Dry high flux semipermeable membranes
    2.
    发明授权
    Dry high flux semipermeable membranes 失效
    干燥高通量半透膜

    公开(公告)号:US4983291A

    公开(公告)日:1991-01-08

    申请号:US450637

    申请日:1989-12-14

    IPC分类号: B01D67/00 B01D69/12

    CPC分类号: B01D67/0088 B01D69/125

    摘要: High flux semipermeable membranes which comprises the polymerized reaction product within and/or on a porous support backing material may be prepared by contacting the porous support such as a polysulfone with an aqueous solution of a polyamine which may, if so desired, contain a polar aprotic solvent not reactive with the amines, a polyhydric compound and an acid acceptor. The surface of the coated support is freed of excess solution and thereafter contacted with an organic solution of a polyacyl halide for a period of time sufficient to form a polymerized reaction product within and/or on the support material. The resulting composite is then treated with a hydroxy polycarboxylic acid, polyaminoalkylene polycarboxylic acid, suffonic acid, amine salts of acids, amino acid, amino acid salt, polymeric acid and inorganic acid, before drying of the membrane. This will enable the membrane to be stored in a dry manner prior to use thereof in a separation process. The resultant membrane composite may be used in separation processes such as desalination of brackish or sea water or the softening of domestic hard water.

    摘要翻译: 在多孔载体背衬材料内和/或多孔载体背衬材料上包含聚合的反应产物的高通量半透膜可以通过使诸如聚砜的多孔载体与多胺的水溶液接触来制备,如果需要,其可以含有极性非质子 不与胺反应的溶剂,多羟基化合物和酸受体。 涂覆的载体的表面没有过量的溶液,然后与多酰基卤的有机溶液接触足以在载体材料内和/或载体材料上形成聚合反应产物的时间。 然后在干燥膜之前,用羟基多元羧酸,聚氨基亚烷基多元羧酸,己酸,酸的胺盐,氨基酸,氨基酸盐,聚合酸和无机酸处理得到的复合物。 这将使膜能够在分离过程中使用之前以干燥方式储存。 所得到的膜复合物可以用于分离过程,例如咸水或海水的淡化或家庭硬水的软化。

    Aminoplast curable coating compositions containing sulfonic acid esters
as latent acid catalysts
    6.
    发明授权
    Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
    含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物

    公开(公告)号:US4477618A

    公开(公告)日:1984-10-16

    申请号:US427402

    申请日:1982-09-29

    IPC分类号: C08F8/36 C08K5/42 C09D161/20

    摘要: A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.

    摘要翻译: 能够进行酸催化交联的高固体,有机溶剂型可喷涂涂料组合物由含活性氢的树脂,在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成,以及 催化量的磺酸的非离子酯。 磺酸酯由以下结构式表示:其中:Z是选自氨基和有机基团的基团,所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1,R 2,R 3,R 4,R 5独立地为氢或有机基团。 这些基团可以特别描述如下:R 1是氢,烷氧羰基,C 3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢,烷氧羰基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R3是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R4是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基,R5是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基。

    High flux semipermeable membranes
    8.
    发明授权
    High flux semipermeable membranes 失效
    高通量半透膜

    公开(公告)号:US4950404A

    公开(公告)日:1990-08-21

    申请号:US400440

    申请日:1989-08-30

    申请人: Michael M. Chau

    发明人: Michael M. Chau

    CPC分类号: B01D69/125

    摘要: High flux semipermeable membranes which comprise a polymerized reaction product within and/or on a porous support may be prepared by contacting the porous support such as a polysulfone sheet with an aqueous solution of an polyamine, said aqueous solution containing a polar aprotic solvent not reactive with amines and optionally an acid acceptor. The surface of the coated support is dried to the touch and then contacted with an organic solution of an polycarboxylic acid halide for a period of time sufficient to form a polymerized reaction product within and/or on the surface of the support material. The resulting composite may be post treated by washing with an alkaline compound. The resultant membrane composite may be used in separation processes such as the desalination of brackish or seawater, or the softening of domestic hard water.

    摘要翻译: 在多孔载体内和/或多孔载体上包含聚合的反应产物的高通量半透膜可以通过使诸如聚砜片的多孔载体与多胺的水溶液接触来制备,所述水溶液含有极性非质子溶剂不与 胺和任选的酸受体。 将涂覆的载体的表面干燥至接触,然后与多元羧酸卤化物的有机溶液接触足以在载体材料的表面内和/或表面上形成聚合的反应产物的时间。 所得复合材料可以用碱性化合物洗涤后处理。 所得的膜复合材料可用于分离过程,例如咸淡化或海水淡化,或软化家用硬水。

    Modified rosin soaps for acrylic emulsions
    9.
    发明授权
    Modified rosin soaps for acrylic emulsions 失效
    用于丙烯酸乳液的改性松香皂

    公开(公告)号:US4812508A

    公开(公告)日:1989-03-14

    申请号:US764029

    申请日:1985-08-09

    CPC分类号: C09F1/04 C08F20/12 C09D11/107

    摘要: This invention discloses a modified rosin soap which is an ammonia-neutralized esterification product of a Diels-Alder adduct of a monomeric rosin and an alpha, beta-unsaturated carboxylic compound. The use of the modified rosin as an emulsifier and/or a stabilizer in the preparation of an acrylic latex and the use of the acrylic latex in ink formulations are also disclosed.

    摘要翻译: 本发明公开了一种改性松香皂,其是单体松香的Diels-Alder加合物和α,β-不饱和羧酸化合物的氨中和的酯化产物。 还公开了在制备丙烯酸胶乳中使用改性松香作为乳化剂和/或稳定剂以及在油墨配方中使用丙烯酸胶乳。

    Polyurea-polyurethane acrylate dispersions
    10.
    发明授权
    Polyurea-polyurethane acrylate dispersions 失效
    聚脲 - 聚氨酯丙烯酸酯分散体

    公开(公告)号:US4721751A

    公开(公告)日:1988-01-26

    申请号:US30309

    申请日:1987-03-26

    摘要: A polymerizable ethylenically unsaturated urea urethane polymer dispersed in a polymerizable ethylenically unsaturated compound is prepared by a process which comprises reacting a polyisocyanate, at least a portion of which is a diisocyanate, with a polyfunctional amine containing primary and/or secondary amino groups in the presence of:(a) a polyol, at least a portion of which is a polymeric polyol containing ethylenic unsaturation and having a carbon to oxygen ratio of at least 4/1;(b) a diluent which is an ethylenically unsaturated compound free of active hydrogens; and(c) an active hydrogen containing polymerizable ethylenically unsaturated compound; under conditions sufficient to form a polymerizable ethylenically unsaturated urea urethane polymer dispersed in a polymerizable ethylenically unsaturated compound.The aforedescribed urea urethane polymer dispersions are particularly useful in formulating curable compositions suitable for use as adhesives and sealants.