公开(公告)号：US09580309B2

公开(公告)日：2017-02-28

申请号：US13819070

申请日：2010-08-31

申请人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

发明人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

IPC分类号： C01B3/50 ,  C01B3/04 ,  B01J23/00 ,  B01J23/10 ,  B01J23/14 ,  B01J23/22 ,  B01J23/26 ,  B01J23/34 ,  B01J23/63 ,  B01J23/66 ,  B01J23/83 ,  B01J37/02 ,  B01J37/03

CPC分类号： C01B3/047 ,  B01J23/002 ,  B01J23/10 ,  B01J23/14 ,  B01J23/22 ,  B01J23/26 ,  B01J23/34 ,  B01J23/63 ,  B01J23/66 ,  B01J23/83 ,  B01J37/0201 ,  B01J37/031 ,  B01J2523/00 ,  Y02E60/364 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/22

摘要： The present invention provides an ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon. By bringing the ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon into contact with ammonia and air at room temperature, the support in a reduced state reacts with oxygen to generate oxidation heat, and the temperature of the catalyst layer is increased in a moment. Once the temperature of the catalyst layer is increased to a temperature at which ammonia and oxygen react with each other, the ammonia oxidation reaction proceeds autonomously after that. The heat generated in this exothermic reaction is used in the course of decomposing ammonia in the presence of the catalytically active metal, thereby producing hydrogen.

摘要翻译： 本发明提供一种氨氧化/分解催化剂，其包含由可氧化还原性金属氧化物和负载在其上的催化活性金属构成的载体。 通过将包含由可氧化和可还原的金属氧化物构成的载体和负载在其上的催化活性金属的氨氧化/分解催化剂在室温下与氨和空气接触，还原态的载体与氧反应产生氧化热， 并且催化剂层的温度暂时增加。 一旦催化剂层的温度升高到氨和氧彼此反应的温度，氨氧化反应就自动进行。 在该放热反应中产生的热在催化活性金属存在下分解氨的过程中使用，从而产生氢。

公开(公告)号：US08932773B2

公开(公告)日：2015-01-13

申请号：US13255381

申请日：2010-03-11

申请人： Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi ,  Sadao Araki ,  Takuma Mori

发明人： Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi ,  Sadao Araki ,  Takuma Mori

IPC分类号： H01M8/06 ,  C01B3/04 ,  B01J8/02 ,  B01J8/04 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/745 ,  B01J23/755 ,  B01J35/02

CPC分类号： C01B3/047 ,  B01J8/0221 ,  B01J8/0438 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/745 ,  B01J23/755 ,  B01J35/023 ,  B01J2208/00061 ,  B01J2208/00274 ,  B01J2208/025 ,  C01B2203/06 ,  C01B2203/066 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  Y02E60/364

摘要： A hydrogen generating apparatus for effectively generating hydrogen from ammonia and relates to the hydrogen generating apparatus for generating hydrogen from ammonia. The apparatus comprises an ammonia oxidation part having ammonia oxidation catalysts which oxidizes ammonia, and an ammonia decomposition part having an ammonia decomposition catalyst which decomposes ammonia to generate nitrogen and hydrogen. The decomposition part is located downstream of the oxidation part in a direction of feed gas flow. The oxidation catalyst contains both a noble metal catalyst and a base metal catalyst, and a loading concentration of the noble metal catalyst in an upstream portion of the oxidation part is higher than a loading concentration of the noble metal catalyst in a downstream portion of the oxidation part, and/or the decomposition catalyst contains both a noble metal catalyst and a base metal catalyst, and a loading concentration of the noble metal catalyst in a downstream portion of the decomposition part is higher than a loading concentration of the noble metal catalyst in an upstream portion of the decomposition part.

摘要翻译： 一种用于从氨有效地产生氢的氢产生装置，涉及用于从氨产生氢的氢生成装置。 该装置包括具有氧化氨的氨氧化催化剂的氨氧化部分和具有分解氨以产生氮和氢的氨分解催化剂的氨分解部分。 分解部分沿着进料气流的方向位于氧化部分的下游。 氧化催化剂含有贵金属催化剂和贱金属催化剂，氧化部分上游部分的贵金属催化剂的负载浓度高于贵金属催化剂在氧化部分的下游部分的负载浓度 部分和/或分解催化剂含有贵金属催化剂和贱金属催化剂，并且贵金属催化剂在分解部分的下游部分的负载浓度高于贵金属催化剂在负载浓度 分解部分的上游部分。

