公开(公告)号：US07882754B2

公开(公告)日：2011-02-08

申请号：US11907905

申请日：2007-10-18

Applicant: Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

Inventor： Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

IPC: G01N1/22

CPC classification number: A61B5/097 ,  G01N1/2205 ,  G01N2001/2244

Abstract: A gas component collector comprises a filter assembly 3 comprising an adsorbent and an adsorbent holding plate having a first face, a second face and a plurality of holes that are bored through from the first face to the second face and are filled with the adsorbent adsorbing at least one gas component to be analyzed, the filter assembly satisfying (AL−V)2/L3≧0.003 mm3 and V/AL≧0.3, where V is a total volume of the adsorbent, A is a sum of an opening areas of the holes, and L is an average length of the holes, and a holding container 2 housing the filter assembly 3. On at least one of the holding container 2 a first opening portion for introducing gas and a second opening portion for allowing the introduced gas to be discharged are formed.

Abstract translation: 气体成分收集器包括一个过滤器组件3，它包括一个吸附剂和一个吸附剂保持板，该吸附剂保持板具有第一面，第二面和多个从第一面到第二面穿透的孔，并填充吸附在 至少一个要分析的气体组分，过滤器组件满足（AL-V）2 /L3≥0.003mm3，V /AL≥0.3，其中V是吸附剂的总体积，A是 并且L是孔的平均长度，以及容纳过滤器组件3的保持容器2.在保持容器2中的至少一个上用于引入气体的第一开口部分和用于允许引入气体的第二开口部分 被排出形成。

公开(公告)号：US20080128615A1

公开(公告)日：2008-06-05

申请号：US11987085

申请日：2007-11-27

Applicant: Masuyoshi Yamada ,  Masako Ishimaru

Inventor： Masuyoshi Yamada ,  Masako Ishimaru

IPC: H01J49/04

CPC classification number: H01J49/0422

Abstract: An analyzer carrying out analysis with a high degree of qualitative accuracy by separating impurities which hinder the analysis while analyzing in real time. An introducing tube is branched with one branched tube directly leading to an ion source for real time analysis. The other branched tube leads to the ion source so as to introduce the sample gas into the ion source at a later time. When a result of the real time analysis shows that a spectrum pattern on a MS spectrum is changed and an increase in the concentration of an impurity is observed, the introducing path for the sample gas is changed so that the sample gas is introduced into the ion source after the impurity is separated at the separation part.

Abstract translation: 分析仪通过分析实时分析分析杂质，以高度的定性精度进行分析。 引入管被分支，一个分支管直接通向离子源进行实时分析。 另一个分支管通向离子源，以便稍后将样品气体引入离子源。 当实时分析的结果表明MS谱上的光谱图变化并且观察到杂质浓度增加时，改变样品气体的引入路径，使样品气体被引入离子 杂质在分离部分分离出来。

公开(公告)号：US07375316B2

公开(公告)日：2008-05-20

申请号：US11712922

申请日：2007-03-02

Applicant: Masuyoshi Yamada ,  Masao Suga ,  Izumi Waki

Inventor： Masuyoshi Yamada ,  Masao Suga ,  Izumi Waki

IPC: H01J49/00 ,  H01J3/07 ,  B01D59/44

CPC classification number: H01J49/0422 ,  H01J49/107

Abstract: A mass spectrometer capable of measuring under switching two ion sources at different pressure levels in which a sample gas separated by GC column is branched, and separately introduced to a first ion source (for example, APCI ion source) and a second ion source (for example, EI ion source) at a pressure level lower than that of the first ion source respectively. Preferably, the flow rate of the sample gas introduced to the APCI ion source is made more than the flow rate of the sample gas introduced to the EI ion source, so that the pressure for each of the ion sources can be maintained and analysis can be conducted by each ionization at a good balance in view of the sensitivity.

Abstract translation: 一种能够在不同压力水平下切换两个离子源的质谱仪，其中由GC柱分离的样品气体被分支，并分别引入第一离子源（例如APCI离子源）和第二离子源（用于 例如，EI离子源），其压力水平分别低于第一离子源的压力水平。 优选地，引入到APCI离子源的样品气体的流量比引入到EI离子源的样品气体的流量更多，从而可以保持每个离子源的压力并且可以分析 鉴于敏感性，通过各种电离进行良好的平衡。

