公开(公告)号：US08991233B2

公开(公告)日：2015-03-31

申请号：US13455688

申请日：2012-04-25

申请人： Wayne A. Kriel ,  Graham M. Mullings

发明人： Wayne A. Kriel ,  Graham M. Mullings

IPC分类号： G01N30/04 ,  G01N30/12 ,  G01N30/88 ,  G01N33/24 ,  G01N33/28

CPC分类号： G01N30/12 ,  G01N30/88 ,  G01N33/241 ,  G01N33/2823 ,  G01N2030/8854 ,  G01N2030/8881

摘要： A self-contained analysis system operable to assess gas to oil ratio (GOR), shrinkage of reservoir fluid, and composition of pressurized reservoir fluids. The analysis system can be used for extended compositional analysis of rich flashed gas and lean gas samples as well as flashed equilibrium liquids, condensates, and black oils. Analysis of the various samples is achieved without cross contamination, for example, between rich flashed gases and lean gases or between extended natural gas and liquids (e.g., black oils and condensates). The system yields accurate results up to and including C20 for gas samples and up to and including C36+ for liquid samples, and entrained water.

摘要翻译： 一种独立的分析系统，可用于评估气油比（GOR），储层流体收缩和加压储层流体的组成。 分析系统可用于对富气体和贫气样品以及闪蒸的平衡液体，冷凝物和黑油进行扩展成分分析。 实现了各种样品的分析，例如在富含闪蒸气体和贫气之间或在延伸的天然气和液体（例如黑油和冷凝物）之间没有交叉污染。 该系统产生直到并包括C20的气体样品并且包括用于液体样品的C36 +和夹带的水的精确结果。

公开(公告)号：US07467540B2

公开(公告)日：2008-12-23

申请号：US11543411

申请日：2006-10-05

申请人： Wayne A. Kriel

发明人： Wayne A. Kriel

IPC分类号： G01N1/00 ,  G01N1/22 ,  G01N30/02 ,  G01N33/22

CPC分类号： G01N35/1095 ,  G01N1/2226 ,  G01N9/04 ,  G01N9/30 ,  G01N9/36 ,  G01N30/06 ,  G01N33/2835 ,  G01N2001/2229 ,  G01N2001/2267 ,  G01N2030/025 ,  G01N2030/065

摘要： A method of analyzing a composition including live crude includes separating the composition into a vapor phase and a liquid phase. A composition of the vapor phase is determined with a gas chromatograph. At least a portion of the liquid phase is deposited in a vessel, and a headspace vapor phase is collected from the vessel. A composition of the headspace vapor is determined with the gas chromatograph.

摘要翻译： 分析包含活粗品的组合物的方法包括将组合物分离成气相和液相。 用气相色谱仪测定蒸气相的组成。 将液相的至少一部分沉积在容器中，并从容器收集顶空气相。 用气相色谱仪测定顶空蒸气的组成。

公开(公告)号：US06910394B2

公开(公告)日：2005-06-28

申请号：US10160973

申请日：2002-05-30

申请人： Wayne A. Kriel

发明人： Wayne A. Kriel

IPC分类号： G01N30/12 ,  G01N30/20 ,  G01N30/30 ,  G01N1/00

CPC分类号： G01N30/30 ,  G01N30/20 ,  G01N2030/127 ,  G01N2030/3015 ,  G01N2030/3046

摘要： An improved chromatograph valve is provided which may be placed in close proximity to a chromatograph in order to avoid temperature variations in the space therebetween. The valve may include a multiple sample slot rotor movable in a single direction to reduce wear upon the rotor and valve body. The rotor sample slots as well as the pairs of sample and carrier gas ports upon the valve body may be diametrically opposed to allow a superior temperature gradient to be created across the valve, the gradient allowing a sample material to enter the valve in a single phase and exit the valve sufficiently volatilized.

摘要翻译： 提供了一种改进的色谱阀，其可以靠近色谱仪放置，以避免它们之间的空间温度变化。 阀可以包括可沿单一方向运动的多个样品槽转子，以减少转子和阀体上的磨损。 转子样品槽以及阀体上的一对样品和载气端口可以在径向上相对，以允许在阀门两端产生优异的温度梯度，梯度允许样品材料以单相进入阀 并使阀门离开充分挥发。

公开(公告)号：US08966969B2

公开(公告)日：2015-03-03

申请号：US13184874

申请日：2011-07-18

申请人： Wayne A. Kriel ,  Shuzong Cai ,  Francisco J. Azcarate

发明人： Wayne A. Kriel ,  Shuzong Cai ,  Francisco J. Azcarate

IPC分类号： E21B49/08 ,  G01N30/88

CPC分类号： G01N30/88 ,  G01N2030/8854

摘要： Processing a reservoir fluid sample includes separating the reservoir fluid sample into a vapor phase stream and a liquid phase stream, assessing a composition of the vapor phase stream, sampling a property of the liquid phase steam, and assessing a volume of a components of the liquid phase stream based at least in part on the sampled property of the liquid phase stream. A system for processing a reservoir fluid sample includes a volumetric receptacle adapted to accept the reservoir fluid sample, a phase separator configured to receive the reservoir fluid sample from the volumetric receptacle and to separate the reservoir fluid sample into a vapor phase stream and a liquid phase stream, a gas chromatograph arranged to receive the vapor phase stream from the phase separator, and a liquid flow meter configured to detect an interface including at least one component of the liquid phase stream.