公开(公告)号：US20110028309A1

公开(公告)日：2011-02-03

申请号：US12936531

申请日：2009-02-16

申请人： Susumu Hikazudani ,  Naoe Hino

发明人： Susumu Hikazudani ,  Naoe Hino

IPC分类号： B01J31/06

CPC分类号： B01J23/30 ,  B01D53/8628 ,  B01D53/88 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/002 ,  B01J37/0219 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/69

摘要： Disclosed are a slurry for the production of a denitration catalyst, which allows a catalytically active component to be present in the inner region of a ceramic fiber sheet so as to achieve extension of the catalyst life and also allows the production process to be shortened so as to reduce the production cost; a process for producing the slurry; a process for producing a denitration catalyst using the slurry; and a denitration catalyst produced by the process. The slurry of the invention for producing a denitration catalyst comprises a silica sol, titania particles, metavanadic acid particles supported on the titania particles, metatungstic acid particles, and an organic acid ammonium salt.

摘要翻译： 公开了一种用于生产脱硝催化剂的浆料，其允许催化活性组分存在于陶瓷纤维片的内部区域中，以实现催化剂寿命的延长，并且还允许缩短生产过程，以便 降低生产成本; 一种生产该浆料的方法; 使用该浆料生产脱硝催化剂的方法; 和通过该方法生产的脱硝催化剂。 用于制造脱硝催化剂的本发明的浆料包括二氧化硅溶胶，二氧化钛颗粒，负载在二氧化钛颗粒上的偏钒酸颗粒，偏钨酸颗粒和有机酸铵盐。

公开(公告)号：US08623313B2

公开(公告)日：2014-01-07

申请号：US13143619

申请日：2009-12-22

申请人： Norihiko Nakamura ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi

发明人： Norihiko Nakamura ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi

IPC分类号： C01C1/04

CPC分类号： C01B3/042 ,  B01J35/004 ,  C01B3/025 ,  C01B3/061 ,  C01B3/063 ,  C01B3/501 ,  C01B3/56 ,  C01B5/00 ,  C01B13/0207 ,  C01B13/0251 ,  C01B13/0281 ,  C01B2203/042 ,  C01B2203/068 ,  C01B2210/0053 ,  C01C1/0405 ,  Y02E60/364 ,  Y02P20/134 ,  Y02P20/52

摘要： The invention provides a process for efficient synthesis of ammonia. The process includes a water-splitting step in which water is decomposed to obtain a first source gas comprising hydrogen and oxygen, a first oxygen removal step in which the oxygen contained in the first source gas is at least partially separated and removed by an oxygen separating membrane or hydrogen separating membrane to obtain a second source gas having a lower oxygen concentration than the first source gas, a second oxygen removal step in which the oxygen in the second source gas is reacted with hydrogen to produce water for removal, or is adsorbed onto an adsorption medium for removal, to obtain a third source gas having a lower oxygen concentration than the second source gas, and an ammonia synthesis step in which the hydrogen in the third source gas is reacted with nitrogen to synthesize ammonia.

摘要翻译： 本发明提供了一种有效合成氨的方法。 该方法包括水分解步骤，其中水被分解以获得包含氢和氧的第一源气体，第一氧除去步骤，其中通过氧分离将至少部分地分离和除去第一源气体中所含的氧 膜或氢分离膜，以获得具有比第一源气体低的氧浓度的第二源气体;第二氧除去步骤，其中第二源气体中的氧与氢反应以产生除去水或吸附到 用于除去的吸附介质，以获得具有比第二源气体低的氧浓度的第三源气体，以及氨合成步骤，其中第三源气体中的氢与氮反应以合成氨。

公开(公告)号：US20130156687A1

公开(公告)日：2013-06-20

申请号：US13819070

申请日：2010-08-31

申请人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

发明人： Sadao Araki ,  Susumu Hikazudani ,  Takuma Mori ,  Akira Taniguchi

IPC分类号： C01B3/04

CPC分类号： C01B3/047 ,  B01J23/002 ,  B01J23/10 ,  B01J23/14 ,  B01J23/22 ,  B01J23/26 ,  B01J23/34 ,  B01J23/63 ,  B01J23/66 ,  B01J23/83 ,  B01J37/0201 ,  B01J37/031 ,  B01J2523/00 ,  Y02E60/364 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/22

摘要： The present invention provides an ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon. By bringing the ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon into contact with ammonia and air at ordinary temperature, the support in a reduced state reacts with oxygen to generate oxidation heat, and the temperature of the catalyst layer is increased in a moment. Once the temperature of the catalyst layer is increased to a temperature at which ammonia and oxygen react with each other, the ammonia oxidation reaction proceeds autonomously after that. The heat generated in this exothermic reaction is used in the course of decomposing ammonia in the presence of the catalytically active metal, thereby producing hydrogen.