公开(公告)号：US20080092629A1

公开(公告)日：2008-04-24

申请号：US11907905

申请日：2007-10-18

Applicant: Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

Inventor： Masao Suga ,  Masuyoshi Yamada ,  Izumi Waki

IPC: G01N1/22

CPC classification number: A61B5/097 ,  G01N1/2205 ,  G01N2001/2244

Abstract: A gas component collector comprises a filter assembly 3 comprising an adsorbent and an adsorbent holding plate having a first face, a second face and a plurality of holes that are bored through from the first face to the second face and are filled with the adsorbent adsorbing at least one gas component to be analyzed, the filter assembly satisfying (AL−V)2/L3≧0.003 mm3 and V/AL≧0.3, where V is a total volume of the adsorbent, A is a sum of an opening areas of the holes, and L is an average length of the holes, and a holding container 2 housing the filter assembly 3. On at least one of the holding container 2 a first opening portion for introducing gas and a second opening portion for allowing the introduced gas to be discharged are formed.

Abstract translation: 气体成分收集器包括一个过滤器组件3，它包括一个吸附剂和一个吸附剂保持板，该吸附剂保持板具有第一面，第二面和多个从第一面到第二面穿透的孔，并填充吸附在 要分析的至少一个气体成分，满足（AL-V）2 / L 3 / SUP 3 = 0.003mm 3和V / AL> = 0.3，其中V是吸附剂的总体积，A是孔的开口面积的总和，L是孔的平均长度，以及容纳过滤器组件3的保持容器2。 在保持容器2的至少一个上形成用于引入气体的第一开口部分和用于允许引入气体排出的第二开口部分。

公开(公告)号：US07064320B2

公开(公告)日：2006-06-20

申请号：US11071345

申请日：2005-03-04

Applicant: Masuyoshi Yamada ,  Izumi Waki ,  Hideo Kasima

Inventor： Masuyoshi Yamada ,  Izumi Waki ,  Hideo Kasima

IPC: H01J49/26 ,  G01N27/62

CPC classification number: H01J49/0422 ,  G01N30/7213 ,  H01J49/145 ,  H01J49/168

Abstract: A mass spectrometer has an atmospheric pressure chemical ionization source that includes a first ionization portion including a needle electrode, for generating a primary ion by discharge of the needle electrode a primary ion introduction aperture, and a second ionization portion including an introduction aperture, for generating a sample ion by the reaction between the primary ion and the sample gas introduced from an end of a column of gas chromatography, a sample ion movement aperture; and a mass analysis portion; wherein the end is arranged at a position satisfying the relation r≦2R where R is a radius of an inner diameter of the aperture and r is a distance between an axis connecting the center of the aperture and the center of the aperture, and the end.

Abstract translation: 质谱仪具有大气压化学电离源，其包括第一离子化部分，其包括针状电极，用于通过针状电极排出初级离子引入孔而产生初级离子;以及第二离子化部分，其包括引入孔，用于产生 通过从气相色谱柱的端部引入的初级离子和样品气体之间的反应的样品离子，样品离子运动孔; 和质量分析部分; 其中端部被布置在满足关系r <= 2R的位置处，其中R是孔的内径的半径，r是连接孔的中心的轴线与孔的中心之间的距离， 结束。

公开(公告)号：US06295860B1

公开(公告)日：2001-10-02

申请号：US09348565

申请日：1999-07-07

Applicant: Minoru Sakairi ,  Masao Suga ,  Yuichiro Hashimoto ,  Masuyoshi Yamada

Inventor： Minoru Sakairi ,  Masao Suga ,  Yuichiro Hashimoto ,  Masuyoshi Yamada

IPC: G01N100

CPC classification number: H01J49/0422 ,  G01N1/22 ,  G01N2001/024

Abstract: An explosive detection system in which vapor leaking from luggage is sampled by a sampling probe, negative corona discharge is used to ionize the vapor, and a mass spectrometer is used to detect the ionized vapor, thereby judging whether an explosive is present or not.

Abstract translation: 一种爆炸检测系统，其中通过采样探针对从行李箱泄漏的蒸气进行采样，使用负电晕放电来电离蒸气，并使用质谱仪检测电离蒸汽，从而判断是否存在爆炸物。

公开(公告)号：US08368013B2

公开(公告)日：2013-02-05

申请号：US13084930

申请日：2011-04-12

Applicant: Masako Ishimaru ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Masuyuki Sugiyama ,  Hidetoshi Morokuma

Inventor： Masako Ishimaru ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Masuyuki Sugiyama ,  Hidetoshi Morokuma

IPC: B01D59/44 ,  H01J49/00

CPC classification number: H01J49/145

Abstract: An analyzer performs dielectric barrier discharge and ionization of a sample by a reaction between the sample and excited molecules or ions generated by the dielectric barrier discharge at a pressure lower than an atmospheric pressure.