摘要翻译： 处理储层流体样品包括将储层流体样品分离成气相物流和液相物流，评估气相物流的组成，取样液相蒸汽的性质，以及评估液体组分的体积 至少部分地基于液相流的采样特性。 用于处理储存器流体样品的系统包括适于接收储存器流体样品的容积式容器，相分离器，其被配置为从容积容器接收储存器流体样品并将储存器流体样品分离成气相流和液相 气流色谱仪，布置成接收来自相分离器的气相物流;以及液体流量计，被配置为检测包括液相物流的至少一个成分的界面。

公开(公告)号：US20120272715A1

公开(公告)日：2012-11-01

申请号：US13455688

申请日：2012-04-25

申请人： Wayne A. Kriel ,  Graham M. Mullings

发明人： Wayne A. Kriel ,  Graham M. Mullings

IPC分类号： G01N30/12

CPC分类号： G01N30/12 ,  G01N30/88 ,  G01N33/241 ,  G01N33/2823 ,  G01N2030/8854 ,  G01N2030/8881

摘要： A self-contained analysis system operable to assess gas to oil ratio (GOR), shrinkage of reservoir fluid, and composition of pressurized reservoir fluids. The analysis system can be used for extended compositional analysis of rich flashed gas and lean gas samples as well as flashed equilibrium liquids, condensates, and black oils. Analysis of the various samples is achieved without cross contamination, for example, between rich flashed gases and lean gases or between extended natural gas and liquids (e.g., black oils and condensates). The system yields accurate results up to and including C20 for gas samples and up to and including C36+ for liquid samples, and entrained water.

摘要翻译： 一种独立的分析系统，可用于评估气油比（GOR），储层流体收缩和加压储层流体的组成。 分析系统可用于对富气体和贫气样品以及闪蒸的平衡液体，冷凝物和黑油进行扩展成分分析。 实现了各种样品的分析，例如在富含闪蒸气体和贫气之间或在延伸的天然气和液体（例如黑油和冷凝物）之间没有交叉污染。 该系统产生直到并包括C20的气体样品并且包括用于液体样品的C36 +和夹带的水的精确结果。

公开(公告)号：US20120011919A1

公开(公告)日：2012-01-19

申请号：US13184874

申请日：2011-07-18

申请人： Wayne A. Kriel ,  Shuzong Cai ,  Francisco J. Azcarate

发明人： Wayne A. Kriel ,  Shuzong Cai ,  Francisco J. Azcarate

IPC分类号： G01N30/90

CPC分类号： G01N30/88 ,  G01N2030/8854

摘要： Processing a reservoir fluid sample includes separating the reservoir fluid sample into a vapor phase stream and a liquid phase stream, assessing a composition of the vapor phase stream, sampling a property of the liquid phase steam, and assessing a volume of a components of the liquid phase stream based at least in part on the sampled property of the liquid phase stream. A system for processing a reservoir fluid sample includes a volumetric receptacle adapted to accept the reservoir fluid sample, a phase separator configured to receive the reservoir fluid sample from the volumetric receptacle and to separate the reservoir fluid sample into a vapor phase stream and a liquid phase stream, a gas chromatograph arranged to receive the vapor phase stream from the phase separator, and a liquid flow meter configured to detect an interface including at least one component of the liquid phase stream.

摘要翻译： 处理储层流体样品包括将储层流体样品分离成气相物流和液相物流，评估气相物流的组成，取样液相蒸汽的性质，以及评估液体组分的体积 至少部分地基于液相流的采样特性。 用于处理储存器流体样品的系统包括适于接收储存器流体样品的容积式容器，相分离器，其被配置为从容积容器接收储存器流体样品并将储存器流体样品分离成气相流和液相 气流色谱仪，布置成接收来自相分离器的气相物流;以及液体流量计，被配置为检测包括液相物流的至少一个成分的界面。

公开(公告)号：US4521636A

公开(公告)日：1985-06-04

申请号：US562365

申请日：1983-12-16

申请人： Wayne A. Kriel

发明人： Wayne A. Kriel

IPC分类号： C07C41/09 ,  C07C43/164

CPC分类号： C07C41/09

摘要： Preparation of bis-(alpha-alkylbenzyl)ethers or substituted derivatives thereof by reaction at elevated temperature of the corresponding alpha alkylbenzyl alcohols in the presence of an aluminum sulfate treated calcined alumina catalyst, quenching of the catalyst and recovery of the desired ether by distillation following separation of the quenched catalyst, is disclosed. The alkyl methylbenzyl alcohol may be present as a component of an aromatic rich distill and product mixture derived from the ethyl benzene hydroperoxide epoxidation of an olefinically unsaturated compound.

