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    ISOTACTIC POLY(ALKYLENE OXIDE) AND PRODUCTION PROCESS THEREOF
    1.
    发明申请
    ISOTACTIC POLY(ALKYLENE OXIDE) AND PRODUCTION PROCESS THEREOF 审中-公开
    异辛烯（氧化亚烷基）及其生产方法

    公开(公告)号：US20110040070A1

    公开(公告)日：2011-02-17

    申请号：US12848402

    申请日：2010-08-02

    申请人： Masaaki NABIKA

    发明人： Masaaki NABIKA

    IPC分类号： C08G65/12

    CPC分类号： C08G65/10

    摘要： An isotactic poly(alkylene oxide) containing the defined repeating unit, and having an isotactic triad fraction of 66 to 100%, and number-average molecular weight of 500,000 or more; and a production process thereof, comprising the step of polymerizing an epoxide represented by the defined formula in the presence of a catalyst and an aliphatic compound and/or alicyclic compound.

    摘要翻译： 具有规定的重复单元的全同立构聚（环氧烷），全同立构三单元组分数为66〜100％，数均分子量为50万以上; 及其制备方法，包括在催化剂和脂族化合物和/或脂环族化合物的存在下聚合由所定义的式表示的环氧化物的步骤。

    TRANSITION METAL COMPLEX, PROCESS FOR PRODUCING THE SAME, AND USE
    2.
    发明申请
    TRANSITION METAL COMPLEX, PROCESS FOR PRODUCING THE SAME, AND USE 失效
    过渡金属复合物，其生产方法和使用

    公开(公告)号：US20100063228A1

    公开(公告)日：2010-03-11

    申请号：US12531852

    申请日：2008-03-18

    申请人： Hidenori Hanaoka ,  Masaaki Nabika

    发明人： Hidenori Hanaoka ,  Masaaki Nabika

    IPC分类号： C08F4/6592 ,  C07F7/28 ,  C08F4/44 ,  C08F4/52 ,  B01J31/12 ,  B01J31/14

    CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/02 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex of the following formula (1): in which A represents an atom of Group 16 of the periodic table; B1 represents an atom of Group 14 of the periodic table; M1 represents a transition metal atom of Group 4 of the periodic table; Cp1 represents a group having a cyclopentadiene anion backbone; R1, R2, R3, R4, R5 and R6 represent independently of one another a hydrogen atom, a halogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; R7, R8, R9, R10, R11 and R12 represent independently of one another a hydrogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R7, R8, R9, R10, R11, R12 and 4 carbon atoms coordinates on M1, and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.

    摘要翻译： 下式（1）的过渡金属络合物：其中A表示周期表第16族的原子; B1表示周期表第14族的原子; M1表示周期表第4族的过渡金属原子; Cp1表示具有环戊二烯阴离子主链的基团; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢原子，卤素原子，任选被卤素原子取代的C 1-20烷基; R 7，R 8，R 9，R 10，R 11和R 12彼此独立地表示氢原子，任选被卤素原子取代的C 1-20烷基; 和在M1上配位的包含R7，R8，R9，R10，R11，R12和4个碳原子的1,3-二烯，1,3-二烯可以是顺式或反式，或其混合形式， 虽然协调形式没有限制，双重债券可能会离域。 当该过渡金属络合物用作催化组分时，产生具有高催化活性的高分子量聚烯烃。

    PROCESS FOR PRODUCING OLEFIN OLIGOMER
    3.
    发明申请
    PROCESS FOR PRODUCING OLEFIN OLIGOMER 失效
    生产烯烃低聚物的方法

    公开(公告)号：US20060293546A1

    公开(公告)日：2006-12-28

    申请号：US11423009

    申请日：2006-06-08

    申请人： Masaaki NABIKA

    发明人： Masaaki NABIKA

    IPC分类号： C07C2/02

    CPC分类号： C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/02

    摘要： A process for producing an olefin oligomer, which comprises the steps of (1) contacting an olefin with an organoaluminum compound to produce a contact product (i), (2) contacting a transition metal compound with a compound represented by the formula, R1R2A—G—AR3R4, to produce a contact product (ii), and (3) contacting the contact product (i), the contact product (ii), an alumoxane compound, and optionally an olefin with one another, wherein A is a nitrogen atom, a phosphorus atom, an arsenic atom or an antimony atom, and As are the same as or different from each other; G is a divalent group; and R1, R2, R3 and R4 are independently of one another a hydrocarbyl group, a halogenated hydrocarbyl group, an oxygen-containing hydrocarbyl group, a sulfur-containing hydrocarbyl group, a selenium-containing hydrocarbyl group, or a tellurium-containing hydrocarbyl group.

