公开(公告)号：US08444952B2

公开(公告)日：2013-05-21

申请号：US13140501

申请日：2009-11-26

Applicant: Mathias Dodin ,  Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

Inventor： Mathias Dodin ,  Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

IPC: C01B39/46 ,  C01B39/48 ,  B01J20/18 ,  B01D15/00 ,  B01D53/14

CPC classification number: C01B39/06 ,  B01J20/18 ,  C01B39/08

Abstract: The invention concerns a crystalline solid designated IM-20 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: sF: wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

Abstract translation: 本发明涉及一种称为IM-20的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。

公开(公告)号：US08372376B2

公开(公告)日：2013-02-12

申请号：US12301889

申请日：2007-05-10

Applicant: Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

Inventor： Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

IPC: C01B39/46 ,  C01B39/48

CPC classification number: C01B39/06 ,  C01B37/00 ,  C01B37/005

Abstract: The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO2: nYO2: pZ2O3: qR: sF: wH2O, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.

Abstract translation: 本发明涉及名称为IM-13的结晶固体，其具有如下提供的X射线衍射图。 所述固体具有根据通式mXO 2：n YO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，X表示一个或多个与以下不同的四价元素： 锗，Y表示锗，Z表示至少一种三价元素，F表示氟。

公开(公告)号：US20060115421A1

公开(公告)日：2006-06-01

申请号：US11256271

申请日：2005-10-24

Applicant: Philibert Leflaive ,  Anne-Claire Dubreuil ,  Philippe Caullet ,  Joel Patarin ,  Jean-Louis Paillaud

Inventor： Philibert Leflaive ,  Anne-Claire Dubreuil ,  Philippe Caullet ,  Joel Patarin ,  Jean-Louis Paillaud

IPC: C01B39/04 ,  C01B33/36 ,  C01F7/00

CPC classification number: C07C7/12 ,  B01D15/00 ,  B01D15/08 ,  B01D15/1821 ,  B01D53/02 ,  B01D2253/108 ,  B01J20/18 ,  B01J2220/54 ,  C07C7/13 ,  C10G25/03 ,  C10G25/05 ,  C10G2300/1025 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/30 ,  C10L3/10

Abstract: A process for adsorption separation uses a solid IM-12 type adsorbent to separate a molecular species from any feed.

Abstract translation: 吸附分离方法使用固体IM-12型吸附剂将分子种类与任何进料分离。

公开(公告)号：US20100324320A1

公开(公告)日：2010-12-23

申请号：US12301889

申请日：2007-05-10

Applicant: Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

Inventor： Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

IPC: C07F7/02

CPC classification number: C01B39/06 ,  C01B37/00 ,  C01B37/005

Abstract: The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO2: nYO2: pZ2O3: qR : sF : wH2O, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.

Abstract translation: 本发明涉及名称为IM-13的结晶固体，其具有如下提供的X射线衍射图。 所述固体具有根据通式mXO 2：n YO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，X表示一个或多个与以下不同的四价元素： 锗，Y表示锗，Z表示至少一种三价元素，F表示氟。

公开(公告)号：US20100286402A1

公开(公告)日：2010-11-11

申请号：US12669651

申请日：2008-06-24

Applicant: Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

Inventor： Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

IPC: C07F5/06 ,  C07F7/30 ,  C07F7/02

CPC classification number: C01B37/00 ,  B01J20/10 ,  B01J20/18 ,  C01B39/48 ,  Y10S423/30

Abstract: The invention relates to a crystallised solid, denoted by the name IM-16, which has an X-ray diffraction pattern as provided hereinafter. Said solid has a chemical composition expressed in accordance with the empirical formula mXO2:nGeO2:pZ2O3:qR:sF:wH2O, where R represents one or more organic species, X represents one or more tetravalent elements different from germanium, Z represents at least one trivalent element and F is fluorine.