摘要翻译： 通过在相应的α烷基苄醇在升高的温度下在硫酸铝处理的煅烧氧化铝催化剂存在下反应制备双 - （α-烷基苄基）醚或其取代的衍生物，淬灭催化剂并通过蒸馏回收所需的醚 公开了淬灭的催化剂的分离。 烷基甲基苄醇可以作为富含芳烃的蒸馏物的组分和衍生自烯属不饱和化合物的乙基苯氢过氧化物环氧化的产物混合物存在。

公开(公告)号：US20130192339A1

公开(公告)日：2013-08-01

申请号：US13750710

申请日：2013-01-25

申请人： Wayne A. Kriel ,  Mario A. Ibarra ,  Sven Lataire

发明人： Wayne A. Kriel ,  Mario A. Ibarra ,  Sven Lataire

IPC分类号： G01N30/28 ,  G01N1/22

CPC分类号： G01N30/28 ,  G01N1/22 ,  G01N1/2247 ,  G01N1/24 ,  G01N30/06 ,  G01N33/225 ,  G01N2001/105 ,  G01N2001/1093 ,  G01N2030/025

摘要： Composite sampling of a fluid flowing through a conduit includes collecting, in a vessel coupled to the conduit through which the fluid is flowing, a first discrete sample of fluid from the conduit, the first discrete sample having a first selected volume, and collecting, in the vessel and at a first interval from the first sample, a second discrete sample of the fluid from the conduit, the second discrete sample having a second selected volume, thereby forming a composite sample in the vessel while the vessel is coupled to conduit. The composite sample includes the first discrete sample and the second discrete sample, and may include one or more additional discrete samples. An apparatus for collecting the composite sample includes a gas chromatograph, and is arranged such that the composite sample is provided to the gas chromatograph without removing the composite sample from the apparatus or transporting the composite sample.

公开(公告)号：USH1651H

公开(公告)日：1997-06-03

申请号：US429894

申请日：1995-04-27

申请人： Winton G. Aubert ,  Wayne A. Kriel

发明人： Winton G. Aubert ,  Wayne A. Kriel

IPC分类号： B01D15/00 ,  B01J20/32 ,  B09B1/00 ,  B09C1/00 ,  C02F1/28 ,  B01D15/04

CPC分类号： C02F1/288 ,  B01J20/12 ,  B01J20/14 ,  B01J20/16 ,  B01J20/261 ,  B01J20/262 ,  B01J20/264 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/3021 ,  B01J20/3204 ,  B01J20/327 ,  B01J20/3272 ,  B01J20/3276 ,  B01J20/3425 ,  B01J20/3466 ,  B01J20/3483 ,  B01J2220/42 ,  B01J2220/58 ,  B09B1/00 ,  B09C1/002 ,  B09C2101/00

摘要： Volatile organic compounds, including, in particular, the BTEX group, present in wastewater and groundwater in concentrations of about 1.0 PPM to 100 PPM, may be removed by adsorption onto a polymer coated porous substrate. The substrate is preferably selected from a group consisting of mullite, diatomaceous earth and ground structural brick and fire brick. The polymer coatings may be applied by immersing the substrate in a solution of the polymer or the polymer coating may be generated on the substrate by polymerization of a substrate coated resin. Polystyrene, polypropylene glycol, polymethyl silicone, polyesters and polyurethanes may be used as the coating material. The adsorbent composition may be disposed in a packed column, as a liner for storage pits, as a barrier for surface bodies of water and groundwater flow, and may be regenerated or disposed of by deep well injection.

摘要翻译： 挥发性有机化合物，特别是BTEX组，其存在于废水和地下水中的浓度约为1.0PPM至100PPM，可通过吸附到聚合物涂覆的多孔基材上除去。 基材优选选自莫来石，硅藻土和地面结构砖和防火砖。 聚合物涂层可以通过将基底浸入聚合物的溶液中或通过基底涂布的树脂的聚合在基底上产生聚合物涂层来施加。 可以使用聚苯乙烯，聚丙二醇，聚甲基硅氧烷，聚酯和聚氨酯作为涂料。 吸附剂组合物可以作为用于储存坑的衬垫填充在填充柱中，作为水和地下水流的表面体的屏障，并且可以通过深井注入再生或处理。