    摘要翻译： 一种制备烯烃低聚物的方法，其包括以下步骤：（1）使烯烃与有机铝化合物接触以产生接触产物（i），（2）使过渡金属化合物与式 以产生接触产物（ⅱ），和（3）接触产物（ⅱ），（ⅲ） 使接触产物（i），接触产物（ii），铝氧烷化合物和任选的烯烃彼此接触，其中A为氮原子，磷原子，砷原子或锑原子，As为 相同或不同; G是二价基团; 且R 1，R 2，R 3和R 4彼此独立地为烃基， 卤代烃基，含氧烃基，含硫烃基，含硒烃基或含碲烃基。

    Process for producing olefin oligomer
    5.
    发明授权
    Process for producing olefin oligomer 失效
    烯烃低聚物的制备方法

    公开(公告)号：US07323611B2

    公开(公告)日：2008-01-29

    申请号：US11423009

    申请日：2006-06-08

    申请人： Masaaki Nabika

    发明人： Masaaki Nabika

    IPC分类号： C07C2/24

    CPC分类号： C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/02

    摘要： A process for producing an olefin oligomer, which comprises the steps of (1) contacting an olefin with an organoaluminum compound to produce a contact product (i), (2) contacting a transition metal compound with a compound represented by the formula, R1R2A-G-AR3R4, to produce a contact product (ii), and (3) contacting the contact product (i), the contact product (ii), an alumoxane compound, and optionally an olefin with one another, wherein A is a nitrogen atom, a phosphorus atom, an arsenic atom or an antimony atom, and As are the same as or different from each other; G is a divalent group; and R1, R2, R3 and R4 are independently of one another a hydrocarbyl group, a halogenated hydrocarbyl group, an oxygen-containing hydrocarbyl group, a sulfur-containing hydrocarbyl group, a selenium-containing hydrocarbyl group, or a tellurium-containing hydrocarbyl group.

    摘要翻译： 一种制备烯烃低聚物的方法，其包括以下步骤：（1）使烯烃与有机铝化合物接触以产生接触产物（i），（2）使过渡金属化合物与式 以产生接触产物（ⅱ），和（3）接触产物（ⅱ），（ⅲ） 使接触产物（i），接触产物（ii），铝氧烷化合物和任选的烯烃彼此接触，其中A为氮原子，磷原子，砷原子或锑原子，As为 相同或不同; G是二价基团; 且R 1，R 2，R 3和R 4彼此独立地为烃基， 卤代烃基，含氧烃基，含硫烃基，含硒烃基或含碲烃基。

    Method for producing bridged type transition metal complex
    7.
    发明授权
    Method for producing bridged type transition metal complex 失效
    制备桥连型过渡金属络合物的方法

    公开(公告)号：US5965758A

    公开(公告)日：1999-10-12

    申请号：US99306

    申请日：1998-06-18

    申请人： Masaaki Nabika ,  Kotohiro Nomura

    发明人： Masaaki Nabika ,  Kotohiro Nomura

    IPC分类号： C07F7/28 ,  C07F17/00 ,  C07F7/00

    CPC分类号： C07F17/00 ,  Y10S526/943

    摘要： A method for producing a bridged type transition metal complex represented by the following formula (1), comprising the following steps (i) and (ii):step (i); a step for reacting a specific cyclopentadiene compound with an organic alkaline metal compound or an organomagnesium compound to produce an alkaline metal salt compound or a magnesium salt compound of the cyclopentadiene compound; andstep (ii); a step for reacting the alkaline metal salt compound or magnesium salt compound of the cyclopentadiene compound with a specific transition metal compound, wherein at least the step (ii) is performed in the presence of an amine compound.According to the present invention, there can be provided a method for producing a bridged type transition metal complex having one cyclopentadiene type anion skeleton on an industrial scale in high yield without requiring an industrially disadvantageous low temperature and replacement of the solvent, which is capable of reducing the number of the steps.