摘要翻译： 本发明提供一种氨氧化/分解催化剂，其包含由可氧化还原性金属氧化物和负载在其上的催化活性金属构成的载体。 通过将包含由可氧化还原性金属氧化物构成的载体和负载有催化活性金属的氨氧化/分解催化剂在常温下与氨和空气接触，还原态的载体与氧气反应产生氧化热， 并且催化剂层的温度暂时增加。 一旦催化剂层的温度升高到氨和氧彼此反应的温度，氨氧化反应就自动进行。 在该放热反应中产生的热在催化活性金属存在下分解氨的过程中使用，从而产生氢。

公开(公告)号：US20110283960A1

公开(公告)日：2011-11-24

申请号：US13130201

申请日：2009-11-19

申请人： Susumu Hikazudani ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Norihiko Nakamura ,  Hidekazu Arikawa

发明人： Susumu Hikazudani ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Norihiko Nakamura ,  Hidekazu Arikawa

IPC分类号： F02B43/10

CPC分类号： F02B43/10 ,  B01D53/9436 ,  B01D2255/1025 ,  B01D2255/1026 ,  B01D2255/20738 ,  B01D2255/20753 ,  B01J23/42 ,  B01J23/46 ,  B01J23/58 ,  B01J23/74 ,  B01J35/04 ,  C01B3/047 ,  F02M25/12 ,  Y02E60/364 ,  Y02T10/121 ,  Y02T10/32

摘要： An ammonia-engine system is capable of supplying an ammonia cracking catalyst with a temperature necessary to promote a reaction even during low load operation in which a temperature of an exhaust gas from an ammonia engine is lower than an operating temperature of the ammonia cracking catalyst. In an ammonia-engine system provided with an ammonia engine (2) using ammonia as fuel and an ammonia cracking device (5) including an ammonia cracking catalyst that cracks ammonia and cracking ammonia to produce hydrogen, an ammonia oxidizing device (4) is provided between the ammonia engine (2) and the ammonia cracking device (5).

摘要翻译： 氨发动机系统即使在来自氨发动机的废气的温度低于氨裂化催化剂的运转温度的低负荷运转中，也能够提供具有促进反应所需的温度的氨裂解催化剂。 在使用氨作为燃料的氨发动机（2）的氨发动机系统中，具有氨裂解催化剂（氨裂解催化剂）的氨裂解装置（5）具有裂解氨和裂解氨以产生氢气，氨氧化装置（4） 在氨发动机（2）和氨裂解装置（5）之间。

公开(公告)号：US08585996B2

公开(公告)日：2013-11-19

申请号：US13143619

申请日：2009-12-22

申请人： Norihiko Nakamura ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi

发明人： Norihiko Nakamura ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Chikashi Inazumi

IPC分类号： C01C1/04

摘要： The invention provides a process for efficient synthesis of ammonia. The process includes a water-splitting step in which water is decomposed to obtain a first source gas comprising hydrogen and oxygen, a first oxygen removal step in which the oxygen contained in the first source gas is at least partially separated and removed by an oxygen separating membrane or hydrogen separating membrane to obtain a second source gas having a lower oxygen concentration than the first source gas, a second oxygen removal step in which the oxygen in the second source gas is reacted with hydrogen to produce water for removal, or is adsorbed onto an adsorption medium for removal, to obtain a third source gas having a lower oxygen concentration than the second source gas, and an ammonia synthesis step in which the hydrogen in the third source gas is reacted with nitrogen to synthesize ammonia.

公开(公告)号：US20130288890A1

公开(公告)日：2013-10-31

申请号：US13883302

申请日：2011-11-09

申请人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

发明人： Susumu Hikazudani ,  Takuma Mori ,  Sadao Araki

IPC分类号： B01J23/83 ,  B01J23/34 ,  B01J23/28 ,  B01J23/63

CPC分类号： C01B3/047 ,  B01J23/28 ,  B01J23/34 ,  B01J23/63 ,  B01J23/83 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/038 ,  B01J37/18 ,  H01M8/0606 ,  H01M8/222 ,  Y02E60/364

摘要： Provided is an ammonia oxidation/decomposition catalyst which can decrease the reduction temperature of a support, which is required for the catalyst to have a property of being activated at room temperature, and also can render a property of being activated at a temperature lower than room temperature. The ammonia oxidation/decomposition catalyst of the present invention is an ammonia oxidation/decomposition catalyst, comprising: a catalyst support composed of a composite oxide of cerium oxide and zirconium oxide; and at least one metal selected from the group consisting of metals of group 6A, group 7A, group 8, and group 1B as a catalytically active metal deposited thereon, characterized in that the molar concentration of zirconium oxide in the catalyst support is from 10 to 90%.

