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    Cyclic hydrocarbon derivative and liquid crystal composition containing the same
    1.
    发明授权
    Cyclic hydrocarbon derivative and liquid crystal composition containing the same 失效
    环状烃衍生物和含有它们的液晶组合物

    公开(公告)号：US5536443A

    公开(公告)日：1996-07-16

    申请号：US429485

    申请日：1995-04-25

    申请人： Haruyoshi Takatsu ,  Sadao Takehara ,  Kiyohumi Takeuchi ,  Masashi Osawa ,  Shinji Ogawa ,  Norie Ishida

    发明人： Haruyoshi Takatsu ,  Sadao Takehara ,  Kiyohumi Takeuchi ,  Masashi Osawa ,  Shinji Ogawa ,  Norie Ishida

    IPC分类号： C07B59/00 ,  C07C69/773 ,  C07C255/50 ,  C07C255/55 ,  C09K19/30 ,  C09K19/40 ,  C09K19/42 ,  G02F1/13

    CPC分类号： C09K19/402 ,  C07B59/001 ,  C07C255/50 ,  C07C255/55 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/3059 ,  C07C2101/14 ,  C09K2019/0444

    摘要： A liquid crystal display comprising a compound of the formula ##STR1## wherein each of Y.sup.1 and Y.sup.2 is independently F, Cl, CN, OCN, SCN, OCF.sub.3, OCF.sub.2 H, OCF.sub.2 CF.sub.3, CF.sub.3, R, --OR, --COOR or --OCOR, wherein R is alkyl, alkenyl or alkoxyalkyl, provided that at least one of Y.sup.1 and Y.sup.2 is R, --OR, --COOR or --OCOR; each of Z, Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 is independently a single bond. CH.sub.2 CH.sub.2 --, --CH.dbd.CH--, --C.dbd.C--, --COO--, --OCO--, --CH.sub.2 O--, OCH.sub.2 --, --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.3 --O-- or --O--(CH.sub.2).sub.3 --: ring A is a group of formula (II): ##STR2## wherein each of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, X.sup.9, and X.sup.10 is independently H or D, provided that at least one of them is D; each of rings K, L, J, M and N is independently trans-1,4-cyclohexylene, 1,4-cyclohexenylene, substituted trans-1,4-cyclohexylene, 1,4-phenylene, substituted 1,4-phenylene, 1,3-dioxane-2,6-diyl, pyrimidine-2,5-diyl, pyridine-2,5-diyl, pyrazine-2,5-diyl or a group of formula (III): ##STR3## wherein each of X.sup.11, X.sup.12, X.sup.13, X.sup.14, X.sup.15, X.sup.16, X.sup.17, X.sup.18, X.sup.19, and X.sup.20 is independently H or D, provided that at least one of them is D; in which the ring of formula (III) may be the same as or different from ring A; and k, l, m, and n each independently is 0 or 1, provided that the sum of k, l, m, and n is 0, 1 or 2. The compound is useful as an electro-optic liquid crystal display material.

    摘要翻译： 其中Y1和Y2各自独立地为F，Cl，CN，OCN，SCN，OCF3，OCF2H，OCF2CF3，CF3，R，-OR， -COOR或-OCOR，其中R是烷基，烯基或烷氧基烷基，条件是Y1和Y2中的至少一个是R，-OR，-COOR或-OCOR; Z，Z1，Z2，Z3和Z4各自独立地为单键。 CH 2 CH 2 - ， - CH = CH - ， - C = C - ， - COO-， - OCO-， - CH 2 O - ，OCH 2 - ， - （CH 2）4 - ， - （CH 2）3 -O-或-O- CH 2）3 - ：环A是式（II）的基团：其中X1，X2，X3，X4，X5，X6，X7，X8，X9和X10各自独立地为H或D ，条件是其中至少有一个是D; 环K，L，J，M和N各自独立地为反式-1,4-亚环己基，1,4-亚环己烯基，取代的反式-1,4-亚环己基，1,4-亚苯基，取代的1,4-亚苯基， （III）所示的基团：式（III）的化合物：其中R 1，R 2，R 3，R 3， 其中X11，X12，X13，X14，X15，X16，X17，X18，X19和X20各自独立地为H或D，条件是它们中的至少一个为D; 其中式（III）的环可以与环A相同或不同; 并且k，l，m和n各自独立地为0或1，条件是k，l，m和n的和为0,1或2.该化合物可用作电光液晶显示材料。

    Cyclic hydrocarbon derivative and liquid crystal composition containing the same
    2.
    发明授权
    Cyclic hydrocarbon derivative and liquid crystal composition containing the same 失效
    环状烃衍生物和含有它们的液晶组合物

    公开(公告)号：US5474707A

    公开(公告)日：1995-12-12

    申请号：US278260

    申请日：1994-07-21

    申请人： Haruyoshi Takatsu ,  Sadao Takehara ,  Kiyohumi Takeuchi ,  Masashi Osawa ,  Shinji Ogawa ,  Norie Ishida

