摘要:
A process for producing polypropylene from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. The catalyst may be pre-coked with a carbonaceous feed. Alternatively, the carbonaceous feed used to coke the catalyst may be co-fed with the naphtha feed.
摘要:
The invention is related to a two step process wherein the first step comprises cracking an olefinic naphtha resulting in a cracked product having a diminished total concentration of olefinic species. The second step comprises hydroprocessing at least a portion of the cracked product, especially a naphtha fraction, to provide a hydroprocessed cracked product having a reduced concentration of contaminant species but without a substantial octane reduction.
摘要:
Disclosed is a process for controlling combustion in a fluid catalytic cracking regenerator. More specifically, afterburning which occurs during the combustion process is controlled by adjusting oxygen concentration in at least one of two combustion streams which is injected into a fluid catalytic cracking regenerator. Preferably, the combustion streams used in the invention are asymmetrically injected into a dense phase catalyst bed within the regenerator.
摘要:
Piston deposits resulting from neutralizing combustion acids present in the lubricating oil circulating within the lubrication system of an internal combustion engine are reduced or eliminated by first cntacting the acids with a soluble weak base in the piston ring zone of the engine to form soluble neutral salts containing the weak base and the combustion acids. Thereafter, the neutral salts are contacted with a heterogenous strong base immobilized within the lubrication system but outside of the piston ring zone. The strong base displaces the weak base from the neutral salts, returning the weak base to the oil for recirculation to the piston ring zone for further use. The remaining strong base/combustion adic salts are immobilized as deposits with the strong base rather than on the piston. In a preferred embodiment, trioctadecyl amine is the weak base and magnesium oxide is the strong base.
摘要:
A filter system for use in a three-phase slurry reactor is provided. The filter system comprises one or more bundles of a plurality of filter elements for separating liquid from a mixture of liquid and solids contained in the reactor. Each filter bundle is connected to a product transfer conduit transporting separated liquid to a location outside of and downstream from the reactor. The transfer conduit is provided with means for backflushing the filter bundle and guard filter means.
摘要:
The invention relates to a process for maintaining heat balance in a fluidized bed catalytic cracking unit. More specifically, the invention relates to a combustion control method capable of maintaining or restoring heat balance by conducting, under appropriate conditions, fuel and an oxygen-containing gas to a transfer line. The transfer line conducts effluent including spent catalyst and combustion products to the unit's catalyst regeneration zone.
摘要:
The invention is related to a catalyst and a process for selectively producing light (i.e., C2-C4) olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions. The catalysts do not require steam activation.
摘要:
This invention relates to a process to produce propylene from a hydrocarbon feed stream, preferably a naphtha feed stream, comprising C5 and C6 components wherein a light portion having a boiling point range of 120° C. or less is introduced into a reactor separately from the other components of the feed stream.
摘要:
A process for obtaining a substantial amount of olefinic products from a residual feedstock by use of a vapor short contact time conversion process unit comprised of a bed of fluidized heat transfer solids. The vapor short contact time process unit is operated at conditions which includes steam dilution to reduce partial pressure of hydrocarbon vapors and a vapor residence time less than about 0.5 seconds.
摘要:
This invention is related to a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to about 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. The resulting product is a high octane naphtha.