C09K2211/185 , H01L51/0083 , H01L51/0084 , H01L51/0087 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H05B33/10 , H05B33/14 , Y02E10/549 , Y02P70/521
Abstract: We report the synthesis and characterization of four novel CCC-NHC pincer platinum(II) and palladium(II) complexes, which adopt a distorted square planar configuration. These complexes emit bright blue light in the solid state under UV irradiation with emissions that are stable in ambient atmosphere (O2 and H2O) for extended periods. We also report the synthesis and characterization of CCC-NHC pincer ligand nickel complexes, and solid state fluorescence spectra have been collected for two of the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Finally, we report the synthesis and characterization of CCC-NHC pincer ligand complexes for abnormal carbenes, triazole, and BIA.
Abstract translation: 我们报告了四种新型CCC-NHC钳状铂(II)和钯(II)配合物的合成和表征,其采用变形的正方形平面构型。 这些配合物在紫外线照射下在固体状态下发出明亮的蓝色光,其排放物在环境大气(O 2和H 2 O)中长时间稳定。 我们还报道了CCC-NHC钳配体镍络合物的合成和表征,并且已经收集了报道的两种络合物的固态荧光光谱。 代表性化合物的X射线结构分析表现出扭曲的平面几何形状。 最后,我们报告了CCC-NHC钳配体配合物异构卡宾,三唑和BIA的合成和表征。
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7.
公开(公告)号:US20110278953A1
公开(公告)日:2011-11-17
申请号:US12676639
申请日:2008-09-05
Applicant: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
Inventor: Chuntao Zhang , Xiaofei Zhang , Xueli Xiao
IPC: H01H33/59
CPC classification number: H02M7/538 , H02M2007/4811 , Y02B70/1441 , Y10T307/76
Abstract: The present invention discloses a control method for a soft switch circuit in a switch power source, which generates an alternating primary power filter current by controlling first and second primary power switching devices to be closed and opened, and generates an intermittent alternating resonant current in the same direction as the primary power filter current in a resonant branch by controlling forward and backward auxiliary switching devices to be closed and opened to thereby achieve closing of the first and second primary power switching devices at a zero voltage, and which generates a balance current with the same magnitude as and in the opposite direction to the resonant current in the resonant branch in at least a period of time during the resting of the resonant current by further controlling the forward and backward auxiliary switching devices to be closed and opened to thereby achieve an average current of zero across the resonant branch in a switching cycle. Without any additional balance circuit, this control method can address the imbalance problem of output power of the positive and negative direct current input voltage sources in a soft switch circuit of an existing switch power source.
Abstract translation: 本发明公开了一种用于开关电源中的软开关电路的控制方法,其通过控制第一和第二主电源开关器件闭合和断开来产生交流的一次电力滤波器电流,并且在所述开关电源中产生间歇的交流谐振电流 通过控制向前和向后的辅助开关装置闭合和断开来共振分支中的主要功率滤波器电流相同的方向,从而在零电压下实现第一和第二主要功率开关装置的闭合,并且其产生与 通过进一步控制正向和反向辅助开关装置关闭和打开,在谐振电流静止期间的至少一段时间内与谐振支路中的谐振电流相同的幅度和相反方向,从而实现 在开关周期中谐振支路的平均电流为零。 没有任何额外的平衡电路,该控制方法可以解决现有开关电源的软开关电路中正,负直流输入电压源的输出功率不平衡问题。
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