公开(公告)号：US09399207B2

公开(公告)日：2016-07-26

申请号：US14007084

申请日：2012-02-02

申请人： Susumu Hikazudani ,  Naoe Hino

发明人： Susumu Hikazudani ,  Naoe Hino

IPC分类号： B01J23/30 ,  B01J21/06 ,  B01J23/22 ,  B01J35/02 ,  B01D53/86

CPC分类号： B01J23/30 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/9202 ,  B01D2257/404 ,  B01D2258/0283 ,  B01J21/063 ,  B01J23/22 ,  B01J35/023

摘要： Provided is a preparation method of a denitration catalyst for treating nitrogen oxides contained in exhaust gas discharged from gas turbines for generating plants, coil fired boilers, etc., in which the catalytic activity can be improved, and furthermore, an increase of the cost of producing the catalyst is not involved. The preparation method of a denitration catalyst used when reacting nitrogen oxides with reducing agent ammonia to decompose the nitrogen oxides into nitrogen and water, and including titanium oxide and vanadium as catalytic active ingredients thereof, is characterized in that the vanadium precursor is ammonium metavanadate powder, the ammonium metavanadate powder containing particles having a particle diameter of 10 μm or less in a cumulative ratio of 20% or more. The ammonium metavanadate powder is preferably a reclaimed product including vanadium recovered from petroleum-based combustion ash such as heavy oil ash.

摘要翻译： 本发明提供了一种用于处理由燃气轮机排出的废气中所含的氮氧化物的脱硝催化剂的制备方法，所述排气是可以提高催化活性的发电厂，线圈式燃烧锅炉等，此外， 生产催化剂不涉及。 当氮氧化物与还原剂氨反应以将氮氧化物分解成氮和水，并且包括氧化钛和钒作为其催化活性成分时，使用的脱硝催化剂的制备方法的特征在于钒前体是偏钒酸铵粉末， 含有粒径为10μm以下的颗粒的偏钒酸铵粉末的累积比为20％以上。 偏钒酸铵粉末优选是包括从石油基燃烧灰如重油灰回收的钒的再生产物。

公开(公告)号：US20140018236A1

公开(公告)日：2014-01-16

申请号：US14007084

申请日：2012-02-02

申请人： Susumu Hikazudani ,  Naoe Hino

发明人： Susumu Hikazudani ,  Naoe Hino

IPC分类号： B01J23/30

CPC分类号： B01J23/30 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/9202 ,  B01D2257/404 ,  B01D2258/0283 ,  B01J21/063 ,  B01J23/22 ,  B01J35/023

摘要： Provided is a preparation method of a denitration catalyst for treating nitrogen oxides contained in exhaust gas discharged from gas turbines for generating plants, coil fired boilers, etc., in which the catalytic activity can be improved, and furthermore, an increase of the cost of producing the catalyst is not involved. The preparation method of a denitration catalyst used when reacting nitrogen oxides with reducing agent ammonia to decompose the nitrogen oxides into nitrogen and water, and including titanium oxide and vanadium as catalytic active ingredients thereof, is characterized in that the vanadium precursor is ammonium metavanadate powder, the ammonium metavanadate powder containing particles having a particle diameter of 10 μm or less in a cumulative ratio of 20% or more. The ammonium metavanadate powder is preferably a reclaimed product including vanadium recovered from petroleum-based combustion ash such as heavy oil ash.

摘要翻译： 本发明提供了一种用于处理由燃气轮机排出的废气中所含的氮氧化物的脱硝催化剂的制备方法，所述排气是可以提高催化活性的发电厂，线圈式燃烧锅炉等，此外， 生产催化剂不涉及。 当氮氧化物与还原剂氨反应以将氮氧化物分解成氮和水，并且包括氧化钛和钒作为其催化活性成分时，使用的脱硝催化剂的制备方法的特征在于钒前体是偏钒酸铵粉末， 含有粒径为10μm以下的颗粒的偏钒酸铵粉末的累计比例为20％以上。 偏钒酸铵粉末优选是包括从石油基燃烧灰如重油灰回收的钒的再生产物。

公开(公告)号：US08133833B2

公开(公告)日：2012-03-13

申请号：US12936531

申请日：2009-02-16

申请人： Susumu Hikazudani ,  Naoe Hino

发明人： Susumu Hikazudani ,  Naoe Hino

IPC分类号： B01J31/06

CPC分类号： B01J23/30 ,  B01D53/8628 ,  B01D53/88 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/002 ,  B01J37/0219 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/69

摘要： Disclosed are a slurry for the production of a denitration catalyst, which allows a catalytically active component to be present in the inner region of a ceramic fiber sheet so as to achieve extension of the catalyst life and also allows the production process to be shortened so as to reduce the production cost; a process for producing the slurry; a process for producing a denitration catalyst using the slurry; and a denitration catalyst produced by the process. The slurry of the invention for producing a denitration catalyst comprises a silica sol, titania particles, metavanadic acid particles supported on the titania particles, metatungstic acid particles, and an organic acid ammonium salt.

摘要翻译： 公开了一种用于生产脱硝催化剂的浆料，其允许催化活性组分存在于陶瓷纤维片的内部区域中，以实现催化剂寿命的延长，并且还允许缩短生产过程，以便 降低生产成本; 一种生产该浆料的方法; 使用该浆料生产脱硝催化剂的方法; 和通过该方法生产的脱硝催化剂。 用于制造脱硝催化剂的本发明的浆料包括二氧化硅溶胶，二氧化钛颗粒，负载在二氧化钛颗粒上的偏钒酸颗粒，偏钨酸颗粒和有机酸铵盐。

公开(公告)号：US20110028309A1

公开(公告)日：2011-02-03

申请号：US12936531

申请日：2009-02-16

申请人： Susumu Hikazudani ,  Naoe Hino

发明人： Susumu Hikazudani ,  Naoe Hino

IPC分类号： B01J31/06

CPC分类号： B01J23/30 ,  B01D53/8628 ,  B01D53/88 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/002 ,  B01J37/0219 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/69

摘要： Disclosed are a slurry for the production of a denitration catalyst, which allows a catalytically active component to be present in the inner region of a ceramic fiber sheet so as to achieve extension of the catalyst life and also allows the production process to be shortened so as to reduce the production cost; a process for producing the slurry; a process for producing a denitration catalyst using the slurry; and a denitration catalyst produced by the process. The slurry of the invention for producing a denitration catalyst comprises a silica sol, titania particles, metavanadic acid particles supported on the titania particles, metatungstic acid particles, and an organic acid ammonium salt.

摘要翻译： 公开了一种用于生产脱硝催化剂的浆料，其允许催化活性组分存在于陶瓷纤维片的内部区域中，以实现催化剂寿命的延长，并且还允许缩短生产过程，以便 降低生产成本; 一种生产该浆料的方法; 使用该浆料生产脱硝催化剂的方法; 和通过该方法生产的脱硝催化剂。 用于制造脱硝催化剂的本发明的浆料包括二氧化硅溶胶，二氧化钛颗粒，负载在二氧化钛颗粒上的偏钒酸颗粒，偏钨酸颗粒和有机酸铵盐。