公开(公告)号：US08962503B2

公开(公告)日：2015-02-24

申请号：US13547529

申请日：2012-07-12

申请人： Kensuke Nagai ,  Yuichi Suzuki ,  Terutaka Maehara

发明人： Kensuke Nagai ,  Yuichi Suzuki ,  Terutaka Maehara

IPC分类号： C03C3/087 ,  C03C4/02

CPC分类号： C03C3/087 ,  C03C4/02

摘要： To provide a colored glass plate, which uses sodium sulfate (Na2SO3) as a refining agent and which is capable of stably maintaining the mass percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 at a high level, while suppressing development of an amber color that is derived from sodium sulfate. A colored glass plate made of alkali-containing silica glass containing elements of iron, tin and sulfur, wherein the percentage of the total sulfur calculated as SO3 is at least 0.025% as represented by mass percentage based on oxides, the percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 is from 60 to 80% as represented by mass percentage, and the percentage of divalent tin calculated as SnO2 in the total tin calculated as SnO2 is at least 0.1% as represented by mol percentage.

摘要翻译： 提供一种使用硫酸钠（Na 2 SO 3）作为澄清剂的彩色玻璃板，其能够稳定地维持以Fe 2 O 3计算的总铁中以Fe 2 O 3计算的二价铁的质量百分比，并以高水平计算，同时抑制 来自硫酸钠的琥珀色。 由含有铁，锡和硫元素的含碱性硅玻璃制成的彩色玻璃板，其中以SO 3计算的总硫的百分比为0.025％，以氧化物为基准的质量百分比表示，计算的二价铁的百分比 以Fe 2 O 3计算的总铁中的Fe 2 O 3以质量百分比表示为60〜80％，以SnO 2计的总锡中计算的二价锡的百分比以摩尔百分比表示为至少0.1％。

公开(公告)号：US20120289394A1

公开(公告)日：2012-11-15

申请号：US13547529

申请日：2012-07-12

申请人： Kensuke NAGAI ,  Yuichi Suzuki ,  Terutaka Maehara

发明人： Kensuke NAGAI ,  Yuichi Suzuki ,  Terutaka Maehara

IPC分类号： C03C4/02 ,  C03C3/076 ,  C03C3/089 ,  C03C3/091 ,  C03C3/064 ,  C03C3/085 ,  C03C3/087 ,  C03C3/078 ,  C03C3/062 ,  C03C3/04 ,  C03C3/083

CPC分类号： C03C3/087 ,  C03C4/02

摘要： To provide a colored glass plate, which uses sodium sulfate (Na2SO3) as a refining agent and which is capable of stably maintaining the mass percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 at a high level, while suppressing development of an amber color that is derived from sodium sulfate. A colored glass plate made of alkali-containing silica glass containing elements of iron, tin and sulfur, wherein the percentage of the total sulfur calculated as SO3 is at least 0.025% as represented by mass percentage based on oxides, the percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 is from 60 to 80% as represented by mass percentage, and the percentage of divalent tin calculated as SnO2 in the total tin calculated as SnO2 is at least 0.1% as represented by mol percentage.

摘要翻译： 提供一种使用硫酸钠（Na 2 SO 3）作为澄清剂的彩色玻璃板，其能够稳定地维持以Fe 2 O 3计算的总铁中以Fe 2 O 3计算的二价铁的质量百分比，并以高水平计算，同时抑制 来自硫酸钠的琥珀色。 由含有铁，锡和硫元素的含碱性硅玻璃制成的彩色玻璃板，其中以SO 3计算的总硫的百分比为0.025％，以氧化物为基准的质量百分比表示，计算的二价铁的百分比 以Fe 2 O 3计算的总铁中的Fe 2 O 3以质量百分比表示为60〜80％，以SnO 2计的总锡中计算的二价锡的百分比以摩尔百分比表示为至少0.1％。

公开(公告)号：US07754631B2

公开(公告)日：2010-07-13

申请号：US12349559

申请日：2009-01-07

申请人： Terutaka Maehara ,  Manabu Nishizawa ,  Junichiro Kase ,  Syuji Matsumoto

发明人： Terutaka Maehara ,  Manabu Nishizawa ,  Junichiro Kase ,  Syuji Matsumoto

IPC分类号： C03C3/087 ,  C03C3/091 ,  C03C3/083 ,  C03C3/085 ,  C03C3/078

CPC分类号： C03C3/091 ,  G02F2001/133302 ,  G02F2202/09

摘要： To provide an alkali-free glass substrate, which has a high Young's modulus, a low linear expansion coefficient, a high strain point and a low density, does not devitrify in the float forming process and is excellent in acid resistance.An alkali-free glass substrate, which contains neither alkali component nor BaO and consists essentially of, as represented by mol % based on oxide, from 57.0 to 65.0% of SiO2, from 10.0 to 12.0% of Al2O3, from 6.0 to 9.0% of B2O3, from 5.0 to 10.0% of MgO, from 5.0 to 10.0% of CaO and from 2.5 to 5.5% of SrO, provided that MgO+CaO+SrO is from 16.0 to 19.0%, MgO/(MgO+CaO+SrO)≧0.40, and B2O3/(SiO2+Al2O3+B2O3)≦0.12; wherein Young's modulus ≧75 GPa; the linear expansion coefficient at from 50 to 350° C. is from 30×10−7/° C. to 40×10−7/° C.; the strain point ≧640° C.; the temperature T2 (the viscosity η satisfies log η=2)≦1,620° C.; the temperature T4 (the viscosity η satisfies log η=4)≦1,245° C.; the devitrification temperature ≦T4; and weight loss per unit area is at most 0.6 mg/cm2, when immersed in 0.1N HCl at 90° C. for 20 hours.