Abstract translation: 本发明涉及具有如下文提供的X射线衍射图的由名称IM-16表示的结晶固体。 所述固体具有根据经验式mXO 2 :nGeO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一种或多种有机物质，X表示一种或多种不同于锗的四价元素，Z表示至少一种 三价元素，F为氟。

公开(公告)号：US5171556A

公开(公告)日：1992-12-15

申请号：US743967

申请日：1991-08-12

Applicant: Philippe Caullet ,  Jean-Louis Guth ,  Anne-Catherine Faust ,  Francis Raatz ,  Jean-Francois Joly ,  Jean-Marie Deves

Inventor： Philippe Caullet ,  Jean-Louis Guth ,  Anne-Catherine Faust ,  Francis Raatz ,  Jean-Francois Joly ,  Jean-Marie Deves

IPC: B01J29/70 ,  C01B39/48

CPC classification number: B01J29/7007 ,  C01B39/48 ,  B01J2229/26 ,  B01J2229/42

Abstract: The object of the invention is a synthetic crystalline zeolite of the beta type characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2where M represents a proton and/or a metallic cationn is the valence of Mx is a number ranging from 5 to 800,b) an X-ray diffraction diagram represented in table I of the description, andc) a fluorine content ranging from about 0.005 to 2.0% by weight, said zeolite having been furthermore synthetized in a fluoride medium.

Abstract translation: 本发明的目的是一种β型合成结晶沸石，其特征在于：a）以下近似通式：M 2 / nO，Al 2 O 3，xSiO 2，其中M表示质子和/或金属阳离子n是M x的化合价 是5〜800的数，b）说明书的表I所示的X射线衍射图，c）氟含量为0.005〜2.0重量％左右，所述沸石进一步在氟化物中合成 中。

公开(公告)号：US08372377B2

公开(公告)日：2013-02-12

申请号：US12742408

申请日：2008-10-17

Applicant: Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joël Patarin ,  Nicolas Bats

Inventor： Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joël Patarin ,  Nicolas Bats

IPC: C01B39/46 ,  C01B39/48 ,  B01D15/00 ,  B01D53/14 ,  B01J20/18

CPC classification number: C01B37/005 ,  B01J20/18 ,  C01B37/02 ,  C01B39/06

Abstract: The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2:nGeO2:pZ2O3:qR:sF:wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

Abstract translation: 本发明涉及一种称为IM-18的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。

公开(公告)号：US08216546B2

公开(公告)日：2012-07-10

申请号：US12513575

申请日：2007-10-01

Applicant: Yannick Lorgouilloux ,  Jean Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

Inventor： Yannick Lorgouilloux ,  Jean Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

IPC: C01B33/36 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01F7/00 ,  C01F7/02 ,  C01G17/02 ,  C01G19/02 ,  C03C3/102

CPC classification number: C01B39/06 ,  B01J20/06 ,  B01J20/08 ,  B01J20/22 ,  C01B37/00 ,  C01G17/00 ,  C01P2002/72

Abstract: A crystallized solid, referred to by the name IM-14, which has an X-ray diffraction diagram as provided below, is described. Said solid has a chemical composition that is expressed according to the formula GeO2:nY2O3:pR:qF:wH2O, where R represents one or more organic radical(s), Y represents at least one trivalent element, and F is fluorine.

Abstract translation: 描述了具有如下所述的具有X射线衍射图的名称为IM-14的结晶固体。 所述固体具有根据式GeO 2：n Y 2 O 3：p R：qF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，Y表示至少一个三价元素，F为氟。

公开(公告)号：US20110011810A1

公开(公告)日：2011-01-20

申请号：US12742408

申请日：2008-10-17

Applicant: Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joël Patarin ,  Nicolas Bats

Inventor： Yannick Lorgouilloux ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Joël Patarin ,  Nicolas Bats

IPC: C01B39/00 ,  B01D37/00

CPC classification number: C01B37/005 ,  B01J20/18 ,  C01B37/02 ,  C01B39/06

Abstract: The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2:nGeO2:pZ2O3:qR:sF:wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

Abstract translation: 本发明涉及一种称为IM-18的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。

公开(公告)号：US20100310449A1

公开(公告)日：2010-12-09

申请号：US12742283

申请日：2008-10-17

Applicant: Yannick Lorgouilloux ,  Jean Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

Inventor： Yannick Lorgouilloux ,  Jean Louis Paillaud ,  Philippe Caullet ,  Joel Patarin ,  Nicolas Bats

IPC: C01B39/02

CPC classification number: C01B37/005 ,  B01J20/10 ,  B01J20/18 ,  C01B39/06

Abstract: The invention concerns a crystalline solid designated IM-17 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: wH2O, in which R represents one or more organic nitrogen-containing species, X represents one or more tetravalent element(s) other than germanium and Z represents at least one trivalent element.

Abstract translation: 本发明涉及一种称为IM-17的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：wH2O，其中R表示一种或多种有机含氮物质，X表示除锗和Z之外的一种或多种四价元素 代表至少一种三价元素。