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公开(公告)号：US20130274429A1
公开(公告)日：2013-10-17
申请号：US13994216
申请日：2012-01-12
CPC分类号： C08F4/76 , C08F4/52 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2420/02 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F4/7006 , C08F210/14
摘要： Activating supports may be suitably prepared by the following procedure (a) providing a porous mineral oxide support material, (b) treating the support with a phosphorus-containing compound, (c) treating the support from step (b) with an organometallic compound, (d) heating the functionalized support from step (c) under an inert gas and then under an atmosphere comprising oxygen, (e) fluorinating the support with a fluorinating agent, and (f) recovering an activating support. The activating supports are suitable used in combination with single site catalysts for the polymerization of olefins. The supports are most preferably used in combination with metallocene complexes. The preparative route for the activating supports provides for supported polymerization catalyst systems having excellent activities.
摘要翻译： 活化载体可以通过以下步骤（a）适当地制备：（a）提供多孔无机氧化物载体材料，（b）用含磷化合物处理载体，（c）用有机金属化合物处理步骤（b）的载体， （d）在惰性气体下，然后在包含氧的气氛下加热步骤（c）的官能化载体，（e）用氟化剂氟化载体，和（f）回收活化载体。 活化载体适合与用于烯烃聚合的单中心催化剂组合使用。 载体最优选与茂金属络合物组合使用。 用于活化载体的制备路线提供了具有优异活性的负载型聚合催化剂体系。
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公开(公告)号：US20090233091A1
公开(公告)日：2009-09-17
申请号：US12225098
申请日：2007-03-06
申请人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
发明人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
IPC分类号： C08F210/02 , C08F210/08 , C08F210/14 , C08F4/42 , B32B5/00 , B29C49/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08J5/18 , C08J2323/08 , Y10T428/268 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/26
摘要： A method for the preparation of a polymer film containing 300-600 gels/m2 of size in the range 100-2000 μm as measured by an optical control system (OCS) as hereinbefore described, said film being derived from an ethylene-α-olefin copolymer is characterised in that said copolymer is prepared in a particle forming polymerisation process in the presence of a single site catalyst system. The preferred single site catalyst system comprises a metallocene and the preferred polymerisation process is a gas phase process. The invention is particularly directed to blown films.
摘要翻译： 制备聚合物膜的方法，该聚合物膜含有300-600凝胶/ m 2的尺寸，其范围为100-2000μm，如通过如上所述的光学控制系统（OCS）所测量的，所述膜衍生自乙烯-α-烯烃 共聚物的特征在于所述共聚物是在单点催化剂体系的存在下在颗粒形成聚合方法中制备的。 优选的单中心催化剂体系包含茂金属，优选的聚合方法是气相方法。 本发明特别涉及吹塑薄膜。
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公开(公告)号：US08338551B2
公开(公告)日：2012-12-25
申请号：US12225098
申请日：2007-03-06
申请人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
发明人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08J5/18 , C08J2323/08 , Y10T428/268 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/26
摘要： Method for the preparation of a blown film containing 300-600 gels/m2 of size in the range 100-2000 μm as measured by an optical control system, in which the film is derived by extrusion from an ethylene-α-olefin copolymer. The method is carried out by preparing the copolymer in a particle forming polymerization process in the presence of a single site catalyst system containing a single site catalyst, a cocatalyst, and a support material.
摘要翻译： 制备通过光学控制系统测量的100-2000μm范围内的300-600凝胶/ m2尺寸的吹塑薄膜的方法，其中通过乙烯-α-烯烃共聚物的挤出得到薄膜。 该方法通过在含有单中心催化剂，助催化剂和载体材料的单中心催化剂体系的存在下，在颗粒形成聚合方法中制备共聚物来进行。
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公开(公告)号：US20110009576A1
公开(公告)日：2011-01-13
申请号：US12736148
申请日：2009-02-24
CPC分类号： C08F210/16 , C08F4/6565 , C08F4/6495 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18
摘要： The present invention relates to a polymerisation process and in particular to a process for the copolymerisation of ethylene and an α-olefin comonomer having 7 to 10 carbon atoms in a fluidised bed gas phase reactor in the presence of a multi-site Ziegler-Natta polymerisation catalyst characterised in that (i) said process is operated in condensed mode, (ii) the amount of said α-olefin is maintained below that at which substantial condensation in the reactor occurs and (iii) at least one of the following apply:a) the catalyst has an uptake rate of 1-octene of at least 700;b) the polymerisation is performed in the presence of an activity promoter.
摘要翻译： 本发明涉及一种聚合方法，特别涉及一种在多位点齐格勒 - 纳塔聚合存在下，在流化床气相反应器中共聚乙烯和具有7至10个碳原子的α-烯烃共聚单体的方法 催化剂的特征在于：（i）所述方法以冷凝模式运行，（ii）所述α-烯烃的量保持低于反应器发生基本冷凝的量，以及（iii）以下至少一种适用： ）催化剂具有至少700的1-辛烯的吸收速率; b）聚合在活性促进剂存在下进行。
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公开(公告)号：US09012359B2
公开(公告)日：2015-04-21
申请号：US13994216
申请日：2012-01-12
IPC分类号： C08F4/02 , C08F4/6592 , C08F110/02 , C08F210/16 , C08F4/76 , C08F10/00 , C08F4/52
CPC分类号： C08F4/76 , C08F4/52 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2420/02 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F4/7006 , C08F210/14
摘要： Activating supports may be suitably prepared by the following procedure (a) providing a porous mineral oxide support material, (b) treating the support with a phosphorus-containing compound, (c) treating the support from step (b) with an organometallic compound, (d) heating the functionalized support from step (c) under an inert gas and then under an atmosphere comprising oxygen, (e) fluorinating the support with a fluorinating agent, and (f) recovering an activating support. The activating supports are suitable used in combination with single site catalysts for the polymerization of olefins. The supports are most preferably used in combination with metallocene complexes. The preparative route for the activating supports provides for supported polymerization catalyst systems having excellent activities.
摘要翻译： 活化载体可以通过以下步骤（a）适当地制备：（a）提供多孔无机氧化物载体材料，（b）用含磷化合物处理载体，（c）用有机金属化合物处理步骤（b）的载体， （d）在惰性气体下，然后在包含氧的气氛下加热步骤（c）的官能化载体，（e）用氟化剂氟化载体，和（f）回收活化载体。 活化载体适合与用于烯烃聚合的单中心催化剂组合使用。 载体最优选与茂金属络合物组合使用。 用于活化载体的制备路线提供了具有优异活性的负载型聚合催化剂体系。
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