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公开(公告)号:US09050572B2
公开(公告)日:2015-06-09
申请号:US11735023
申请日:2007-04-13
申请人: Sigurd Buchholz , Maziar Kakhi , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
发明人: Sigurd Buchholz , Maziar Kakhi , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
CPC分类号: B01J8/18 , B01J8/24 , B01J2208/00548 , B01J2208/00575 , B01J2208/00584 , B01J2208/00672 , B01J2208/00681 , B01J2208/00725 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/36
摘要: The present invention relates to a process for the production of carbon nanotubes by decomposition of hydrocarbons on a heterogeneous catalyst in a fluidized bed reactor, wherein the reactor can be operated batchwise or continuously, and in the case of continuous operation discharge can take place with sifting or without sifting.
摘要翻译: 本发明涉及通过在流化床反应器中在非均相催化剂上分解碳氢化合物来生产碳纳米管的方法,其中反应器可以间歇或连续地操作,并且在连续操作的情况下,可以通过筛分 或不筛选。
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公开(公告)号:US09024057B2
公开(公告)日:2015-05-05
申请号:US12632117
申请日:2009-12-07
申请人: Klaus Biskup , Rainer Bruns , Wolfgang Lorenz , Fritz Pohl , Friedhelm Steffens , Volker Michele
发明人: Klaus Biskup , Rainer Bruns , Wolfgang Lorenz , Fritz Pohl , Friedhelm Steffens , Volker Michele
IPC分类号: C07C263/00 , C07C263/10
CPC分类号: C07C263/10 , C07C265/14
摘要: Aromatic isocyanates are produced by reacting one or more aromatic primary amines with phosgene in the gas phase. The phosgene and primary aromatic amine(s) are reacted at a temperature above the boiling temperature of the amine(s) in a reactor having a reaction space which is essentially rotationally symmetric to the direction of flow. The flow fate, averaged over the cross-section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is between 4 and 80% is not more than 8 m/sec. The flow rate averaged over the cross-section of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is 4 to 80% is always below the flow rate averaged over the cross-section at the start of this section.
摘要翻译: 通过一种或多种芳族伯胺与气相中的光气反应制备芳族异氰酸酯。 光气和伯芳基胺在具有反应空间的反应器中在高于胺的沸点温度的温度下反应,反应空间基本上与流动方向旋转对称。 反应混合物沿着反应空间部分中基本上旋转对称的反应空间轴线的横截面平均流动,其中胺基转化为异氰酸酯基的反应空间为4-80% 不超过8米/秒。 反应混合物的横截面上的平均流量在反应空间的基本上旋转对称的反应空间的轴上,其中胺基转化为异氰酸酯基团的部分总是低于 在本节开头的横截面上平均流量。
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公开(公告)号:US20130039839A1
公开(公告)日:2013-02-14
申请号:US13579007
申请日:2011-02-14
CPC分类号: B01J37/031 , B01J37/16 , B82Y30/00 , B82Y40/00 , C01B32/15
摘要: The invention relates to a novel process for the production of catalysts for the production of carbon nanotubes in agglomerated form, which are characterised by a low bulk density. This invention likewise provides the catalysts, their use in the production of carbon nanotubes in high catalyst-specific yields, and the carbon nanotubes produced by this process.
摘要翻译: 本发明涉及用于生产以团聚形式生产碳纳米管的催化剂的新方法,其特征在于低堆积密度。 本发明同样提供了催化剂,它们在以高催化剂特异性产率生产碳纳米管的用途,以及通过该方法生产的碳纳米管。
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公开(公告)号:US08093176B2
公开(公告)日:2012-01-10
申请号:US11673878
申请日:2007-02-12
申请人: Sigurd Buchholz , Volker Michele , Leslaw Mileczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
发明人: Sigurd Buchholz , Volker Michele , Leslaw Mileczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
IPC分类号: B01J23/00 , B01J23/32 , B01J23/58 , B01J23/56 , B01J23/70 , B01J23/74 , C01B31/00 , C01B31/02
CPC分类号: B01J37/033 , B01J23/8892 , B01J23/8898 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/164 , Y10S977/742
摘要: Process for the continuous production of catalysts which are useful for the production of carbon nanotubes by decomposition of gaseous carbon compounds.
摘要翻译: 用于连续生产可用于通过气态碳化合物分解生产碳纳米管的催化剂的方法。
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公开(公告)号:US20110233071A1
公开(公告)日:2011-09-29
申请号:US13131166
申请日:2009-12-05
CPC分类号: C25B11/14 , B01J21/185 , B82Y30/00 , C25B1/16 , C25B1/46 , C25B9/08 , C25B15/00 , C25B15/02 , H01M12/06 , Y02E60/366
摘要: Electrochemical process for the reduction of molecular oxygen in alkaline solutions in the presence of nitrogen-doped carbon nanotubes, in which no hydrogen peroxide forms as a by-product of the reduction.
