公开(公告)号：US08658746B2

公开(公告)日：2014-02-25

申请号：US12976446

申请日：2010-12-22

申请人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

发明人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

IPC分类号： C08F16/24

CPC分类号： C08J5/2243 ,  C08J2327/12 ,  H01B1/122 ,  H01M4/8668 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56

摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

公开(公告)号：US20090088539A1

公开(公告)日：2009-04-02

申请号：US12329119

申请日：2008-12-05

申请人： Nobuyuki KASAHARA ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

发明人： Nobuyuki KASAHARA ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

IPC分类号： C08F2/34

CPC分类号： C08J5/2243 ,  C08J2327/12 ,  H01B1/122 ,  H01M4/8668 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56

摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

公开(公告)号：US20060092763A1

公开(公告)日：2006-05-04

申请号：US11232007

申请日：2005-09-22

申请人： Nobuyuki Kasahara ,  Shin Tatematsu ,  Shigeki Kobayashi ,  Yasuhiko Matsuoka ,  Hiroki Nagai ,  Terence Attwood ,  Steven McDonald ,  Philip MacKrell ,  Shigeki Hiraoka

发明人： Nobuyuki Kasahara ,  Shin Tatematsu ,  Shigeki Kobayashi ,  Yasuhiko Matsuoka ,  Hiroki Nagai ,  Terence Attwood ,  Steven McDonald ,  Philip MacKrell ,  Shigeki Hiraoka

IPC分类号： B01F7/08

CPC分类号： B01F3/04765 ,  B01F7/00158 ,  B01F7/0025 ,  B01F7/00275 ,  B01F7/00433 ,  B01F7/04 ,  B01F7/08 ,  B01J19/0066 ,  B01J2219/182

摘要： A gas/liquid mixing equipment of the present invention comprises a stirring vessel 1, a stirring shaft 10 inserted horizontally in the stirring vessel 1 and a helical ribbon impeller 20 attached to the stirring shaft 10, whereby a high gas absorption performance can be secured even with low shearing. Further, a polymer can be produced with high productivity. A gas/liquid mixing method of the present invention is a method which comprises employing the above-mentioned gas/liquid mixing equipment, and a method for producing a polymer of the present invention is a method which comprises polymerizing feed monomers containing gaseous monomers in aqueous solvents, wherein the gaseous monomers and the aqueous solvents are mixed by such a gas/liquid mixing method. A polymer of the present invention is produced by the above-mentioned method for producing a polymer.

摘要翻译： 本发明的气/液混合设备包括搅拌容器1，水平地插入搅拌容器1中的搅拌轴10和安装在搅拌轴10上的螺旋带叶轮20，由此甚至可以确保高气体吸收性能 低剪切。 此外，可以高生产率制造聚合物。 本发明的气/液混合方法是采用上述气/液混合设备的方法，本发明的聚合物的制造方法是将含有气态单体的进料单体在水溶液 溶剂，其中气态单体和水性溶剂通过这种气/液混合方法混合。 本发明的聚合物是通过上述聚合物的制造方法制造的。

公开(公告)号：US20060063903A1

公开(公告)日：2006-03-23

申请号：US11271915

申请日：2005-11-14

申请人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

发明人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

IPC分类号： C08F16/24

CPC分类号： C08J5/2243 ,  C08J2327/12 ,  H01B1/122 ,  H01M4/8668 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56

摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

公开(公告)号：US20050143540A1

公开(公告)日：2005-06-30

申请号：US11030295

申请日：2005-01-07

申请人： Ichiro Terada ,  Satoru Hommura ,  Nobuyuki Kasahara ,  Katsuya Ueno

发明人： Ichiro Terada ,  Satoru Hommura ,  Nobuyuki Kasahara ,  Katsuya Ueno

IPC分类号： C08F30/04 ,  C08F130/04 ,  C08F230/04 ,  C08J3/03 ,  C08J5/20 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M4/96

CPC分类号： C08J5/2293 ,  C08F30/04 ,  C08F130/04 ,  C08F230/04 ,  C08J3/05 ,  C08J5/20 ,  C08J2327/12 ,  C08J2327/18 ,  H01M4/8605 ,  H01M4/8803 ,  H01M4/8828 ,  H01M4/921 ,  H01M4/96 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1081 ,  Y02P70/56 ,  Y10T428/24802

摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25° C. at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.