摘要翻译： 提供了能够降低载体的还原温度的氨氧化/分解催化剂，催化剂具有在室温下被活化的性质，并且还可以使其在低于室温的温度下活化 温度。 本发明的氨氧化/分解催化剂是氨氧化/分解催化剂，包括：由氧化铈和氧化锆的复合氧化物构成的催化剂载体; 和选自6A，7A，8族和1B族金属中的至少一种金属作为沉积在其上的催化活性金属，其特征在于催化剂载体中氧化锆的摩尔浓度为10〜 90％。

公开(公告)号：US07825060B2

公开(公告)日：2010-11-02

申请号：US12441917

申请日：2007-09-18

申请人： Susumu Hikazudani ,  Kazuhiro Yano ,  Takehiro Shimizu ,  Hidetake Okamoto ,  Masaki Akiyama

发明人： Susumu Hikazudani ,  Kazuhiro Yano ,  Takehiro Shimizu ,  Hidetake Okamoto ,  Masaki Akiyama

IPC分类号： B01J27/24

CPC分类号： B01J37/024 ,  B01D53/8628 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01J23/30 ,  B01J35/04

摘要： A method for producing a catalyst of the present invention is characterized by sequentially performing the steps of: (i) dipping an end face portion of a carrier structure having a catalytic component carried thereon in an aqueous metal salt solution at a concentration of 2.7 to 3.88 mol/L in terms of mole of the metal; (ii) drying the dipped end face portion; (iii) dipping the dried end face portion again in an aqueous metal salt solution whose metal species is the same as that in the aqueous metal salt solution at a concentration of 2.7 to 3.88 mol/L in terms of mole of the metal; and (iv) performing a calcination treatment to harden the catalytic end face.

摘要翻译： 本发明的催化剂的制造方法的特征在于，依次进行以下工序：（i）将负载有催化剂成分的载体结构的端面部浸渍在金属盐水溶液中，浓度为2.7〜3.88 mol / L; （ii）干燥浸渍端面部分; （iii）将干燥的端面部分再次浸入与金属盐水溶液相同的金属盐溶液中，其浓度为金属摩尔量的2.7至3.88mol / L; 和（iv）进行煅烧处理以硬化催化剂端面。

公开(公告)号：US20100041547A1

公开(公告)日：2010-02-18

申请号：US12441917

申请日：2007-09-18

申请人： Susumu Hikazudani ,  Kazuhiro Yano ,  Takehiro Shimizu ,  Hidetake Okamoto ,  Masaki Akiyama

发明人： Susumu Hikazudani ,  Kazuhiro Yano ,  Takehiro Shimizu ,  Hidetake Okamoto ,  Masaki Akiyama

IPC分类号： B01J27/24

CPC分类号： B01J37/024 ,  B01D53/8628 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01J23/30 ,  B01J35/04

摘要： A method for producing a catalyst of the present invention is characterized by sequentially performing the steps of: (i) dipping an end face portion of a carrier structure having a catalytic component carried thereon in an aqueous metal salt solution at a concentration of 2.7 to 3.88 mol/L in terms of mole of the metal; (ii) drying the dipped end face portion; (iii) dipping the dried end face portion again in an aqueous metal salt solution whose metal species is the same as that in the aqueous metal salt solution at a concentration of 2.7 to 3.88 mol/L in terms of mole of the metal; and (iv) performing a calcination treatment to harden the catalytic end face.

摘要翻译： 本发明的催化剂的制造方法的特征在于，依次进行以下工序：（i）将负载有催化剂成分的载体结构的端面部浸渍在金属盐水溶液中，浓度为2.7〜3.88 mol / L; （ii）干燥浸渍端面部分; （iii）将干燥的端面部分再次浸入与金属盐水溶液相同的金属盐溶液中，其浓度为金属摩尔量的2.7至3.88mol / L; 和（iv）进行煅烧处理以硬化催化剂端面。