摘要翻译: 用于在氮掺杂的碳纳米管存在下还原碱性溶液中的分子氧的电化学方法,其中没有过氧化氢作为还原的副产物形成。
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公开(公告)号:US20110042231A1
公开(公告)日:2011-02-24
申请号:US12922992
申请日:2009-03-19
申请人: Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann
发明人: Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann
CPC分类号: C25B1/26 , B01J21/185 , B82Y30/00 , C25B11/0447
摘要: Process for the reduction of oxygen in aqueous chlorine- and/or chloride-containing solutions in the presence of a catalyst comprising nitrogen-doped carbon nanotubes.
摘要翻译: 在含有氮掺杂碳纳米管的催化剂存在下还原含氯和/或氯化氯水溶液中的氧的还原方法。
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公开(公告)号:US20110005938A1
公开(公告)日:2011-01-13
申请号:US12920202
申请日:2009-03-25
申请人: Aurel Wolf , Leslaw Mleczko , Volker Michele , Jens Assmann , Jürgen Kintrup , Rainer Weber
发明人: Aurel Wolf , Leslaw Mleczko , Volker Michele , Jens Assmann , Jürgen Kintrup , Rainer Weber
CPC分类号: C25B11/0478 , C25B1/26
摘要: Apparatus for hydrogen chloride electrolysis, comprising a cathode that has a layer of nitrogen-doped carbon nanotubes having functional groups containing nitrogen.
摘要翻译: 用于氯化氢电解的装置,包括具有含氮杂质官能团的氮掺杂碳纳米管层的阴极。
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公开(公告)号:US20100276644A1
公开(公告)日:2010-11-04
申请号:US12743721
申请日:2008-12-09
申请人: Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann , Sigurd Buchholz
发明人: Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann , Sigurd Buchholz
CPC分类号: B01J37/031 , B01J23/002 , B01J23/8892 , B01J35/023 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01P2002/52 , C01P2004/04 , C01P2004/13 , C01P2004/54 , C01P2004/62 , C01P2004/64 , C01P2004/80 , B01J2523/22 , B01J2523/31 , B01J2523/72 , B01J2523/845
摘要: Process for producing nitrogen-doped carbon nanotubes (NCNTs) in a fluidized bed.
摘要翻译: 在流化床中生产氮掺杂碳纳米管(NCNTs)的方法。
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公开(公告)号:US08614355B2
公开(公告)日:2013-12-24
申请号:US12997301
申请日:2009-06-03
申请人: Aurel Wolf , Volker Michele , Jens Aβmann , Leslaw Mleczko
发明人: Aurel Wolf , Volker Michele , Jens Aβmann , Leslaw Mleczko
IPC分类号: C07C209/00
CPC分类号: C07C209/36 , B01J21/185 , B01J27/24 , B82Y30/00 , C07C211/46
摘要: The invention relates to a catalyst and to a process for hydrogenating organic compounds. In particular, the invention is directed to a process and catalyst for hydrogenating organic compounds with hydrogen. The organic compounds are subjected to hydrogenation in the presence of a catalyst comprising nitrogen-doped carbon nanotubes as a catalytically active component, wherein the proportion of nitrogen in the nanotubes is in the range of from about 0.05 to 20 wt. %.
摘要翻译: 本发明涉及一种催化剂和一种氢化有机化合物的方法。 特别地,本发明涉及用氢氢化有机化合物的方法和催化剂。 有机化合物在含有掺杂氮的碳纳米管作为催化活性组分的催化剂存在下进行氢化,其中纳米管中的氮的比例在约0.05至20重量%的范围内。 %。
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公开(公告)号:US20130011328A1
公开(公告)日:2013-01-10
申请号:US13574321
申请日:2011-01-20
申请人: Ralph Weber , Volker Michele , Leslaw Mleczko
发明人: Ralph Weber , Volker Michele , Leslaw Mleczko
CPC分类号: B82Y40/00 , B82Y30/00 , C01B32/168
摘要: The present invention relates to a process comprising the steps a) synthesis of carbon nanotubes, b) optional inerting and c) cooling of the product. The process permits problem-free handling and packing of the carbon nanotube material that is produced.
摘要翻译: 本发明涉及包括以下步骤的方法:a)碳纳米管的合成,b)任选的惰性化和c)产物的冷却。 该方法允许无问题地处理和包装所生产的碳纳米管材料。
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