PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES
    2.
    发明申请
    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES 有权
    生产氯化碱的方法

    公开(公告)号:US20150045592A1

    公开(公告)日:2015-02-12

    申请号:US14358079

    申请日:2012-11-13

    IPC分类号: C07C17/013

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise reacting one or more mono- and/or dichloroalkanes to form tri-, tetra- and/or pentachloroalkanes, with high regioselectivity. In those embodiments wherein a dichloroalkane is desirably utilized, it may advantageously be a vicinal dichloroalkane. Further, only one catalyst is utilized. The present processes make use of sulfuryl chloride as a chlorinating agent, rather than a gaseous chlorinating agent such as chlorine gas. Finally, the process uses lower intensity process conditions than at least some conventional processes, and thus, operating costs are saved.

    摘要翻译: 提供了生产氯代烷烃的方法。 本方法包括使一种或多种单 - 和/或二氯烷烃反应形成具有高区域选择性的三,四和/或五氯代烷烃。 在其中希望使用二氯烷烃的那些实施方案中,它可以有利地是连续的二氯烷烃。 此外,仅使用一种催化剂。 本方法使用磺酰氯作为氯化剂,而不是气态氯化剂如氯气。 最后,该方法使用比至少一些常规方法更低强度的工艺条件,因此节省了操作成本。

    Process for the production of chlorinated alkanes
    3.
    发明授权
    Process for the production of chlorinated alkanes 有权
    氯化烷烃生产工艺

    公开(公告)号:US09067855B2

    公开(公告)日:2015-06-30

    申请号:US14358079

    申请日:2012-11-13

    IPC分类号: C07C17/013 C07C17/10

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise reacting one or more mono- and/or dichloroalkanes to form tri-, tetra- and/or pentachloroalkanes, with high regioselectivity. In those embodiments wherein a dichloroalkane is desirably utilized, it may advantageously be a vicinal dichloroalkane. Further, only one catalyst is utilized. The present processes make use of sulfuryl chloride as a chlorinating agent, rather than a gaseous chlorinating agent such as chlorine gas. Finally, the process uses lower intensity process conditions than at least some conventional processes, and thus, operating costs are saved.

    摘要翻译: 提供了生产氯代烷烃的方法。 本发明方法包括使一种或多种单 - 和/或二氯烷烃反应形成具有高区域选择性的三,四和/或五氯代烷烃。 在其中希望使用二氯烷烃的那些实施方案中,它可以有利地是连续的二氯烷烃。 此外,仅使用一种催化剂。 本方法使用磺酰氯作为氯化剂,而不是气态氯化剂如氯气。 最后,该方法使用比至少一些常规方法更低强度的工艺条件,因此节省了操作成本。

    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES
    4.
    发明申请
    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES 有权
    生产氯化碱的方法

    公开(公告)号:US20140323775A1

    公开(公告)日:2014-10-30

    申请号:US14362249

    申请日:2012-11-30

    IPC分类号: C07C17/013

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise catalyzing the addition of at least two chlorine atoms to an alkane and/or alkene with a catalyst system comprising one or more nonmetallic iodides and/or lower than conventional levels of elemental iodine and at least one Lewis acid. The present processes make use of sulfuryl chloride, or chlorine gas, as a chlorinating agent.

    摘要翻译: 提供了生产氯代烷烃的方法。 本发明的方法包括催化使用包含一种或多种非金属碘化物和/或低于常规水平的元素碘和至少一种路易斯酸的催化剂体系向烷烃和/或烯烃中加入至少两个氯原子。 本方法使用磺酰氯或氯气作为氯化剂。

    Process for the production of chlorinated alkanes
    5.
    发明授权
    Process for the production of chlorinated alkanes 有权
    氯化烷烃生产工艺

    公开(公告)号:US09199899B2

    公开(公告)日:2015-12-01

    申请号:US14362249

    申请日:2012-11-30

    IPC分类号: C07C17/013 C07C17/10

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise catalyzing the addition of at least two chlorine atoms to an alkane and/or alkene with a catalyst system comprising one or more nonmetallic iodides and/or lower than conventional levels of elemental iodine and at least one Lewis acid. The present processes make use of sulfuryl chloride, or chlorine gas, as a chlorinating agent.

    摘要翻译: 提供了生产氯代烷烃的方法。 本发明的方法包括催化使用包含一种或多种非金属碘化物和/或低于常规水平的元素碘和至少一种路易斯酸的催化剂体系向烷烃和/或烯烃中加入至少两个氯原子。 本方法使用磺酰氯或氯气作为氯化剂。

    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES
    6.
    发明申请
    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES 有权
    生产氯化碱的方法

    公开(公告)号:US20140323776A1

    公开(公告)日:2014-10-30

    申请号:US14362289

    申请日:2012-11-30

    IPC分类号: C07C17/06

    CPC分类号: C07C17/06 C07C17/10 C07C19/01

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise catalyzing the chlorination of a feedstream comprising one or more alkanes and/or alkenes with a catalyst system comprising one or more inorganic iodine salts and/or lower than conventional levels of elemental iodine and at least one Lewis acid. The processes are conducted in a nonaqueous media, and so, the one or more inorganic iodine salts are recoverable and/or reusable, in whole or in part.

    摘要翻译: 提供了生产氯代烷烃的方法。 本发明的方法包括用包含一种或多种无机碘盐和/或低于常规水平的元素碘和至少一种路易斯酸的催化剂体系催化包含一种或多种烷烃和/或烯烃的进料流的氯化。 所述方法在非水介质中进行,因此,一种或多种无机碘盐可全部或部分回收和/或可再利用。