    发明人： Haruyoshi Takatsu ,  Sadao Takehara ,  Kiyohumi Takeuchi ,  Masashi Osawa ,  Shinji Ogawa ,  Norie Ishida

    IPC分类号： C07B59/00 ,  C07C69/773 ,  C07C255/50 ,  C07C255/55 ,  C09K19/30 ,  C09K19/40 ,  C09K19/42 ,  G02F1/13 ,  C07C19/08 ,  C09K19/12 ,  C09K19/34

    CPC分类号： C09K19/402 ,  C07B59/001 ,  C07C255/50 ,  C07C255/55 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/3059 ,  C07C2101/14 ,  C09K2019/0444

    摘要： A cyclic hydrocarbon derivative represented by formula (I): ##STR1## wherein each of Y.sup.1 and Y.sup.2 is independently F, Cl, CN, OCN, SCN, OCF.sub.3, OCF.sub.2 H, OCF.sub.2 CF.sub.3, CF.sub.3, R, --OR, --COOR or --OCOR, wherein R is alkyl, alkenyl or alkoxyalkyl, provided that at least one of Y.sup.1 and Y.sup.2 is R, --OR, --COOR or --OCOR; each of Z, Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 is independently a single bond, --CH.sub.2 CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, --COO--, --OCO--, --CH.sub.2 O--, OCH.sub.2 --, --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.3 --O-- or --O--(CH.sub.2).sub.3 --; ring A is group of formula (II): ##STR2## wherein each of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, X.sup.9, and X.sup.10 is independently H or D, provided that at least one of them is D; each of rings K, L, J, M and N is independently trans-1,4-cyclohexylene, 1,4-cyclohexenylene, substituted trans-1,4-cyclohexylene, 1,4-phenylene, substituted 1,4-phenylene, 1,3-dioxane-2,6-diyl, pyrimidine-2,5-diyl, pyridine-2,5-diyl, pyarazine-2,5-diyl or a group of formula (III): ##STR3## wherein each of X.sup.11, X.sup.12, X.sup.13, X.sup.14, X.sup.15, X.sup.16, X.sup.17, X.sup.18, X.sup.19, and X.sup.20 is independently H or D, provided that at least one of them is D; in which the ring of formula (III) may be the same as or different from ring A; and k, l, m, and n each independently is 0 or 1, provided that the sum of k, l, m, and n is 0, 1 or 2. The compound is useful as an electro-optic liquid crystal display material.

    摘要翻译： 由式（I）表示的环状烃衍生物：其中Y1和Y2各自独立地为F，Cl，CN，OCN，SCN，OCF3，OCF2H，OCF2CF3，CF3，R，-OR -COOR或-OCOR，其中R是烷基，烯基或烷氧基烷基，条件是Y1和Y2中的至少一个是R，-OR，-COOR或-OCOR; Z，Z 1，Z 2，Z 3和Z 4各自独立地为单键，-CH 2 CH 2 - ， - CH = CH - ， - C 3BOND C - ， - COO - ， - OCO-， - CH 2 O-，OCH 2 - CH2）4-， - （CH2）3-O-或-O-（CH2）3-; 环A是式（II）的基团：其中X 1，X 2，X 3，X 4，X 5，X 6，X 7，X 8，X 9和X 10各自独立地为H或D，条件是至少一个 他们是D 环K，L，J，M和N各自独立地为反式-1,4-亚环己基，1,4-亚环己烯基，取代的反式-1,4-亚环己基，1,4-亚苯基，取代的1,4-亚苯基， （III）的基团：式（III）的化合物：其中R 1，R 2，R 3，R 3， 其中X11，X12，X13，X14，X15，X16，X17，X18，X19和X20各自独立地为H或D，条件是它们中的至少一个为D; 其中式（III）的环可以与环A相同或不同; 并且k，l，m和n各自独立地为0或1，条件是k，l，m和n的和为0,1或2.该化合物可用作电光液晶显示材料。

    Compound having 2-fluorophenyloxymethane structure
    5.
    发明授权
    Compound having 2-fluorophenyloxymethane structure 有权
    具有2-氟苯氧基甲烷结构的化合物

    公开(公告)号：US08916718B2

    公开(公告)日：2014-12-23

    申请号：US14116709

    申请日：2012-05-22

    申请人： Kenta Tojo ,  Kiyofumi Takeuchi ,  Masashi Osawa ,  Masakazu Kaneoya ,  Tetsuo Kusumoto

    发明人： Kenta Tojo ,  Kiyofumi Takeuchi ,  Masashi Osawa ,  Masakazu Kaneoya ,  Tetsuo Kusumoto

    IPC分类号： C07D407/08 ,  C07D309/06 ,  C09K19/30 ,  C09K19/20 ,  C07C43/225

    CPC分类号： C07D309/06 ,  C07C43/225 ,  C09K19/20 ,  C09K19/3066 ,  C09K19/322 ,  C09K2019/3422 ,  G02F2001/13706

    摘要： The present invention relates to a compound having a 2-fluorophenyloxymethane structure and useful for organic electronic materials and medical and agricultural chemicals, particularly materials for liquid crystal display elements.A problem to be solved by the invention is to provide a compound having relatively large Δ∈, relatively high T→i, low viscosity (η), and high miscibility with other liquid crystal compounds, and also provide a liquid crystal composition containing the compound as a constituent component.The present invention provides a compound having a 2-fluorophenyloxymethane structure and also provides a liquid crystal composition containing the compound and a liquid crystal display device using the liquid crystal composition.