摘要翻译： 通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声波振动或剪切力，使得分散体在25℃下的粘度 在10（1 / s）的剪切速率下，在增稠步骤中增加2-2000次。 当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。 此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上形成的层来制备作为催化剂层的膜 - 电极组件 通过相对于离子交换膜提供催化剂层，阴极和阳极中的至少一个。 由于催化剂层强度高，缺点少，光滑性好，因此可以得到固体高分子电解质燃料电池用高性能膜 - 电极组件。

公开(公告)号：US08026316B2

公开(公告)日：2011-09-27

申请号：US12616873

申请日：2009-11-12

申请人： Nobuyuki Kasahara ,  Noriaki Miyake

发明人： Nobuyuki Kasahara ,  Noriaki Miyake

IPC分类号： C08F8/22

CPC分类号： C08F8/22 ,  B01J19/0013 ,  B01J19/2415 ,  B01J2219/00087 ,  B29C47/0014 ,  C08F14/18 ,  C08F14/26 ,  C08F214/18 ,  C08F214/262 ,  C08F2/00

摘要： To provide a process for efficiently producing a perfluoropolymer having unstable terminal groups reduced. A process for producing a fluorination-treated perfluoropolymer, which comprises melting a thermoplastic perfluoropolymer to form strands and contacting the polymer strands with a fluorine gas. For fluorination-treatment of the perfluoropolymer, an apparatus 10 is used, which comprises a melt extruder 11 for melting and extruding the perfluoropolymer, a die 12 for forming the melt extruded polymer into continuous strands 1 and a fluorination tank 13 for contacting the continuous strands 1 with a fluorine gas.

摘要翻译： 提供一种有效生产具有不稳定末端基团的全氟聚合物降低的方法。 一种氟化处理的全氟聚合物的制造方法，其包括熔融热塑性全氟聚合物以形成股线并使聚合物链与氟气接触。 对于全氟聚合物的氟化处理，使用装置10，其包括用于熔融和挤出全氟聚合物的熔体挤出机11，用于将熔融挤出的聚合物形成为连续的链1的模具12和用于使连续的链条接触的氟化槽13 1与氟气。

公开(公告)号：US06410808B1

公开(公告)日：2002-06-25

申请号：US09840072

申请日：2001-04-24

申请人： Yutaka Furukawa ,  Nobuyuki Kasahara ,  Kazuya Oharu ,  Shin Tatematsu

发明人： Yutaka Furukawa ,  Nobuyuki Kasahara ,  Kazuya Oharu ,  Shin Tatematsu

IPC分类号： C07C3134

CPC分类号： C07C41/26 ,  C07C29/124 ,  C07C43/137 ,  C07C31/38

摘要： A method for producing a fluoroalcohol of the following formula 1a, which comprises reacting a compound of the following formula 1 with water in a liquid phase at a temperature of 150° C. or higher under a gauge pressure of 0.4 MPa or higher: wherein n is an integer of from 1 to 5, X is a chlorine atom, a bromine atom or an iodine atom, p is an integer of at least 1, and R is a p-valent organic group, provided that when p is 1, R may be a hydrogen atom or a halogen atom.

摘要翻译： 一种下式1a的氟代醇的制造方法，其特征在于，在表压为0.4MPa以上的条件下，使下式1的化合物与液相中的水在150℃以上的温度下反应：其中n 为1〜5的整数，X为氯原子，溴原子或碘原子，p为1以上的整数，R为p价有机基团，条件是当p为1时，R 可以是氢原子或卤素原子。

公开(公告)号：US20110091791A1

公开(公告)日：2011-04-21

申请号：US12976446

申请日：2010-12-22

申请人： Nobuyuki KASAHARA ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

发明人： Nobuyuki KASAHARA ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

IPC分类号： H01M8/10

CPC分类号： C08J5/2243 ,  C08J2327/12 ,  H01B1/122 ,  H01M4/8668 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56

摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

公开(公告)号：US07012164B2

公开(公告)日：2006-03-14

申请号：US10895063

申请日：2004-07-21

申请人： Kazuhiko Yamada ,  Nobuyuki Kasahara ,  Yoshinori Toyota ,  Chitoshi Suzuki ,  Shigeru Ikai ,  Hiroshi Hatano

发明人： Kazuhiko Yamada ,  Nobuyuki Kasahara ,  Yoshinori Toyota ,  Chitoshi Suzuki ,  Shigeru Ikai ,  Hiroshi Hatano

IPC分类号： C08G65/28

CPC分类号： C08G65/2696 ,  C08G65/2663

摘要： A method for precisely producing a polyether having a relatively high molecular weight by means of a double metal cyanide complex catalyst is provided. A method for continuously producing a polyether, which comprises ring opening addition polymerization of an alkylene oxide in the presence of a double metal cyanide complex catalyst, wherein substantially no vapor phase part is present in a reactor.

摘要翻译： 提供了一种通过双金属氰化物配合物催化剂精确生产具有较高分子量的聚醚的方法。 一种连续生产聚醚的方法，其包括在双金属氰化物配位催化剂存在下环氧烷的开环加成聚合反应，其中在反应器中基本上不存在气相部分。

公开(公告)号：US07902311B2

公开(公告)日：2011-03-08

申请号：US12329119

申请日：2008-12-05

申请人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

发明人： Nobuyuki Kasahara ,  Atsushi Watakabe ,  Tetsuji Shimohira ,  Hisao Kawazoe ,  Ichiro Terada

IPC分类号： C08F16/24

CPC分类号： C08J5/2243 ,  C08J2327/12 ,  H01B1/122 ,  H01M4/8668 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56

摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。