    摘要翻译： 一种制备由下式（1）表示的桥连型过渡金属配合物的方法，包括以下步骤（i）和（ii）：步骤（i）; 使特定的环戊二烯化合物与有机碱金属化合物或有机镁化合物反应以制备环戊二烯化合物的碱金属盐化合物或镁盐化合物的步骤; 和步骤（ii）; 使环戊二烯化合物的碱金属盐化合物或镁盐化合物与特定的过渡金属化合物反应的步骤，其中至少步骤（ii）在胺化合物的存在下进行。 根据本发明，可以提供以工业规模高产率制备具有一个环戊二烯型阴离子骨架的桥连型过渡金属络合物的方法，而不需要工业上不利的低温和更换溶剂，其能够 减少步数。

    PROCESS FOR PRODUCING POLYMERIZATION CATALYST OF ALKYLENE OXIDE AND POLY(ALKYLENE OXIDE)
    8.
    发明申请
    PROCESS FOR PRODUCING POLYMERIZATION CATALYST OF ALKYLENE OXIDE AND POLY(ALKYLENE OXIDE) 审中-公开
    生产氧化亚烷基和聚（氧化亚烷基）的聚合催化剂的方法

    公开(公告)号：US20110112264A1

    公开(公告)日：2011-05-12

    申请号：US12911802

    申请日：2010-10-26

    申请人： Shigeyoshi KANOH ,  Masaaki NABIKA

    发明人： Shigeyoshi KANOH ,  Masaaki NABIKA

    IPC分类号： C08F4/52 ,  B01J31/14 ,  B01J31/02

    CPC分类号： C08G65/12 ,  C08G65/2654

    摘要： A production process of a polymerization catalyst of an alkylene oxide, comprising a step of contacting an alumoxane compound with a compound having a hydroxyl group; a production process of a pre-polymerized polymerization catalyst thereof, comprising a step of pre-polymerizing an alkylene oxide in the presence of the above polymerization catalyst; and a production process of a poly(alkylene oxide), comprising a step of polymerizing an alkylene oxide in the presence of the above polymerization catalyst or pre-polymerized polymerization catalyst.

    摘要翻译： 一种环氧烷聚合催化剂的制备方法，包括使铝氧烷化合物与具有羟基的化合物接触的步骤; 其预聚合聚合催化剂的制备方法，包括在上述聚合催化剂存在下预聚烯化氧的步骤; 和聚（环氧烷）的制造方法，包括在上述聚合催化剂或预聚合催化剂的存在下使烯化氧聚合的工序。

    PROCESS FOR PRODUCING OLEFIN OLIGOMER
    9.
    发明申请
    PROCESS FOR PRODUCING OLEFIN OLIGOMER 失效
    生产烯烃低聚物的方法

    公开(公告)号：US20070027350A1

    公开(公告)日：2007-02-01

    申请号：US11423251

    申请日：2006-06-09

    申请人： Masaaki NABIKA

    发明人： Masaaki NABIKA

    IPC分类号： C07C2/04

    CPC分类号： C07C2/36 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07C2531/14 ,  C07C2531/24

    摘要： A process for producing an olefin oligomer, which comprises the steps of (1) contacting a transition metal compound with a compound represented by the formula, R1R2A-G-AR3R4, to produce a contact product (i), (2) contacting an alumoxane compound with an organoaluminum compound to produce a contact product (ii), and (3) contacting the contact product (i), the contact product (ii), and an olefin with one another, wherein A is a nitrogen atom, a phosphorus atom, an arsenic atom or an antimony atom; G is a divalent group; and R1, R2, R3 and R4 are independently of one another a hydrocarbyl group, a halogenated hydrocarbyl group, an oxygen-containing hydrocarbyl group, a sulfur-containing hydrocarbyl group, a selenium-containing hydrocarbyl group, or a tellurium-containing hydrocarbyl group.

    摘要翻译： 一种制备烯烃低聚物的方法，其包括以下步骤：（1）使过渡金属化合物与下式表示的化合物R 1，R 2，R 2， 制备接触产物（i），（2）使铝氧烷化合物与有机铝化合物接触以制备接触产物（ⅱ）和（3） ）使接触产物（i），接触产物（ii）和烯烃彼此接触，其中A是氮原子，磷原子，砷原子或锑原子; G是二价基团; 且R 1，R 2，R 3和R 4彼此独立地为烃基， 卤代烃基，含氧烃基，含硫烃基，含硒烃基或含碲烃基。