Abstract translation: 分析仪通过在低于大气压的压力下通过介电阻挡放电产生的样品和激发的分子或离子之间的反应来进行介电阻挡放电和样品的离子化。

公开(公告)号：US20120326022A1

公开(公告)日：2012-12-27

申请号：US13527627

申请日：2012-06-20

Applicant: Shun KUMANO ,  Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Hidetoshi Morokuma ,  Shuhei Hashiba

Inventor： Shun KUMANO ,  Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hideki Hasegawa ,  Masuyoshi Yamada ,  Hidetoshi Morokuma ,  Shuhei Hashiba

IPC: H01J49/04

CPC classification number: H01J49/0409 ,  H01J49/0495

Abstract: A mass spectrometer including a sample attaching member of attaching a sample, an ionizing chamber including an introductory port of the sample attaching member and an ionization source of generating a sample ion, a vacuumed chamber having a mass analyzer of analyzing the sample ion, and an opening/closing mechanism provided between the ionizing chamber and the vacuumed chamber, in which the opening/closing mechanism is controlled from a closed state to an open state after introducing the sample attaching member into the ionizing chamber to thereby enable to perform ionization with inconsiderable fragmentation at a high sensitivity with a high throughput

Abstract translation: 一种质谱仪，包括附着样品的样品附着构件，包括样品附着构件的入口的电离室和产生样品离子的离子源，具有分析样品离子的质量分析器的真空室，以及 设置在离子化室和真空室之间的开/关机构，其中将样品附着构件引入电离室之后，将开/关机构从关闭状态控制到打开状态，从而能够以不可分割的碎片进行电离 灵敏度高，吞吐量高

公开(公告)号：US20120112061A1

公开(公告)日：2012-05-10

申请号：US13289633

申请日：2011-11-04

Applicant: Hidetoshi MOROKUMA ,  Yuichiro HASHIMOTO ,  Masuyuki SUGIYAMA ,  Masuyoshi YAMADA ,  Hideki HASEGAWA

Inventor： Hidetoshi MOROKUMA ,  Yuichiro HASHIMOTO ,  Masuyuki SUGIYAMA ,  Masuyoshi YAMADA ,  Hideki HASEGAWA

IPC: H01J49/04

CPC classification number: H01J49/0013 ,  H01J49/0031 ,  H01J49/0422 ,  H01J49/0495 ,  H01J49/10 ,  H01J49/105 ,  H01J49/24 ,  H01J49/26

Abstract: A mass spectrometer of reduced size and weight is provided which is capable to conduct highly accurate mass spectroscopy. The mass spectrometer includes an ion source adapted to ionize gas flowing in from outside in order to ionize a measurement sample and a mass spectroscopy section for separating the ionized measurement sample. The ion source has its interior reduced in pressure by differential pumping from the mass spectroscopy section and ionizes the gas when the interior pressure rises as it inhales the gas, and the mass spectroscopy section separates the ionized measurement sample when its interior pressure falls after inhale of the gas. The mass spectrometer may further include a restriction device for suppressing a flow rate of the gas the ion source inhales and an open/close device for opening and closing a flow of the gas the ion source inhales.

Abstract translation: 提供了减小尺寸和重量的质谱仪，其能够进行高精度的质谱。 质谱仪包括离子源，其适于使从外部流入的气体电离，以便电离测量样品和用于分离离子化测量样品的质谱部分。 离子源的内部通过从质谱分析部分的差分泵送而在内部减压，并且当吸入气体时内部压力升高时电离气体，质谱仪分离离子化测量样品，当其内部压力在吸入后 气体。 质谱仪还可以包括用于抑制离子源吸入的气体的流量的限制装置和用于打开和关闭离子源吸入的气体流的打开/关闭装置。

公开(公告)号：US20120112059A1

公开(公告)日：2012-05-10

申请号：US13383371

申请日：2010-07-09

Applicant: Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

Inventor： Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

IPC: H01J49/26

CPC classification number: H01J49/004

Abstract: An object is to measure both cations and anions with high duty cycle. In a mass spectrometer comprising an ion source (1), an ion guide part (31), and an ion trap (32), while ions are being mass-selectively ejected from the ion trap, ions having a polarity reverse to that of the ions trapped in the ion trap are introduced into the ion guide part.

Abstract translation: 一个目标是测量阳离子和阴离子高占空比。 在离子源（1），离子引导部（31）和离子阱（32）的质谱仪中，离子从离子阱中质量选择性地喷出时，具有与 捕获在离子阱中的离子被引入离子引导部。