Process for the preparation of isocyanates in the gas phase
    2.
    发明授权
    Process for the preparation of isocyanates in the gas phase 有权
    在气相中制备异氰酸酯的方法

    公开(公告)号:US09024057B2

    公开(公告)日:2015-05-05

    申请号:US12632117

    申请日:2009-12-07

    IPC分类号: C07C263/00 C07C263/10

    CPC分类号: C07C263/10 C07C265/14

    摘要: Aromatic isocyanates are produced by reacting one or more aromatic primary amines with phosgene in the gas phase. The phosgene and primary aromatic amine(s) are reacted at a temperature above the boiling temperature of the amine(s) in a reactor having a reaction space which is essentially rotationally symmetric to the direction of flow. The flow fate, averaged over the cross-section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is between 4 and 80% is not more than 8 m/sec. The flow rate averaged over the cross-section of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is 4 to 80% is always below the flow rate averaged over the cross-section at the start of this section.

    摘要翻译: 通过一种或多种芳族伯胺与气相中的光气反应制备芳族异氰酸酯。 光气和伯芳基胺在具有反应空间的反应器中在高于胺的沸点温度的温度下反应,反应空间基本上与流动方向旋转对称。 反应混合物沿着反应空间部分中基本上旋转对称的反应空间轴线的横截面平均流动,其中胺基转化为异氰酸酯基的反应空间为4-80% 不超过8米/秒。 反应混合物的横截面上的平均流量在反应空间的基本上旋转对称的反应空间的轴上,其中胺基转化为异氰酸酯基团的部分总是低于 在本节开头的横截面上平均流量。

    Catalyst and process for hydrogenating organic compounds
    9.
    发明授权
    Catalyst and process for hydrogenating organic compounds 失效
    用于氢化有机化合物的催化剂和方法

    公开(公告)号:US08614355B2

    公开(公告)日:2013-12-24

    申请号:US12997301

    申请日:2009-06-03

    IPC分类号: C07C209/00

    摘要: The invention relates to a catalyst and to a process for hydrogenating organic compounds. In particular, the invention is directed to a process and catalyst for hydrogenating organic compounds with hydrogen. The organic compounds are subjected to hydrogenation in the presence of a catalyst comprising nitrogen-doped carbon nanotubes as a catalytically active component, wherein the proportion of nitrogen in the nanotubes is in the range of from about 0.05 to 20 wt. %.

    摘要翻译: 本发明涉及一种催化剂和一种氢化有机化合物的方法。 特别地,本发明涉及用氢氢化有机化合物的方法和催化剂。 有机化合物在含有掺杂氮的碳纳米管作为催化活性组分的催化剂存在下进行氢化,其中纳米管中的氮的比例在约0.05至20重量%的范围内。 %。

    PREPARATION OF CNTS
    10.
    发明申请
    PREPARATION OF CNTS 审中-公开
    CNTS的准备

    公开(公告)号:US20130011328A1

    公开(公告)日:2013-01-10

    申请号:US13574321

    申请日:2011-01-20

    IPC分类号: D01F9/12 B82Y40/00

    摘要: The present invention relates to a process comprising the steps a) synthesis of carbon nanotubes, b) optional inerting and c) cooling of the product. The process permits problem-free handling and packing of the carbon nanotube material that is produced.

    摘要翻译: 本发明涉及包括以下步骤的方法:a)碳纳米管的合成,b)任选的惰性化和c)产物的冷却。 该方法允许无问题地处理和包装所生产的碳纳米管材料。