摘要翻译： 为了提供具有高杨氏模量，低线膨胀系数，高应变点和低密度的无碱玻璃基板，在浮法成形工艺中不会失透，并且耐酸性优异。 不含碱成分和BaO的碱性玻璃基材，其基本上由氧化物的摩尔％表示，SiO 2为57.0〜65.0％，Al 2 O 3为10.0〜12.0％，Al 2 O 3为6.0〜9.0％ B 2 O 3，MgO 5.0〜10.0％，CaO 5.0〜10.0％，SrO 2.5〜5.5％，MgO + CaO + SrO为16.0〜19.0％，MgO /（MgO + CaO + SrO）≥ 0.40和B2O3 /（SiO2 + Al2O3 + B2O3）＆nlE; 0.12; 其中杨氏模量≥75GPa; 50〜350℃的线膨胀系数为30×10 -7 /℃至40×10 -7 /℃。 应变点≧640℃。 温度T2（粘度＆eegr;满足log＆eegr = 2）＆nlE; 1,620℃。 温度T4（粘度＆eegr;满足log＆eegr; = 4）＆nlE; 1,245℃; 失透温度＆nlE; T4; 当在90℃下浸入0.1N HCl中20小时时，每单位面积的重量损失为0.6mg / cm 2以下。

公开(公告)号：US20090176640A1

公开(公告)日：2009-07-09

申请号：US12349559

申请日：2009-01-07

申请人： Terutaka Maehara ,  Manabu Nishizawa ,  Junichiro Kase ,  Syuji Matsumoto

发明人： Terutaka Maehara ,  Manabu Nishizawa ,  Junichiro Kase ,  Syuji Matsumoto

IPC分类号： C03C3/091 ,  C03B18/00

CPC分类号： C03C3/091 ,  G02F2001/133302 ,  G02F2202/09

摘要： To provide an alkali-free glass substrate, which has a high Young's modulus, a low linear expansion coefficient, a high strain point and a low density, does not devitrify in the float forming process and is excellent in acid resistance.An alkali-free glass substrate, which contains neither alkali component nor BaO and consists essentially of, as represented by mol % based on oxide, from 57.0 to 65.0% of SiO2, from 10.0 to 12.0% of Al2O3, from 6.0 to 9.0% of B2O3, from 5.0 to 10.0% of MgO, from 5.0 to 10.0% of CaO and from 2.5 to 5.5% of SrO, provided that MgO+CaO+SrO is from 16.0 to 19.0%, MgO/(MgO+CaO+SrO)≧0.40, and B2O3/(SiO2+Al2O3+B2O3)≦0.12; wherein Young's modulus ≧75 GPa; the linear expansion coefficient at from 50 to 350° C. is from 30×10−7/° C. to 40×10−7/° C.; the strain point ≧640° C.; the temperature T2 (the viscosity η satisfies log η=2)≦1,620° C.; the temperature T4 (the viscosity η satisfies log η=4)≦1,245° C.; the devitrification temperature ≦T4; and weight loss per unit area is at most 0.6 mg/cm2, when immersed in 0.1N HCl at 90° C. for 20 hours.

摘要翻译： 为了提供具有高杨氏模量，低线膨胀系数，高应变点和低密度的无碱玻璃基板，在浮法成形工艺中不会失透，并且耐酸性优异。 不含碱成分和BaO的碱性玻璃基材，其基本上由氧化物的摩尔％表示，SiO 2为57.0〜65.0％，Al 2 O 3为10.0〜12.0％，Al 2 O 3为6.0〜9.0％ B2O3为5.0〜10.0％，CaO为5.0〜10.0％，SrO为2.5〜5.5％，MgO + CaO + SrO为16.0〜19.0％，MgO /（MgO + CaO + SrO） = 0.40，B2O3 /（SiO2 + Al2O3 + B2O3）= 0.12; 其中杨氏模量> 75GPa; 在50至350℃的线性膨胀系数为30×10 -7 /℃至40×10 -7 /℃。 应变点> = 640°C。 温度T2（粘度eta满足log eta = 2）= 1,620℃。 温度T4（粘度eta满足log eta = 4）<= 1,245℃。 失透温度<= T4; 当在90℃下浸入0.1N HCl中20小时时，每单位面积的重量损失为0.6mg / cm 2以下。