    摘要翻译： 本发明涉及具有2-氟苯氧基甲烷结构并可用于有机电子材料和医用农药的化合物，特别是涉及液晶显示元件的材料。 本发明要解决的问题是提供具有相对较大的Dgr∈，相对较高的T→i，低粘度（＆eegr）和与其它液晶化合物的高混溶性的化合物，并且还提供含有 该化合物作为组成成分。 本发明提供具有2-氟苯氧基甲烷结构的化合物，并且还提供含有该化合物的液晶组合物和使用该液晶组合物的液晶显示装置。

    COMPOUND HAVING 2-FLUOROPHENYLOXYMETHANE STRUCTURE
    6.
    发明申请
    COMPOUND HAVING 2-FLUOROPHENYLOXYMETHANE STRUCTURE 有权
    具有2-氟亚戊基甲基丙烯酸结构的化合物

    公开(公告)号：US20140275577A1

    公开(公告)日：2014-09-18

    申请号：US14116709

    申请日：2012-05-22

    申请人： Kenta Tojo ,  Kiyofumi Takeuchi ,  Masashi Osawa ,  Masakazu Kaneoya ,  Tetsuo Kusumoto

    发明人： Kenta Tojo ,  Kiyofumi Takeuchi ,  Masashi Osawa ,  Masakazu Kaneoya ,  Tetsuo Kusumoto

    IPC分类号： C07D309/06 ,  C09K19/20 ,  C09K19/30 ,  C07C43/225

    CPC分类号： C07D309/06 ,  C07C43/225 ,  C09K19/20 ,  C09K19/3066 ,  C09K19/322 ,  C09K2019/3422 ,  G02F2001/13706

    摘要： The present invention relates to a compound having a 2-fluorophenyloxymethane structure and useful for organic electronic materials and medical and agricultural chemicals, particularly materials for liquid crystal display elements.A problem to be solved by the invention is to provide a compound having relatively large Δ∈, relatively high T→i, low viscosity (η), and high miscibility with other liquid crystal compounds, and also provide a liquid crystal composition containing the compound as a constituent component.The present invention provides a compound having a 2-fluorophenyloxymethane structure and also provides a liquid crystal composition containing the compound and a liquid crystal display device using the liquid crystal composition.

    摘要翻译： 本发明涉及具有2-氟苯氧基甲烷结构并可用于有机电子材料和医用农药的化合物，特别是涉及液晶显示元件的材料。 本发明要解决的问题是提供具有相对较大的Dgr∈，相对较高的T→i，低粘度（＆eegr）和与其它液晶化合物的高混溶性的化合物，并且还提供含有 该化合物作为组成成分。 本发明提供具有2-氟苯氧基甲烷结构的化合物，并且还提供含有该化合物的液晶组合物和使用该液晶组合物的液晶显示装置。

    Naphthalene derivative and liquid crystal composition comprising the same
    8.
    发明授权
    Naphthalene derivative and liquid crystal composition comprising the same 有权
    萘衍生物和包含它们的液晶组合物

    公开(公告)号：US06468607B1

    公开(公告)日：2002-10-22

    申请号：US09296550

    申请日：1999-04-22

    申请人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

    发明人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

    IPC分类号： C09K1932

    CPC分类号： C07C17/2637 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C2601/14 ,  C07C2602/28 ,  C09K19/322 ,  Y10T428/10

    摘要： Disclosed is a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accordingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal composition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

    摘要翻译： 公开了一种新颖的液晶化合物，它是一种可用作电光液晶显示材料的萘衍生物，含有该衍生物的液晶组合物和包含该衍生物的液晶显示装置。 由本发明提供的萘衍生物与当前广泛使用的液晶组合物或组合物显示出优异的液晶性和混溶性。 通过加入萘衍生物可以使液晶组合物的阈值电压大大降低，同时保持其高响应性。 本发明的萘衍生物的特征在于双折射率大。 此外，本发明的大多数萘衍生物在其分子中没有强极性基团，因此也可用于有源矩阵驱动。 此外，如前述实施例所示，本发明的萘衍生物可以容易地制备，并且是无色和化学稳定的。 因此，含有本发明的萘衍生物的液晶组合物作为实用的液晶组合物，特别是能够在宽温度范围内工作并需要高速响应和低电压驱动的液晶组合物是非常有用的。